Enhancing Charge Storage of Mo ₂ Ti ₂ C ₃ MXene by Partial Oxidation

Journal Article · 15 September 2023 · Advanced Functional Materials

DOI: https://doi.org/10.1002/adfm.202306815 · OSTI ID:2580504

Saraf, Mohit ; Chacon, Benjamin; Ippolito, Stefano ; Lord, Robert; Anayee, Mark; Wang, Ruocun ; Inman, Alex ; Shuck, Christopher ; Gogotsi, Yury

Abstract Driving the pseudocapacitive redox intercalation in 2DMXenes with neutral electrolytes is important for safer, more sustainable, and improved electrochemical charge storage. Single transition metal MXenes, such as Ti₃C₂, have shown great promise for energy storage, owing to their high conductivity and redox activity. Mixed metallic MXenes, such as out‐of‐plane ordered Mo₂Ti₂C₃, have remained underexplored in energy storage because of the absence of redox activity in most of the electrolytes. Simultaneous structural modifications and instigating intercalation pseudocapacitance in neutral electrolytes could be a viable strategy for enhancing their electrochemical properties. Herein, a facile synthesis of partially oxidized Mo₂Ti₂C₃MXene (PO‐Mo₂Ti₂C₃) exhibiting improved charge storage capability is demonstrated. Optical, structural, and spectroscopic analyses indicate the formation of oxide nanostructures upon thermal oxidation of Mo₂Ti₂C₃. This leads to an enhanced energy storage capability with remarkably improved cyclability as well as a high Coulombic efficiency in a neutral LiCl electrolyte. This work highlights the importance of structural modifications of MXenes to enhance their charge storage and shows the promise of less explored double transition metal MXenes in energy storage.

• Research Organization: Energy Frontier Research Centers (EFRC) (United States). Fluid Interface Reactions, Structures and Transport Center (FIRST)
• Sponsoring Organization: USDOE
• Grant/Contract Number: AC05-00OR22725
• OSTI ID: 2580504
• Journal Information: Advanced Functional Materials, Journal Name: Advanced Functional Materials Journal Issue: 1 Vol. 34; ISSN 1616-301X
• Publisher: WileyCopyright Statement
• Country of Publication: United States
• Language: EN