Operando Investigation on the Role of Densification and Chemo-Mechanics on Solid-State Cathodes

Jeong, Min‐Gi; Naik, Kaustubh G.; Zheng, Yanjie; Suk, Won Joon; Vishnugopi, Bairav S.; Lin, Lin; Puthusseri, Dhanya; Chuang, Andrew C.; Okasinski, John S.; Sakamoto, Jeff; Mukherjee, Partha P.; Hatzell, Kelsey B.

doi:10.1002/aenm.202304544

Title: Operando Investigation on the Role of Densification and Chemo-Mechanics on Solid-State Cathodes

Journal Article · 18 May 2024 · Advanced Energy Materials

DOI: https://doi.org/10.1002/aenm.202304544 · OSTI ID:2565698

Jeong, Min‐Gi ^[1]; Naik, Kaustubh G. ^[2]; Zheng, Yanjie ^[1]; Suk, Won Joon ^[3]; Vishnugopi, Bairav S. ^[2]; Lin, Lin ^[1]; Puthusseri, Dhanya ^[1]; Chuang, Andrew C. ^[4]; Okasinski, John S. ^[4]; Sakamoto, Jeff ^[3]; Mukherjee, Partha P. ^[2];

^[1]

Princeton Univ., NJ (United States)
Purdue Univ., West Lafayette, IN (United States)
Univ. of Michigan, Ann Arbor, MI (United States)
Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

All solid-state batteries are desirable for a range of energy storage applications which require high energy density. Achieving a high energy density in a solid-state battery requires the operation of an energy dense anode with a composite solid-state cathode. Pores and/or voids within a solid state cathode are ion-blocking and thus control over the concentration and distribution of pores in the initial electrode and cycled electrode is desirable. This study provides an understanding of the interplay between electrode microstructure and mechanics on active material utilization in solid state cathodes composed of NCM 811 and Li₆PS₅Cl. Decreasing the solid electrolyte particle size leads to greater active material-electrolyte contact and less total deformation when exposed to an external load. Composite cathodes with greater compliance can potentially decrease strain between the active material and solid electrolyte, decrease delamination events and result in higher overall active material utilization and high capacity retention.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS); Energy Frontier Research Centers (EFRC) (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357; SC0023438

OSTI ID:: 2565698

Alternate ID(s):: OSTI ID: 2352526; OSTI ID: 2568131

Journal Information:: Advanced Energy Materials, Journal Name: Advanced Energy Materials Journal Issue: 23 Vol. 14; ISSN 1614-6832

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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