Surface-enhanced stimulated Raman spectroscopy with squeezed photonic states

Hagelberg, Frank; Passian, Ali

doi:10.1103/physreva.111.012628

Title: Surface-enhanced stimulated Raman spectroscopy with squeezed photonic states

Journal Article · 27 January 2025 · Physical Review A

DOI: https://doi.org/10.1103/physreva.111.012628 · OSTI ID:2538282

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East Tennessee State Univ. (ETSU), Johnson CIty, TN (United States)
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Recent advances in generating light in specific quantum states facilitate new sensing applications and enhance or revitalize established measurement and sensing techniques. Stimulated Raman spectroscopy (SRS), a measurement modality based on Raman scattering, could benefit from tuning the quantum properties of the pump and the Stokes lights or the properties of quantum states of the stimulating and excitation fields. Additionally, this modality could also benefit from field enhancement accompanied by plasmon excitation in the surface regions of metal nanoparticles. We present a theoretical investigation of stimulated Raman scattering involving squeezed states of light. The concept of surface- and quantum-enhanced stimulated Raman scattering is introduced. Furthermore, expressions for the respective SRS transition rates are derived, and their dependence on the quantum states of the optical field is discussed, with particular emphasis on the squeezing parameters characterizing these states. For cases involving surface enhancements, we also employ classical computational electrodynamics to guide our exploration of atomically large systems that support plasmon excitation.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Biological and Environmental Research (BER)

Grant/Contract Number:: AC05-00OR22725; SC0023337

OSTI ID:: 2538282

Journal Information:: Physical Review A, Journal Name: Physical Review A Journal Issue: 1 Vol. 111; ISSN 2469-9926

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

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