Freestanding BaTiO 3 ‐Au Vertically Aligned Nanocomposite toward Flexible Multi‐Sensing Platform

Tsai, Benson Kunhung; Huang, Jialong; Yu, Ya‐Ching; Lee, Meng Hao; Stegman, Benjamin Thomas; Flores, Emiliano Joseph; Tong, Patrick Zhang; Xu, Ke; Zhou, Shiyu; Shen, Jianan; Song, Jiawei; Zhang, Yizhi; Stanciu, Lia; Wu, Wenzhuo; Zhang, Xinghang; Wang, Haiyan

doi:10.1002/adfm.202418004

Title: Freestanding BaTiO ₃ ‐Au Vertically Aligned Nanocomposite toward Flexible Multi‐Sensing Platform

Journal Article · 22 January 2025 · Advanced Functional Materials

DOI: https://doi.org/10.1002/adfm.202418004 · OSTI ID:2538706

Tsai, Benson Kunhung ^[1]; Huang, Jialong ^[1]; Yu, Ya‐Ching ^[1]; Lee, Meng Hao ^[2]; Stegman, Benjamin Thomas ^[1]; Flores, Emiliano Joseph ^[1]; Tong, Patrick Zhang ^[1]; Xu, Ke ^[1]; Zhou, Shiyu ^[1]; Shen, Jianan ^[1]; Song, Jiawei ^[1]; Zhang, Yizhi ^[1]; Stanciu, Lia ^[3]; Wu, Wenzhuo ^[2]; Zhang, Xinghang ^[1];

^[4]

School of Materials Engineering Purdue University West Lafayette IN 47907 USA
School of Industrial Engineering Purdue University West Lafayette IN 47907 USA
School of Materials Engineering Purdue University West Lafayette IN 47907 USA, School of Biomedical Engineering Purdue University West Lafayette IN 47907 USA
School of Materials Engineering Purdue University West Lafayette IN 47907 USA, School of Electrical and Computer Engineering Purdue University West Lafayette IN 47907 USA

Abstract Flexible and wearable sensors show enormous potential for personalized healthcare devices by real‐time monitoring of an individual's health. Typically, a single functional material is selected for one sensor to sense a particular physical signal while multiple materials will be selected for multi‐mode sensing. Vertically aligned nanocomposites (VANs) have recently demonstrated various material combinations and novel coupled multifunctionalities that are hard to achieve in any single‐phase material alone, including multiphase multiferroics, magneto‐optic coupling, and strong magnetic and optical anisotropy. Integrating these novel VANs into wearable sensors shows enormous potential in multi‐mode sensing owing to their multifunctional nature. In this work, the transfer of VANs onto polydimethylsiloxane as a novel flexible chemical and pressure sensor is demonstrated. For this demonstration, the classical BaTiO ₃ ‐Au VAN with combined plasmonic and piezoelectric properties is used to demonstrate a multi‐sensing mechanism. A thin water‐soluble buffer of Sr ₃ Al ₂ O ₆ serves as a buffer layer for the epitaxial growth and transfer process. The electrical output based on the piezoelectric responses and identifying 4‐mercaptobenzoic acid by surface‐enhanced Raman spectroscopy reveal great potential for free‐standing VANs in a wearable multifunctional sensing platform.

View Journal Article

Cite

Export

Save

Sponsoring Organization:: USDOE

Grant/Contract Number:: SC0020077

OSTI ID:: 2538706

Journal Information:: Advanced Functional Materials, Journal Name: Advanced Functional Materials Journal Issue: 13 Vol. 35; ISSN 1616-301X

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

References (59)

