Polyamides based on the renewable monomer, 1,13-tridecane diamine I: synthesis and characterization of nylon 13,T

He, Jie; Samanta, Satyabrata; Selvakumar, Sermadurai; Lattimer, Jessica; Ulven, Chad; Sibi, Mukund; Bahr, James; Chisholm, Bret J.

doi:10.1680/gmat.12.00021

Title: Polyamides based on the renewable monomer, 1,13-tridecane diamine I: synthesis and characterization of nylon 13,T

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Abstract

Nylon 13,T was successfully synthesized and chemical composition, thermal properties, crystal structure, and moisture absorption characterized. Melting temperature and glass transition temperature were determined to be 263 °C and 90 °C, respectively, while the equilibrium melting temperature was determined to be 289 °C. Characterization of the crystallization kinetics showed that nylon 13,T exhibits very fast crystallization compared to the industrially important nylons, nylon 6 and nylon 6,6. In addition, the moisture absorption of nylon 13,T was dramatically lower than nylon 6 and nylon 6,6 which is consistent with the much lower amide content of nylon 13,T. The crystal structure was determined to be pseudohexagonal.

Authors:

He, Jie ^[1]; Samanta, Satyabrata ^[1]; Selvakumar, Sermadurai ^[1]; Lattimer, Jessica ^[1]; Ulven, Chad ^[1]; Sibi, Mukund ^[1]; Bahr, James ^[1]; Chisholm, Bret J. ^[1]

North Dakota State Univ., Fargo, ND (United States)

Publication Date:: Sat Jun 01 00:00:00 EDT 2013

Research Org.:: North Dakota State Univ., Fargo, ND (United States)

Sponsoring Org.:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

OSTI Identifier:: 1072208

Report Number(s):: DOE/GO/88160-50
Journal ID: ISSN 2049-1220

Grant/Contract Number:: FG36-08GO88160

Resource Type:: Accepted Manuscript

Journal Name:: Green Materials

Additional Journal Information:: Journal Volume: 1; Journal Issue: 2; Journal ID: ISSN 2049-1220

Publisher:: ICE Publishing

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE

Citation Formats


                    He, Jie, Samanta, Satyabrata, Selvakumar, Sermadurai, Lattimer, Jessica, Ulven, Chad, Sibi, Mukund, Bahr, James, and Chisholm, Bret J. Polyamides based on the renewable monomer, 1,13-tridecane diamine I: synthesis and characterization of nylon 13,T.  United States: N. p., 2013. 
Web.  doi:10.1680/gmat.12.00021.

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                    He, Jie, Samanta, Satyabrata, Selvakumar, Sermadurai, Lattimer, Jessica, Ulven, Chad, Sibi, Mukund, Bahr, James, & Chisholm, Bret J. Polyamides based on the renewable monomer, 1,13-tridecane diamine I: synthesis and characterization of nylon 13,T.  United States.  https://doi.org/10.1680/gmat.12.00021

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                    He, Jie, Samanta, Satyabrata, Selvakumar, Sermadurai, Lattimer, Jessica, Ulven, Chad, Sibi, Mukund, Bahr, James, and Chisholm, Bret J. Sat .  
"Polyamides based on the renewable monomer, 1,13-tridecane diamine I: synthesis and characterization of nylon 13,T".  United States.  https://doi.org/10.1680/gmat.12.00021.  https://www.osti.gov/servlets/purl/1072208.

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@article{osti_1072208,

  title        = {Polyamides based on the renewable monomer, 1,13-tridecane diamine I: synthesis and characterization of nylon 13,T},

  author       = {He, Jie and Samanta, Satyabrata and Selvakumar, Sermadurai and Lattimer, Jessica and Ulven, Chad and Sibi, Mukund and Bahr, James and Chisholm, Bret J.},

  abstractNote = {Nylon 13,T was successfully synthesized and chemical composition, thermal properties, crystal structure, and moisture absorption characterized. Melting temperature and glass transition temperature were determined to be 263 °C and 90 °C, respectively, while the equilibrium melting temperature was determined to be 289 °C. Characterization of the crystallization kinetics showed that nylon 13,T exhibits very fast crystallization compared to the industrially important nylons, nylon 6 and nylon 6,6. In addition, the moisture absorption of nylon 13,T was dramatically lower than nylon 6 and nylon 6,6 which is consistent with the much lower amide content of nylon 13,T. The crystal structure was determined to be pseudohexagonal.},

  doi          = {10.1680/gmat.12.00021},

  journal      = {Green Materials},

  number       = 2,

  volume       = 1,

  place        = {United States},

  year         = {Sat Jun 01 00:00:00 EDT 2013},

  month        = {Sat Jun 01 00:00:00 EDT 2013}

}

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