Dielectric Polarization Studies of Metallic Chelates

Journal Article · 31 October 1951 · Journal of the American Chemical Society

DOI: https://doi.org/10.1021/ja01155a066 · OSTI ID:4422729

Charles, Robert G. ^[1]; Freiser, Henry ^[1]

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1. Univ. of Pittsburgh, PA (United States)

The dielectric polarizations of dioxane solutions of lead 8-hydroxyquinolinate and disalicylidenemethylamine copper have been measured at 30°. These compounds, as do the acetylacetonates, are found to have abnormally high atomic polarizations. It is possible that most metallic chelates exhibit this phenomenon. In conclusion, the solubilities of some metallic 8-hydroxyquinolinates in benzene and dioxane at 25° have also been measured.

• Research Organization: Univ. of Pittsburgh, PA (United States)
• Sponsoring Organization: US Atomic Energy Commission (AEC)
• NSA Number: NSA-05-004701
• OSTI ID: 4422729
• Report Number(s): NYO--735
• Journal Information: Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 11 Vol. 73; ISSN 0002-7863
• Publisher: American Chemical Society (ACS)Copyright Statement
• Country of Publication: United States
• Language: English