Vertically Aligned Nanocomposite Thin Films as a Cathode/Electrolyte Interface Layer for Thin-Film Solid Oxide Fuel Cells Yoon, Jongsik; Cho, Sungmee; Kim, Jung-Hyun Advanced Functional Materials, Vol. 19, Issue 24 https://doi.org/10.1002/adfm.200901338	journal	December 2009
A New Material for High-Temperature Lead-Free Actuators Kursumovic, Ahmed; Defay, Emmanuel; Lee, Oon Jew Advanced Functional Materials, Vol. 23, Issue 47 https://doi.org/10.1002/adfm.201300899	journal	June 2013
Freestanding Perovskite Oxide Membranes: A New Playground for Novel Ferroic Properties and Applications Han, Lu; Dong, Guohua; Liu, Ming Advanced Functional Materials, Vol. 34, Issue 4 https://doi.org/10.1002/adfm.202309543	journal	October 2023
Highly-Efficient, Flexible Piezoelectric PZT Thin Film Nanogenerator on Plastic Substrates Park, Kwi-Il; Son, Jung Hwan; Hwang, Geon-Tae Advanced Materials, Vol. 26, Issue 16 https://doi.org/10.1002/adma.201305659	journal	February 2014
Self-Powered Cardiac Pacemaker Enabled by Flexible Single Crystalline PMN-PT Piezoelectric Energy Harvester Hwang, Geon-Tae; Park, Hyewon; Lee, Jeong-Ho Advanced Materials, Vol. 26, Issue 28, p. 4880-4887 https://doi.org/10.1002/adma.201400562	journal	April 2014
Highly Conductive, Flexible, and Compressible All-Graphene Passive Electronic Skin for Sensing Human Touch Hou, Chengyi; Wang, Hongzhi; Zhang, Qinghong Advanced Materials, Vol. 26, Issue 29 https://doi.org/10.1002/adma.201401367	journal	June 2014
Periodic Wrinkle‐Patterned Single‐Crystalline Ferroelectric Oxide Membranes with Enhanced Piezoelectricity Dong, Guohua; Li, Suzhi; Li, Tao Advanced Materials, Vol. 32, Issue 50 https://doi.org/10.1002/adma.202004477	journal	November 2020
Freestanding Ferroelectric Bubble Domains Bakaul, Saidur R.; Prokhorenko, Sergei; Zhang, Qi Advanced Materials, Vol. 33, Issue 45 https://doi.org/10.1002/adma.202105432	journal	September 2021
Ultrathin Piezoelectric Resonators Based on Graphene and Free‐Standing Single‐Crystal BaTiO₃ Lee, Martin; Renshof, Johannes R.; van Zeggeren, Kasper J. Advanced Materials, Vol. 34, Issue 44 https://doi.org/10.1002/adma.202204630	journal	October 2022
Size‐Induced Ferroelectricity in Antiferroelectric Oxide Membranes Xu, Ruijuan; Crust, Kevin J.; Harbola, Varun Advanced Materials, Vol. 35, Issue 17 https://doi.org/10.1002/adma.202210562	journal	March 2023
Multifunctional Magnetic Oxide‐MoS₂ Heterostructures on Silicon Yang, Allen Jian; Wu, Liang; Liu, Yanran Advanced Materials, Vol. 35, Issue 33 https://doi.org/10.1002/adma.202302620	journal	July 2023
Tunable Friction Properties of Periodic Wrinkled BaTiO₃ Membranes Liu, Haixia; Yuan, Haozhi; Dong, Guohua Advanced Materials Interfaces, Vol. 9, Issue 13 https://doi.org/10.1002/admi.202102316	journal	March 2022
Tunable Optical Properties in Self‐Assembled Oxide‐Metal Hybrid Thin Films via Au‐Phase Geometry Control: From Nanopillars to Nanodisks Zhang, Di; Misra, Shikhar; Li, Leigang Advanced Optical Materials, Vol. 8, Issue 4 https://doi.org/10.1002/adom.201901359	journal	December 2019
Design of 3D Oxide–Metal Hybrid Metamaterial for Tailorable Light–Matter Interactions in Visible and Near‐Infrared Region Zhang, Di; Lu, Ping; Misra, Shikhar Advanced Optical Materials, Vol. 9, Issue 1 https://doi.org/10.1002/adom.202001154	journal	November 2020
Nanoscale Artificial Plasmonic Lattice in Self-Assembled Vertically Aligned Nitride-Metal Hybrid Metamaterials Huang, Jijie; Wang, Xuejing; Hogan, Nicki L. Advanced Science, Vol. 5, Issue 7 https://doi.org/10.1002/advs.201800416	journal	April 2018
One-Dimensional Nanomaterials for Soft Electronics Gong, Shu; Cheng, Wenlong Advanced Electronic Materials, Vol. 3, Issue 3 https://doi.org/10.1002/aelm.201600314	journal	December 2016
