Tuning electrochemical performance and interfacial compatibility of oxygen electrodes in proton-conducting solid oxide electrolysis cells

Karki, Saroj; Zheng, Shuanglin; Bello, Idris Temitope; Le, Allison; Ding, Hanping

doi:10.1039/D4TA08716J

Title: Tuning electrochemical performance and interfacial compatibility of oxygen electrodes in proton-conducting solid oxide electrolysis cells

Journal Article · 06 May 2025 · Journal of Materials Chemistry. A

DOI: https://doi.org/10.1039/D4TA08716J · OSTI ID:2549430

Karki, Saroj ^[1]; Zheng, Shuanglin ^[1]; Bello, Idris Temitope ^[1]; Le, Allison ^[1];

^[1]

School of Aerospace and Mechanical Engineering, University of Oklahoma, Norman, OK, USA

Modifying perovskite into A-site deficient electrode: oxygen vacancy enhances surface kinetics and durability, enabling superior performance and stability for protonic ceramic cells.

View Journal Article

Cite

Export

Save

Sponsoring Organization:: USDOE

Grant/Contract Number:: EE0011336

OSTI ID:: 2549430

Journal Information:: Journal of Materials Chemistry. A, Journal Name: Journal of Materials Chemistry. A Journal Issue: 18 Vol. 13; ISSN JMCAET; ISSN 2050-7488

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

References (52)

