Mechanical and Light Activation of Materials for Chemical Production

Đorđević, Luka; Jaynes, Tyler J.; Sai, Hiroaki; Barbieri, Marianna; Kupferberg, Jacob E.; Sather, Nicholas A.; Weigand, Steven; Stupp, Samuel I.

doi:10.1002/adma.202418137

Title: Mechanical and Light Activation of Materials for Chemical Production

Journal Article · 11 March 2025 · Advanced Materials

DOI: https://doi.org/10.1002/adma.202418137 · OSTI ID:2530665

^[1];

^[2];

^[3];

^[4];

^[5];

^[6];

^[7]

Department of Chemical Sciences University of Padova Via Marzolo 1 Padova 35131 Italy, Center for Bio‐inspired Energy Science Northwestern University 2145 Sheridan Road Evanston IL 60208 USA, Department of Chemistry Northwestern University 2145 Sheridan Road Evanston IL 60208 USA
Center for Bio‐inspired Energy Science Northwestern University 2145 Sheridan Road Evanston IL 60208 USA, Department of Chemistry Northwestern University 2145 Sheridan Road Evanston IL 60208 USA
Center for Regenerative Nanomedicine Northwestern University 303 E Superior Chicago IL 60611 USA
Department of Chemical Sciences University of Padova Via Marzolo 1 Padova 35131 Italy
Department of Materials Science and Engineering Northwestern University 2220 Campus Drive Evanston IL 60208 USA
DuPont‐Northwestern‐Dow Collaborative Access Team Synchrotron Research Center Northwestern University DND‐CAT Argonne IL 60439 USA
Center for Bio‐inspired Energy Science Northwestern University 2145 Sheridan Road Evanston IL 60208 USA; Department of Chemistry Northwestern University 2145 Sheridan Road Evanston IL 60208 USA; Department of Materials Science and Engineering Northwestern University 2220 Campus Drive Evanston IL 60208 USA; Department of Biomedical Engineering Northwestern University 2145 Sheridan Road Evanston IL 60208 USA; Department of Medicine Northwestern University 676 N St. Clair Street Chicago IL 60611 USA

Abstract Mechanical expansion and contraction of pores within photosynthetic organisms regulate a series of processes that are necessary to manage light absorption, control gas exchange, and regulate water loss. These pores, known as stoma, allow the plant to maximize photosynthetic output depending on environmental conditions such as light intensity, humidity, and temperature by actively changing the size of the stomal opening. Despite advances in artificial photosynthetic systems, little is known about the effect of such mechanical actuation in synthetic materials where chemical reactions occur. It is reported here on a hybrid hydrogel that combines light‐activated supramolecular polymers for superoxide production with thermal mechanical actuation of a covalent polymer. Superoxide production is important in organic synthesis and environmental remediation, and is a potential precursor to hydrogen peroxide liquid fuel. It is shown that the closing of pores in the hybrid hydrogel results in a substantial decrease in photocatalysis, but cycles of swollen and contracted states enhance photocatalysis. The observations motivate the development of biomimetic photosynthetic materials that integrate large scale motion and chemical reactions.

View Journal Article

Cite

Export

Save

Sponsoring Organization:: USDOE

Grant/Contract Number:: SC0000989

OSTI ID:: 2530665

Journal Information:: Advanced Materials, Journal Name: Advanced Materials Journal Issue: 16 Vol. 37; ISSN 0935-9648

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

References (75)