Freestanding Perovskite Oxide Films: Synthesis, Challenges, and Properties Chiabrera, Francesco M.; Yun, Shinhee; Li, Ying Annalen der Physik, Vol. 534, Issue 9 https://doi.org/10.1002/andp.202200084	journal	June 2022
Piezoelectric Flexible Energy Harvester Based on BaTiO₃ Thin Film Enabled by Exfoliating the Mica Substrate Hyeon, Dong Yeol; Park, Kwi-Il Energy Technology, Vol. 7, Issue 10 https://doi.org/10.1002/ente.201900638	journal	August 2019
Strain Engineering: Perfecting Freestanding Perovskite Oxide Fabrication Yun, Shinhee; le Cozannet, Thomas Emil; Christoffersen, Christina Høgfeldt Small, Vol. 20, Issue 30 https://doi.org/10.1002/smll.202310782	journal	March 2024
High Yield Transfer of Clean Large-Area Epitaxial Oxide Thin Films Zhang, Bowen; Yun, Chao; MacManus-Driscoll, Judith L. Nano-Micro Letters, Vol. 13, Issue 1 https://doi.org/10.1007/s40820-020-00573-4	journal	January 2021
Multifunctional self-assembled BaTiO3-Au nanocomposite thin films on flexible mica substrates with tunable optical properties Liu, Juncheng; Wang, Xuejing; Gao, Xingyao Applied Materials Today, Vol. 21 https://doi.org/10.1016/j.apmt.2020.100856	journal	December 2020
Electrophoretic deposition of BaTiO3/CoFe2O4 multiferroic composite films Zhou, Dongxiang; Jian, Gang; Zheng, Yanan Applied Surface Science, Vol. 257, Issue 17 https://doi.org/10.1016/j.apsusc.2011.03.141	journal	June 2011
Flexible piezoelectric pressure sensor with high sensitivity for electronic skin using near-field electrohydrodynamic direct-writing method Luo, Jiaqing; Zhang, Libing; Wu, Ting Extreme Mechanics Letters, Vol. 48 https://doi.org/10.1016/j.eml.2021.101279	journal	October 2021
Tunable, room-temperature multiferroic Fe-BaTiO3 vertically aligned nanocomposites with perpendicular magnetic anisotropy Zhang, B.; Huang, J.; Rutherford, B. X. Materials Today Nano, Vol. 11 https://doi.org/10.1016/j.mtnano.2020.100083	journal	August 2020
2D Materials in Flexible Electronics: Recent Advances and Future Prospectives Katiyar, Ajit Kumar; Hoang, Anh Tuan; Xu, Duo Chemical Reviews, Vol. 124, Issue 2 https://doi.org/10.1021/acs.chemrev.3c00302	journal	December 2023
Multifunctional Metal–Oxide Nanocomposite Thin Film with Plasmonic Au Nanopillars Embedded in Magnetic La _0.67 Sr _0.33 MnO ₃ Matrix Huang, Jijie; Wang, Han; Qi, Zhimin Nano Letters, Vol. 21, Issue 2 https://doi.org/10.1021/acs.nanolett.0c04213	journal	January 2021
Multiferroic Self-Assembled BaTiO₃–Fe Vertically Aligned Nanocomposites on Mica Substrates toward Flexible Electronics Liu, Juncheng; Wang, Xuejing; Wang, Han ACS Applied Electronic Materials, Vol. 4, Issue 8 https://doi.org/10.1021/acsaelm.2c00712	journal	August 2022
Exchange Bias in a La _0.67 Sr _0.33 MnO ₃ /NiO Heterointerface Integrated on a Flexible Mica Substrate Huang, Jijie; Wang, Han; Wang, Xuejing ACS Applied Materials & Interfaces, Vol. 12, Issue 35 https://doi.org/10.1021/acsami.0c12935	journal	August 2020
Self-Assembled Complex Three-Phase Core–Shell Nanostructure of Au–CoFe₂–TiN with a Magneto-Optical Coupling Effect Song, Jiawei; Zhang, Di; Lu, Ping ACS Applied Materials & Interfaces, Vol. 15, Issue 31 https://doi.org/10.1021/acsami.3c06777	journal	July 2023
All-Oxide Nanocomposites to Yield Large, Tunable Perpendicular Exchange Bias above Room Temperature Wu, Rui; Yun, Chao; Wang, Xuejing ACS Applied Materials & Interfaces, Vol. 10, Issue 49 https://doi.org/10.1021/acsami.8b14635	journal	November 2018
Present and Future of Surface-Enhanced Raman Scattering Langer, Judith; Jimenez de Aberasturi, Dorleta; Aizpurua, Javier ACS Nano, Vol. 14, Issue 1 https://doi.org/10.1021/acsnano.9b04224	journal	September 2019