A High-Performance Electrocatalyst for Oxygen Evolution Reaction: LiCo _0.8 Fe _0.2 O ₂ Zhu, Yinlong; Zhou, Wei; Chen, Yubo Advanced Materials, Vol. 27, Issue 44 https://doi.org/10.1002/adma.201503532	journal	October 2015
3D Self-Architectured Steam Electrode Enabled Efficient and Durable Hydrogen Production in a Proton-Conducting Solid Oxide Electrolysis Cell at Temperatures Lower Than 600 °C Wu, Wei; Ding, Hanping; Zhang, Yunya Advanced Science, Vol. 5, Issue 11 https://doi.org/10.1002/advs.201800360	journal	August 2018
Enhancing Hydrogen Generation Through Nanoconfinement of Sensitizers and Catalysts in a Homogeneous Supramolecular Organic Framework Yu, Shang-Bo; Qi, Qi; Yang, Bo Small, Vol. 14, Issue 24 https://doi.org/10.1002/smll.201801037	journal	May 2018
An Unbalanced Battle in Excellence: Revealing Effect of Ni/Co Occupancy on Water Splitting and Oxygen Reduction Reactions in Triple‐Conducting Oxides for Protonic Ceramic Electrochemical Cells Tang, Wei; Ding, Hanping; Bian, Wenjuan Small, Vol. 18, Issue 30 https://doi.org/10.1002/smll.202201953	journal	June 2022
Electrokinetic Insights into the Triple Ionic and Electronic Conductivity of a Novel Nanocomposite Functional Material for Protonic Ceramic Fuel Cells Bello, Idris Temitope; Yu, Na; Song, Yufei Small, Vol. 18, Issue 40 https://doi.org/10.1002/smll.202203207	journal	September 2022
Cell performance enhancement facilitated by mixed ionic and electronic conductor fiber for protonic ceramic fuel cells Park, Sangho; Lee, Sewook; Baek, Hyeonwoo Journal of Electroceramics, Vol. 45, Issue 1 https://doi.org/10.1007/s10832-020-00218-3	journal	August 2020
Constructing an active and stable oxygen electrode surface for reversible protonic ceramic electrochemical cells Pei, Kai; Luo, Shunrui; He, Fan Applied Catalysis B: Environmental, Vol. 330 https://doi.org/10.1016/j.apcatb.2023.122601	journal	August 2023
Revolutionizing material design for protonic ceramic fuel cells: Bridging the limitations of conventional experimental screening and machine learning methods Bello, Idris Temitope; Guan, Daqin; Yu, Na Chemical Engineering Journal, Vol. 477 https://doi.org/10.1016/j.cej.2023.147098	journal	December 2023
Application of the distribution of relaxation time method in electrochemical analysis of the air electrodes in the SOFC/SOEC devices: A review Ghamarinia, Mitra; Babaei, Alireza; Zamani, Cyrus Chemical Engineering Journal Advances, Vol. 15 https://doi.org/10.1016/j.ceja.2023.100503	journal	August 2023
Evaluation of A-site deficient Sr 1−x Sc 0.175 Nb 0.025 Co 0.8 O 3−δ (x=0, 0.02, 0.05 and 0.1) perovskite cathodes for intermediate-temperature solid oxide fuel cells Chen, Guihua; Sunarso, Jaka; Wang, Yong Ceramics International, Vol. 42, Issue 11 https://doi.org/10.1016/j.ceramint.2016.05.057	journal	August 2016
A novel PrBaCo2O5+σ-BaZr0.1Ce0.7Y0.1Yb0.1O3 composite cathode for proton-conducting solid oxide fuel cells Liu, Bo; Jia, Lichao; Chi, Bo Composites Part B: Engineering, Vol. 191 https://doi.org/10.1016/j.compositesb.2020.107936	journal	June 2020
Composite cathodes for protonic ceramic fuel cells: Rationales and materials Wang, Meng; Su, Chao; Zhu, Zhonghua Composites Part B: Engineering, Vol. 238 https://doi.org/10.1016/j.compositesb.2022.109881	journal	June 2022
A comprehensive review of recent progresses in cathode materials for Proton-conducting SOFCs Gao, Yang; Zhang, Mingming; Fu, Min Energy Reviews, Vol. 2, Issue 3 https://doi.org/10.1016/j.enrev.2023.100038	journal	September 2023
A high-performance composite cathode based on thermal expansion complementation for SOFC Hu, Ling; Zhou, Defeng; Zhu, Xiaofei Fuel, Vol. 362 https://doi.org/10.1016/j.fuel.2024.130864	journal	April 2024