Biomimetic Solar Photocatalytic Reactor for Selective Oxidation of Aromatic Alcohols with Enhanced Solar‐Energy Utilization Qin, Jingjing; Li, Jiahao; Chu, Kaibin Advanced Functional Materials, Vol. 34, Issue 9 https://doi.org/10.1002/adfm.202311214	journal	November 2023
Nature Inspired Phototropic Artificial Photosynthesis Zhang, Jiaqi; Fang, Tao; Chen, Tingting Advanced Functional Materials https://doi.org/10.1002/adfm.202422228	journal	January 2025
Molecular Structural Design of Conjugated Microporous Poly(Benzooxadiazole) Networks for Enhanced Photocatalytic Activity with Visible Light Wang, Zi Jun; Ghasimi, Saman; Landfester, Katharina Advanced Materials, Vol. 27, Issue 40 https://doi.org/10.1002/adma.201502735	journal	September 2015
Self-Assembled PDINH Supramolecular System for Photocatalysis under Visible Light Liu, Di; Wang, Jun; Bai, Xiaojuan Advanced Materials, Vol. 28, Issue 33 https://doi.org/10.1002/adma.201601168	journal	June 2016
Enhanced Singlet Oxygen Generation in Oxidized Graphitic Carbon Nitride for Organic Synthesis Wang, Hui; Jiang, Shenlong; Chen, Shichuan Advanced Materials, Vol. 28, Issue 32 https://doi.org/10.1002/adma.201601413	journal	June 2016
Aggregation‐Induced Emission‐Active Gels: Fabrications, Functions, and Applications Li, Zhao; Ji, Xiaofan; Xie, Huilin Advanced Materials, Vol. 33, Issue 33 https://doi.org/10.1002/adma.202100021	journal	July 2021
Solvothermal Template‐Induced Hierarchical Porosity in Covalent Organic Frameworks: A Pathway to Enhanced Diffusivity Heck, Fabian; Grunenberg, Lars; Schnabel, Nadine Advanced Materials https://doi.org/10.1002/adma.202415882	journal	January 2025
Water‐Soluble Organic Dyes as Molecular Photocatalysts for H ₂ O ₂ Evolution Gryszel, Maciej; Rybakiewicz, Renata; Głowacki, Eric Daniel Advanced Sustainable Systems, Vol. 3, Issue 8 https://doi.org/10.1002/adsu.201900027	journal	May 2019
Aqueous Photocatalytic Glycerol Oxidation to Formic Acid Coupled to H₂O₂ Production with an Anthraquinone Dye Tacchi, Elena; Rossi, Greta; Natali, Mirco Advanced Sustainable Systems, Vol. 9, Issue 1 https://doi.org/10.1002/adsu.202400538	journal	October 2024
Recent Progress of Electrochemical Production of Hydrogen Peroxide by Two‐Electron Oxygen Reduction Reaction Wang, Nan; Ma, Shaobo; Zuo, Pengjian Advanced Science, Vol. 8, Issue 15 https://doi.org/10.1002/advs.202100076	journal	May 2021
The Importance of the Macroscopic Geometry in Gas‐Phase Photocatalysis Matter, Fabian; Niederberger, Markus Advanced Science, Vol. 9, Issue 13 https://doi.org/10.1002/advs.202105363	journal	March 2022
Lattice Symmetry‐Guided Charge Transport in 2D Supramolecular Polymers Promotes Triplet Formation Emmanuele, Ruggero; Sai, Hiroaki; Chen, Jia‐Shiang Advanced Science, Vol. 11, Issue 30 https://doi.org/10.1002/advs.202402932	journal	June 2024
Controlling Photocatalytic Activity by Self‐Assembly – Tuning Perylene Bisimide Photocatalysts for the Hydrogen Evolution Reaction McDowall, Daniel; Greeves, Benjamin J.; Clowes, Rob Advanced Energy Materials, Vol. 10, Issue 46 https://doi.org/10.1002/aenm.202002469	journal	October 2020
Hydrogen Peroxide Synthesis: An Outlook beyond the Anthraquinone Process Campos-Martin, Jose M.; Blanco-Brieva, Gema; Fierro, Jose L. G. Angewandte Chemie International Edition, Vol. 45, Issue 42 https://doi.org/10.1002/anie.200503779	journal	October 2006
Highly Efficient Aerobic Oxidative Hydroxylation of Arylboronic Acids: Photoredox Catalysis Using Visible Light Zou, You-Quan; Chen, Jia-Rong; Liu, Xiao-Peng Angewandte Chemie International Edition, Vol. 51, Issue 3 https://doi.org/10.1002/anie.201107028	journal	December 2011