Lab-On-Capillary Platform for On-Site Quantitative SERS Analysis of Surface Contaminants Based on Au@4-MBA@Ag Core–Shell Nanorods Lin, Shuang; Hasi, Wuliji; Lin, Xiang ACS Sensors, Vol. 5, Issue 5 https://doi.org/10.1021/acssensors.0c00398	journal	April 2020
A Generalized Description of the Elastic Properties of Nanowires Heidelberg, Andreas; Ngo, Lien T.; Wu, Bin Nano Letters, Vol. 6, Issue 6 https://doi.org/10.1021/nl060028u	journal	June 2006
Piezoelectric BaTiO ₃ Thin Film Nanogenerator on Plastic Substrates Park, Kwi-Il; Xu, Sheng; Liu, Ying Nano Letters, Vol. 10, Issue 12 https://doi.org/10.1021/nl102959k	journal	December 2010
Mechanical properties of ultrahigh-strength gold nanowires Wu, Bin; Heidelberg, Andreas; Boland, John J. Nature Materials, Vol. 4, Issue 7 https://doi.org/10.1038/nmat1403	journal	June 2005
Synthesis of freestanding single-crystal perovskite films and heterostructures by etching of sacrificial water-soluble layers Lu, Di; Baek, David J.; Hong, Seung Sae Nature Materials, Vol. 15, Issue 12 https://doi.org/10.1038/nmat4749	journal	September 2016
Dynamics of ferroelastic domains in ferroelectric thin films Nagarajan, V.; Roytburd, A.; Stanishevsky, A. Nature Materials, Vol. 2, Issue 1 https://doi.org/10.1038/nmat800	journal	December 2002
Mechanical-force-induced non-local collective ferroelastic switching in epitaxial lead-titanate thin films Lu, Xiaoyan; Chen, Zuhuang; Cao, Ye Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-11825-2	journal	September 2019
Nonvolatile ferroelectric domain wall memory integrated on silicon Sun, Haoying; Wang, Jierong; Wang, Yushu Nature Communications, Vol. 13, Issue 1 https://doi.org/10.1038/s41467-022-31763-w	journal	July 2022
Enhanced polarization and abnormal flexural deformation in bent freestanding perovskite oxides Cai, Songhua; Lun, Yingzhuo; Ji, Dianxiang Nature Communications, Vol. 13, Issue 1 https://doi.org/10.1038/s41467-022-32519-2	journal	August 2022
Remarkable flexibility in freestanding single-crystalline antiferroelectric PbZrO3 membranes Guo, Yunting; Peng, Bin; Lu, Guangming Nature Communications, Vol. 15, Issue 1 https://doi.org/10.1038/s41467-024-47419-w	journal	May 2024
Freestanding crystalline oxide perovskites down to the monolayer limit Ji, Dianxiang; Cai, Songhua; Paudel, Tula R. Nature, Vol. 570, Issue 7759 https://doi.org/10.1038/s41586-019-1255-7	journal	June 2019
High-density switchable skyrmion-like polar nanodomains integrated on silicon Han, Lu; Addiego, Christopher; Prokhorenko, Sergei Nature, Vol. 603, Issue 7899 https://doi.org/10.1038/s41586-021-04338-w	journal	March 2022
High-κ perovskite membranes as insulators for two-dimensional transistors Huang, Jing-Kai; Wan, Yi; Shi, Junjie Nature, Vol. 605, Issue 7909 https://doi.org/10.1038/s41586-022-04588-2	journal	May 2022
Wearable sweat sensors Bariya, Mallika; Nyein, Hnin Yin Yin; Javey, Ali Nature Electronics, Vol. 1, Issue 3 https://doi.org/10.1038/s41928-018-0043-y	journal	March 2018
Van der Waals integration of high-κ perovskite oxides and two-dimensional semiconductors Yang, Allen Jian; Han, Kun; Huang, Ke Nature Electronics, Vol. 5, Issue 4 https://doi.org/10.1038/s41928-022-00753-7	journal	April 2022
Ultrathin complex oxide nanomechanical resonators Davidovikj, D.; Groenendijk, D. J.; Monteiro, A. M. R. V. L. Communications Physics, Vol. 3, Issue 1 https://doi.org/10.1038/s42005-020-00433-y	journal	September 2020
Bimetallic silver–gold nanowires: fabrication and use in surface-enhanced Raman scattering Hunyadi, Simona E.; Murphy, Catherine J. J. Mater. Chem., Vol. 16, Issue 40 https://doi.org/10.1039/B607116C	journal	January 2006
