Integrated electro- and chemical characterization of sulfide-based solid-state electrolytes

Li, Yuanshun; Lehmann, Michelle; Cheng, Lei; Zawodzinski, Thomas A.; Nanda, Jagjit; Yang, Guang

doi:10.1039/D4MA00619D

Title: Integrated electro- and chemical characterization of sulfide-based solid-state electrolytes

Journal Article · 02 October 2024 · Materials Advances

DOI: https://doi.org/10.1039/D4MA00619D · OSTI ID:2561485

Li, Yuanshun ^[1]; Lehmann, Michelle ^[2];

^[2]; Zawodzinski, Thomas A. ^[1]; Nanda, Jagjit ^[3];

^[2]

Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)

Sulfide solid-state electrolytes (SSEs) represent a critical advancement towards enabling next-generation lithium metal batteries. However, a profound knowledge gap remains in understanding the structure–property relationships inherent to these sulfide SSEs. Electrochemical assessment and spectroscopic tools, such as Raman spectroscopy, offer bench-top ready, non-invasive, powerful avenues for operando and in situ analyses. Despite this potential, the integration of these methodologies, particularly for real-time interrogation, is markedly under-investigated. This review endeavors to catalog the use of diverse electrochemical techniques and spectroscopic tools in elucidating the structural and functional nuances of sulfide SSEs. Through the harmonization of these multifaceted evaluation strategies, our objective is to chart a course towards optimized sulfide SSEs, thereby aiding in the development of informed protocols for a deeper comprehension and understanding of the structure–property relationship and interfacial engineered design of solid-state batteries using sulfide-based SSEs.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE; USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Vehicle Technologies Office (VTO)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 2561485

Journal Information:: Materials Advances, Journal Name: Materials Advances Journal Issue: 23 Vol. 5; ISSN 2633-5409

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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