Dual‐Responsive Photocatalytic Polymer Nanogels Ferguson, Calum T. J.; Huber, Niklas; Landfester, Katharina Angewandte Chemie International Edition, Vol. 58, Issue 31 https://doi.org/10.1002/anie.201903309	journal	July 2019
Temperature‐ and pH‐Responsive Polymeric Photocatalysts for Enhanced Control and Recovery Li, Rong; Landfester, Katharina; Ferguson, Calum T. J. Angewandte Chemie International Edition, Vol. 61, Issue 51 https://doi.org/10.1002/anie.202211132	journal	November 2022
Heterocyclic Chromophore Amphiphiles and their Supramolecular Polymerization Đorđević, Luka; Sai, Hiroaki; Yang, Yang Angewandte Chemie International Edition, Vol. 62, Issue 17 https://doi.org/10.1002/anie.202214997	journal	March 2023
Tandem Proton Transfer in Carboxylated Supramolecular Polymer for Highly Efficient Overall Photosynthesis of Hydrogen Peroxide Zhang, Qiang; Che, Huinan; Yang, Hongbin Angewandte Chemie International Edition, Vol. 63, Issue 38 https://doi.org/10.1002/anie.202409328	journal	August 2024
Synthesis and Modification of Terrylenediimides as High-Performance Fluorescent Dyes Nolde, Fabian; Qu, Jianqiang; Kohl, Christopher Chemistry - A European Journal, Vol. 11, Issue 13 https://doi.org/10.1002/chem.200401177	journal	June 2005
Self‐Assembly Propensity Dictates Lifetimes in Transient Naphthalimide–Dipeptide Nanofibers Kumar, Mohit; Sementa, Deborah; Narang, Vishal Chemistry – A European Journal, Vol. 26, Issue 38 https://doi.org/10.1002/chem.202001008	journal	June 2020
Water‐Soluble Cationic Perylene Diimide Dyes as Stable Photocatalysts for H₂O₂ Evolution Gryszel, Maciej; Schlossarek, Tim; Würthner, Frank ChemPhotoChem, Vol. 7, Issue 9 https://doi.org/10.1002/cptc.202300070	journal	June 2023
Poly(N-isopropylacrylamide): experiment, theory and application Schild, H. G. Progress in Polymer Science, Vol. 17, Issue 2, p. 163-249 https://doi.org/10.1016/0079-6700(92)90023-R	journal	January 1992
Stimuli-responsive polymers: Biomedical applications and challenges for clinical translation Hoffman, Allan S. Advanced Drug Delivery Reviews, Vol. 65, Issue 1 https://doi.org/10.1016/j.addr.2012.11.004	journal	January 2013
Metallurgical alloy approach to two-dimensional supramolecular materials Dannenhoffer, Adam; Sai, Hiroaki; Bruckner, Eric P. Chem, Vol. 9, Issue 1 https://doi.org/10.1016/j.chempr.2022.09.026	journal	January 2023
Aggregation-Induced Emission: Together We Shine, United We Soar! Mei, Ju; Leung, Nelson L. C.; Kwok, Ryan T. K. Chemical Reviews, Vol. 115, Issue 21 https://doi.org/10.1021/acs.chemrev.5b00263	journal	October 2015
Superoxide Ion: Generation and Chemical Implications Hayyan, Maan; Hashim, Mohd Ali; AlNashef, Inas M. Chemical Reviews, Vol. 116, Issue 5 https://doi.org/10.1021/acs.chemrev.5b00407	journal	February 2016
Expanded Theory of H- and J-Molecular Aggregates: The Effects of Vibronic Coupling and Intermolecular Charge Transfer Hestand, Nicholas J.; Spano, Frank C. Chemical Reviews, Vol. 118, Issue 15 https://doi.org/10.1021/acs.chemrev.7b00581	journal	April 2018
The Belousov–Zhabotinsky Reaction in Thermoresponsive Core–Shell Hydrogel Microspheres with a Tris(2,2′-bipyridyl)ruthenium Catalyst in the Core Inui, Kohei; Watanabe, Takumi; Minato, Haruka The Journal of Physical Chemistry B, Vol. 124, Issue 18 https://doi.org/10.1021/acs.jpcb.0c02238	journal	April 2020
Dynamic Control of Photocatalytic Proton Reduction through the Mechanical Actuation of a Hydrogel Host Matrix Yang, Muwen; Xiong, Qinsi; Kodaimati, Mohamad S. The Journal of Physical Chemistry Letters, Vol. 12, Issue 50 https://doi.org/10.1021/acs.jpclett.1c03713	journal	December 2021