Hybrid plasmonic Au–TiN vertically aligned nanocomposites: a nanoscale platform towards tunable optical sensing Wang, Xuejing; Jian, Jie; Diaz-Amaya, Susana Nanoscale Advances, Vol. 1, Issue 3 https://doi.org/10.1039/C8NA00306H	journal	January 2019
Review on the growth, properties and applications of self-assembled oxide–metal vertically aligned nanocomposite thin films—current and future perspectives Misra, Shikhar; Wang, Haiyan Materials Horizons, Vol. 8, Issue 3 https://doi.org/10.1039/D0MH01111H	journal	January 2021
Mapping cation diffusion through lattice defects in epitaxial oxide thin films on the water-soluble buffer layer Sr3Al2O6 using atomic resolution electron microscopy Baek, David J.; Lu, Di; Hikita, Yasuyuki APL Materials, Vol. 5, Issue 9 https://doi.org/10.1063/1.4994538	journal	September 2017
Substrate Clamping Effects on Irreversible Domain Wall Dynamics in Lead Zirconate Titanate Thin Films Griggio, F.; Jesse, S.; Kumar, A. Physical Review Letters, Vol. 108, Issue 15 https://doi.org/10.1103/PhysRevLett.108.157604	journal	April 2012
Phase transition enhanced superior elasticity in freestanding single-crystalline multiferroic BiFeO ₃ membranes Peng, Bin; Peng, Ren-Ci; Zhang, Yong-Qiang Science Advances, Vol. 6, Issue 34 https://doi.org/10.1126/sciadv.aba5847	journal	August 2020
Wearable plasmonic paper–based microfluidics for continuous sweat analysis Mogera, Umesha; Guo, Heng; Namkoong, Myeong Science Advances, Vol. 8, Issue 12 https://doi.org/10.1126/sciadv.abn1736	journal	March 2022
Super-elastic ferroelectric single-crystal membrane with continuous electric dipole rotation Dong, Guohua; Li, Suzhi; Yao, Mouteng Science, Vol. 366, Issue 6464 https://doi.org/10.1126/science.aay7221	journal	October 2019
Super-tetragonal Sr ₄ Al ₂ O ₇ as a sacrificial layer for high-integrity freestanding oxide membranes Zhang, Jinfeng; Lin, Ting; Wang, Ao Science, Vol. 383, Issue 6681 https://doi.org/10.1126/science.adi6620	journal	January 2024
High energy density in artificial heterostructures through relaxation time modulation Han, Sangmoon; Kim, Justin S.; Park, Eugene Science, Vol. 384, Issue 6693 https://doi.org/10.1126/science.adl2835	journal	April 2024
All-printed soft human-machine interface for robotic physicochemical sensing Yu, You; Li, Jiahong; Solomon, Samuel A. Science Robotics, Vol. 7, Issue 67 https://doi.org/10.1126/scirobotics.abn0495	journal	June 2022
New epitaxy paradigm in epitaxial self-assembled oxide vertically aligned nanocomposite thin films Huang, Jijie; MacManus-Driscoll, Judith L.; Wang, Haiyan Journal of Materials Research, Vol. 32, Issue 21 https://doi.org/10.1557/jmr.2017.281	journal	July 2017

Similar Records

Face mask integrated with flexible and wearable manganite oxide respiration sensor

Journal Article · 2023 · Nano Energy · OSTI ID:2421419

Ye, Lianxu; Wu, Fan; Xu, Ruixing; +19 more

Tunable, room-temperature multiferroic Fe-BaTiO₃ vertically aligned nanocomposites with perpendicular magnetic anisotropy

Journal Article · 2020 · Materials Today Nano · OSTI ID:1668353

Zhang, B.; Huang, J.; Rutherford, B. X.; +8 more

An Ultra‐Shapeable, Smart Sensing Platform Based on a Multimodal Ferrofluid‐Infused Surface

Journal Article · 2019 · Advanced Materials · OSTI ID:1492459

Ahmed, Abdelsalam; Hassan, Islam; Mosa, Islam M.; +4 more

Title: Freestanding BaTiO 3 ‐Au Vertically Aligned Nanocomposite toward Flexible Multi‐Sensing Platform

Citation Formats

References (59)

Similar Records

Related Subjects

Title: Freestanding BaTiO ₃ ‐Au Vertically Aligned Nanocomposite toward Flexible Multi‐Sensing Platform