skip to main content

DOE PAGESDOE PAGES

3 results for: All records
Author ORCID ID is 000000029169169X
Full Text and Citations
Filters
  1. Water has an incredible ability to form a rich variety of structures, with 16 bulk ice phases identified, for example, as well as numerous distinct structures for water at interfaces or under confinement. Many of these structures are built from hexagonal motifs of water molecules, and indeed, for water on metal surfaces, individual hexamers of just six water molecules have been observed. Here in this paper, we report the results of low-temperature scanning tunneling microscopy experiments and density functional theory calculations which reveal a host of new structures for water–ice nanoclusters when adsorbed on an atomically flat Cu surface. Themore » H-bonding networks within the nanoclusters resemble the resonance structures of polycyclic aromatic hydrocarbons, and water–ice analogues of inene, naphthalene, phenalene, anthracene, phenanthrene, and triphenylene have been observed. The specific structures identified and the H-bonding patterns within them reveal new insight about water on metals that allows us to refine the so-called “2D ice rules”, which have so far proved useful in understanding water–ice structures at solid surfaces.« less

"Cited by" information provided by Web of Science.

DOE PAGES offers free public access to the best available full-text version of DOE-affiliated accepted manuscripts or articles after an administrative interval of 12 months. The portal and search engine employ a hybrid model of both centralized and distributed content, with PAGES maintaining a permanent archive of all full text and metadata.