High performance of anode supported BaZr0.1Ce0.7Y0.2O3−δ(BZCY) electrolyte cell for IT-SOFC Liu, Mingfei; Gao, Jianfeng; Liu, Xingqin International Journal of Hydrogen Energy, Vol. 36, Issue 21 https://doi.org/10.1016/j.ijhydene.2011.07.087	journal	October 2011
Investigation of A-site deficient Ba0.9Co0.7Fe0.2Nb0.1O3−δ cathode for proton conducting electrolyte based solid oxide fuel cells Yang, Chenghao; Zhao, Fei; Chen, Fanglin International Journal of Hydrogen Energy, Vol. 39, Issue 16 https://doi.org/10.1016/j.ijhydene.2014.03.158	journal	May 2014
Evaluation of strontium-site-deficient Sr2Fe1.4Co0.1Mo0.5O6−δ-based perovskite oxides as intermediate temperature solid oxide fuel cell cathodes Zhen, Shuying; Sun, Wang; Tang, Guangze International Journal of Hydrogen Energy, Vol. 41, Issue 22 https://doi.org/10.1016/j.ijhydene.2016.04.094	journal	June 2016
Development of Pr2-Sr CuO4± mixed ion-electron conducting system as cathode for intermediate temperature solid oxide fuel cell Khandale, A. P.; Pahune, B. S.; Bhoga, S. S. International Journal of Hydrogen Energy, Vol. 44, Issue 29 https://doi.org/10.1016/j.ijhydene.2019.04.055	journal	June 2019
PrBaCo2-xTaxO5+δ based composite materials as cathodes for proton-conducting solid oxide fuel cells with high CO2 resistance Wang, Di; Xia, Yunpeng; Lv, Huanlin International Journal of Hydrogen Energy, Vol. 45, Issue 55 https://doi.org/10.1016/j.ijhydene.2020.08.094	journal	November 2020
Enhanced ORR activity of A-site deficiency engineered BaCo0·4Fe0·4Zr0·1Y0·1O3-δ cathode in practical YSZ fuel cells Wang, Wei; Zhang, Xiaozhen; Khan, Kashif International Journal of Hydrogen Energy, Vol. 46, Issue 7 https://doi.org/10.1016/j.ijhydene.2020.11.020	journal	January 2021
Ca-doped La0.75Sr0.25Cr0.5Mn0.5O3 cathode with enhanced CO2 electrocatalytic performance for high-temperature solid oxide electrolysis cells Qian, Bin; Liu, Chaohang; Wang, Shun International Journal of Hydrogen Energy, Vol. 46, Issue 67 https://doi.org/10.1016/j.ijhydene.2021.07.174	journal	September 2021
The influence of A-site deficiency on the electrochemical properties of (Ba0.95La0.05)1-xFeO3-δ as an intermediate temperature solid oxide fuel cell cathode Belotti, Alessio; Wang, Yuhao; Curcio, Antonino International Journal of Hydrogen Energy, Vol. 47, Issue 2 https://doi.org/10.1016/j.ijhydene.2021.10.098	journal	January 2022
BaZr0.1Fe0.9-xNixO3-δ cubic perovskite oxides for protonic ceramic fuel cell cathodes Wang, Jinpeng; Li, Zhongbiao; Zang, Huaikuan International Journal of Hydrogen Energy, Vol. 47, Issue 15 https://doi.org/10.1016/j.ijhydene.2022.01.012	journal	February 2022
Pr0.7Ba0.3Co0.8-Fe0.2Ni O3−δ perovskite: High activity and durable cathode for intermediate-to-low-temperature proton-conducting solid oxide fuel cells Zhu, Wanfeng; Wang, Haocong; Xu, Lanlan International Journal of Hydrogen Energy, Vol. 48, Issue 86 https://doi.org/10.1016/j.ijhydene.2023.05.115	journal	October 2023
Preparation of Pr, Co co-doped BaFeO3–δ-based nanofiber cathode materials by electrospinning Zhang, Youjie; Zhou, Defeng; Zhu, Xiaofei International Journal of Hydrogen Energy, Vol. 50 https://doi.org/10.1016/j.ijhydene.2023.09.277	journal	January 2024
A highly active catalytic cathode La0.8Sr0.2Co0.7Ni0.3O3-δ for protonic ceramic fuel cells: Experimental and computational insights Yao, Penghui; Zhang, Jian; Qiu, Qianyuan International Journal of Hydrogen Energy, Vol. 104 https://doi.org/10.1016/j.ijhydene.2024.08.305	journal	February 2025
Tailoring cathode composite boosts the performance of proton-conducting SOFCs fabricated by a one-step co-firing method Dai, Hailu; Da'as, Eman Husni; Shafi, Shahid P. Journal of the European Ceramic Society, Vol. 38, Issue 7 https://doi.org/10.1016/j.jeurceramsoc.2018.02.022	journal	July 2018
