Fluorogel elastomers with tunable transparency, elasticity, shape-memory, and antifouling properties
Abstract
In this study, omniphobic fluorogel elastomers were prepared by photocuring perfluorinated acrylates and a perfluoropolyether crosslinker. By tuning either the chemical composition or the temperature that control the crystallinity of the resulting polymer chains, a broad range of optical and mechanical properties of the fluorogel can be achieved. After infusing with fluorinated lubricants, the fluorogels showed excellent resistance to wetting by various liquids and anti-biofouling behavior, while maintaining cytocompatiblity.
- Authors:
-
- Harvard Univ., Cambridge, MA (United States)
- Publication Date:
- Research Org.:
- Harvard Univ., Cambridge, MA (United States)
- Sponsoring Org.:
- USDOE Advanced Research Projects Agency - Energy (ARPA-E)
- OSTI Identifier:
- 1159326
- Report Number(s):
- DOE-HARVARD-AR0000326-6
Journal ID: ISSN 1433-7851
- Grant/Contract Number:
- AR0000326
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Angewandte Chemie (International Edition)
- Additional Journal Information:
- Journal Name: Angewandte Chemie (International Edition); Journal Volume: 53; Journal Issue: 17; Journal ID: ISSN 1433-7851
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; antifouling; omniphobic surface; polymer gel; shape memory; surface chemistry
Citation Formats
Yao, Xi, Dunn, Stuart S., Kim, Philseok, Duffy, Meredith, Alvarenga, Jack, and Aizenberg, Joanna. Fluorogel elastomers with tunable transparency, elasticity, shape-memory, and antifouling properties. United States: N. p., 2014.
Web. doi:10.1002/anie.201310385.
Yao, Xi, Dunn, Stuart S., Kim, Philseok, Duffy, Meredith, Alvarenga, Jack, & Aizenberg, Joanna. Fluorogel elastomers with tunable transparency, elasticity, shape-memory, and antifouling properties. United States. https://doi.org/10.1002/anie.201310385
Yao, Xi, Dunn, Stuart S., Kim, Philseok, Duffy, Meredith, Alvarenga, Jack, and Aizenberg, Joanna. Tue .
"Fluorogel elastomers with tunable transparency, elasticity, shape-memory, and antifouling properties". United States. https://doi.org/10.1002/anie.201310385. https://www.osti.gov/servlets/purl/1159326.
@article{osti_1159326,
title = {Fluorogel elastomers with tunable transparency, elasticity, shape-memory, and antifouling properties},
author = {Yao, Xi and Dunn, Stuart S. and Kim, Philseok and Duffy, Meredith and Alvarenga, Jack and Aizenberg, Joanna},
abstractNote = {In this study, omniphobic fluorogel elastomers were prepared by photocuring perfluorinated acrylates and a perfluoropolyether crosslinker. By tuning either the chemical composition or the temperature that control the crystallinity of the resulting polymer chains, a broad range of optical and mechanical properties of the fluorogel can be achieved. After infusing with fluorinated lubricants, the fluorogels showed excellent resistance to wetting by various liquids and anti-biofouling behavior, while maintaining cytocompatiblity.},
doi = {10.1002/anie.201310385},
journal = {Angewandte Chemie (International Edition)},
number = 17,
volume = 53,
place = {United States},
year = {Tue Mar 18 00:00:00 EDT 2014},
month = {Tue Mar 18 00:00:00 EDT 2014}
}
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