Self-Assembled Triple-Conducting Nanocomposite as a Superior Protonic Ceramic Fuel Cell Cathode Song, Yufei; Chen, Yubo; Wang, Wei Joule, Vol. 3, Issue 11 https://doi.org/10.1016/j.joule.2019.07.004	journal	November 2019
A-site deficient Ba_1−xCo_0.7Fe_0.2Ni_0.1O_3−δ cathode for intermediate temperature SOFC Liu, Ze; Cheng, Ling-zhi; Han, Min-Fang Journal of Power Sources, Vol. 196, Issue 2, p. 868-871 https://doi.org/10.1016/j.jpowsour.2010.05.051	journal	January 2011
A highly active anode functional layer for solid oxide fuel cells based on proton-conducting electrolyte BaZr0.1Ce0.7Y0.2O3−δ Zhang, Xiuling; Qiu, Yu'e; Jin, Feng Journal of Power Sources, Vol. 241 https://doi.org/10.1016/j.jpowsour.2013.05.002	journal	November 2013
Praseodymium-deficiency Pr0.94BaCo2O6- double perovskite: A promising high performance cathode material for intermediate-temperature solid oxide fuel cells Meng, Fuchang; Xia, Tian; Wang, Jingping Journal of Power Sources, Vol. 293 https://doi.org/10.1016/j.jpowsour.2015.06.007	journal	October 2015
A highly efficient composite cathode for proton-conducting solid oxide fuel cells Bu, Yunfei; Joo, Sangwook; Zhang, Yanxiang Journal of Power Sources, Vol. 451 https://doi.org/10.1016/j.jpowsour.2020.227812	journal	March 2020
Recent progress on cathode materials for protonic ceramic fuel cells Zhang, Wenwen; Zhang, Xiaomin; Song, Yuefeng Next Sustainability, Vol. 3 https://doi.org/10.1016/j.nxsust.2024.100028	journal	January 2024
Proton conducting oxides: A review of materials and applications for renewable energy conversion and storage Kim, J.; Sengodan, S.; Kim, S. Renewable and Sustainable Energy Reviews, Vol. 109 https://doi.org/10.1016/j.rser.2019.04.042	journal	July 2019
Sm0.5Sr0.5CoO3−δ–BaCe0.8Sm0.2O3-δ composite cathodes for proton-conducting solid oxide fuel cells Wu, Tianzhi; Peng, Ranran; Xia, Changrong Solid State Ionics, Vol. 179, Issue 27-32 https://doi.org/10.1016/j.ssi.2007.12.005	journal	September 2008
Enhancing Electrocatalytic Activity of Perovskite Oxides by Tuning Cation Deficiency for Oxygen Reduction and Evolution Reactions Zhu, Yinlong; Zhou, Wei; Yu, Jie Chemistry of Materials, Vol. 28, Issue 6 https://doi.org/10.1021/acs.chemmater.5b04457	journal	February 2016
Ultrafast Sintered Composite Cathode Incorporating a Negative Thermal Expansion Material for High-Performance Protonic Ceramic Fuel Cells Tahir, Abdullah; Belotti, Alessio; Song, Yufei ACS Applied Materials & Interfaces, Vol. 16, Issue 34 https://doi.org/10.1021/acsami.4c03312	journal	August 2024
An Active and Robust Air Electrode for Reversible Protonic Ceramic Electrochemical Cells Zhou, Yucun; Liu, Enzuo; Chen, Yu ACS Energy Letters https://doi.org/10.1021/acsenergylett.1c00432	journal	March 2021
Nanoengineering of cathode layers for solid oxide fuel cells to achieve superior power densities Develos-Bagarinao, Katherine; Ishiyama, Tomohiro; Kishimoto, Haruo Nature Communications, Vol. 12, Issue 1 https://doi.org/10.1038/s41467-021-24255-w	journal	June 2021
Surface restructuring of a perovskite-type air electrode for reversible protonic ceramic electrochemical cells Pei, Kai; Zhou, Yucun; Xu, Kang Nature Communications, Vol. 13, Issue 1 https://doi.org/10.1038/s41467-022-29866-5	journal	April 2022
Triple ionic–electronic conducting oxides for next-generation electrochemical devices Papac, Meagan; Stevanović, Vladan; Zakutayev, Andriy Nature Materials, Vol. 20, Issue 3 https://doi.org/10.1038/s41563-020-00854-8	journal	December 2020
Steam electrolysis by solid oxide electrolysis cells (SOECs) with proton-conducting oxides Bi, Lei; Boulfrad, Samir; Traversa, Enrico Chem. Soc. Rev., Vol. 43, Issue 24 https://doi.org/10.1039/C4CS00194J	journal	January 2014
A high performance cathode for proton conducting solid oxide fuel cells Wang, Zhiquan; Yang, Wenqiang; Shafi, Shahid P. Journal of Materials Chemistry A, Vol. 3, Issue 16 https://doi.org/10.1039/C5TA00391A	journal	January 2015
Performance and DRT analysis of P-SOFCs fabricated using new phase inversion combined tape casting technology Shi, Nai; Su, Feng; Huan, Daoming Journal of Materials Chemistry A, Vol. 5, Issue 37 https://doi.org/10.1039/C7TA04967F	journal	January 2017
High performing triple-conductive Pr ₂ NiO _4+δ anode for proton-conducting steam solid oxide electrolysis cell Li, Wenyuan; Guan, Bo; Ma, Liang Journal of Materials Chemistry A, Vol. 6, Issue 37 https://doi.org/10.1039/C8TA04018D	journal	January 2018
Tuning the defects of the triple conducting oxide BaCo 0.4 Fe 0.4 Zr 0.1 Y 0.1 O 3−δ perovskite toward enhanced cathode activity of protonic ceramic fuel cells Ren, Rongzheng; Wang, Zhenhua; Xu, Chunming Journal of Materials Chemistry A, Vol. 7, Issue 31 https://doi.org/10.1039/C9TA04335G	journal	January 2019
Transition from perovskite to misfit-layered structure materials: a highly oxygen deficient and stable oxygen electrode catalyst Saqib, Muhammad; Choi, In-Gyu; Bae, Hohan Energy & Environmental Science, Vol. 14, Issue 4 https://doi.org/10.1039/D0EE02799E	journal	January 2021
Understanding of A-site deficiency in layered perovskites: promotion of dual reaction kinetics for water oxidation and oxygen reduction in protonic ceramic electrochemical cells Tang, Wei; Ding, Hanping; Bian, Wenjuan Journal of Materials Chemistry A, Vol. 8, Issue 29 https://doi.org/10.1039/D0TA05137C	journal	January 2020
Design of anode functional layers for protonic solid oxide electrolysis cells Tang, Chunmei; Wang, Ning; Zhu, Ruijie Journal of Materials Chemistry A, Vol. 10, Issue 29 https://doi.org/10.1039/D2TA02760G	journal	January 2022
A robust protonic ceramic fuel cell with a triple conducting oxygen electrode under accelerated stress tests Zheng, Shuanglin; Bian, Wenjuan; Ding, Hanping Materials Advances, Vol. 5, Issue 6 https://doi.org/10.1039/D3MA01167D	journal	January 2024
A double perovskite oxygen electrode in Zr-rich proton conducting ceramic cells for efficient electricity generation and hydrogen production Zheng, Haoyu; Riegraf, Matthias; Sata, Noriko Journal of Materials Chemistry A, Vol. 11, Issue 20 https://doi.org/10.1039/D3TA01298K	journal	January 2023
Review on MIEC Cathode Materials for Solid Oxide Fuel Cells Burnwal, Suman Kumar; Bharadwaj, S.; Kistaiah, P. Journal of Molecular and Engineering Materials, Vol. 04, Issue 02 https://doi.org/10.1142/S2251237316300011	journal	June 2016

Similar Records

An Unbalanced Battle in Excellence: Revealing Effect of Ni/Co Occupancy on Water Splitting and Oxygen Reduction Reactions in Triple–Conducting Oxides for Protonic Ceramic Electrochemical Cells

Journal Article · 2022 · Small · OSTI ID:2228913

Tang, Wei; Ding, Hanping; Bian, Wenjuan; +11 more

Self-sustainable protonic ceramic electrochemical cells using a triple conducting electrode for hydrogen and power production

Journal Article · 2020 · Nature Communications · OSTI ID:1618272

Ding, Hanping; Wu, Wei; Jiang, Chao; +8 more

Theoretical understanding of stability of the oxygen electrode in a proton-conductor based solid oxide electrolysis cell

Journal Article · 2023 · International Journal of Hydrogen Energy · OSTI ID:2418802

Wang, Yudong; Marchetti, Barbara; Zhou, Xiao-Dong

Title: Tuning electrochemical performance and interfacial compatibility of oxygen electrodes in proton-conducting solid oxide electrolysis cells

Citation Formats

References (52)

Similar Records

Related Subjects