Growth of Extra-Large Chromophore Supramolecular Polymers for Enhanced Hydrogen Production Dannenhoffer, Adam J.; Sai, Hiroaki; Harutyunyan, Boris Nano Letters, Vol. 21, Issue 9 https://doi.org/10.1021/acs.nanolett.0c05024	journal	April 2021
Functional 1,8-Naphthalimide AIE/AIEEgens: Recent Advances and Prospects Gopikrishna, Peddaboodi; Meher, Niranjan; Iyer, Parameswar Krishnan ACS Applied Materials & Interfaces, Vol. 10, Issue 15 https://doi.org/10.1021/acsami.7b14473	journal	November 2017
Hybrid Nanocrystals of Small Molecules and Chemically Disordered Polymers Bruckner, Eric P.; Curk, Tine; Đorđević, Luka ACS Nano, Vol. 16, Issue 6 https://doi.org/10.1021/acsnano.2c00266	journal	May 2022
Two-Step Freezing Polymerization Method for Efficient Synthesis of High-Performance Stimuli-Responsive Hydrogels Liu, Jingwei; Fan, Xuhao; Tao, Yufeng ACS Omega, Vol. 5, Issue 11 https://doi.org/10.1021/acsomega.9b04224	journal	March 2020
How super is superoxide? Sawyer, Donald T.; Valentine, Joan S. Accounts of Chemical Research, Vol. 14, Issue 12 https://doi.org/10.1021/ar00072a005	journal	December 1981
Temperature-Driven Oxygenation Rate Control by Polymeric Photosensitizer Koizumi, Hisao; Shiraishi, Yasuhiro; Tojo, Sachiko Journal of the American Chemical Society, Vol. 128, Issue 27 https://doi.org/10.1021/ja062949c	journal	July 2006
Efficient Artificial Light-Harvesting System Based on Supramolecular Peptide Nanotubes in Water Song, Qiao; Goia, Sofia; Yang, Jie Journal of the American Chemical Society, Vol. 143, Issue 1 https://doi.org/10.1021/jacs.0c11060	journal	December 2020
A Donor–Acceptor [2]Catenane for Visible Light Photocatalysis Jiao, Yang; Đorđević, Luka; Mao, Haochuan Journal of the American Chemical Society, Vol. 143, Issue 21 https://doi.org/10.1021/jacs.1c01493	journal	May 2021
Photocatalytic Aqueous CO₂ Reduction to CO and CH₄ Sensitized by Ullazine Supramolecular Polymers Dumele, Oliver; Đorđević, Luka; Sai, Hiroaki Journal of the American Chemical Society, Vol. 144, Issue 7 https://doi.org/10.1021/jacs.1c12155	journal	February 2022
Ion Pair−π Interactions Fujisawa, Kaori; Humbert-Droz, Marie; Letrun, Romain Journal of the American Chemical Society, Vol. 137, Issue 34 https://doi.org/10.1021/jacs.5b05593	journal	August 2015
Intermolecular Structural Change for Thermoswitchable Polymeric Photosensitizer Park, Wooram; Park, Sin-Jung; Cho, Soojeong Journal of the American Chemical Society, Vol. 138, Issue 34 https://doi.org/10.1021/jacs.6b04875	journal	August 2016
Photophysical Properties of Intramolecular Charge-Transfer Excited Singlet State of Aminofluorenone Derivatives Yatsuhashi, Tomoyuki; Nakajima, Yuka; Shimada, Tetsuya The Journal of Physical Chemistry A, Vol. 102, Issue 18 https://doi.org/10.1021/jp980158u	journal	April 1998
Controlled growth factor release from synthetic extracellular matrices Lee, Kuen Yong; Peters, Martin C.; Anderson, Kenneth W. Nature, Vol. 408, Issue 6815 https://doi.org/10.1038/35050141	journal	December 2000
Self-assembling hydrogel scaffolds for photocatalytic hydrogen production Weingarten, Adam S.; Kazantsev, Roman V.; Palmer, Liam C. Nature Chemistry, Vol. 6, Issue 11 https://doi.org/10.1038/nchem.2075	journal	October 2014
Soft support for energy conversion Stolley, Ryan M.; Helm, Monte L. Nature Chemistry, Vol. 6, Issue 11 https://doi.org/10.1038/nchem.2088	journal	October 2014
Seawater usable for production and consumption of hydrogen peroxide as a solar fuel Mase, Kentaro; Yoneda, Masaki; Yamada, Yusuke Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms11470	journal	May 2016
A metal-free photocatalyst for highly efficient hydrogen peroxide photoproduction in real seawater Wu, Qingyao; Cao, Jingjing; Wang, Xiao Nature Communications, Vol. 12, Issue 1 https://doi.org/10.1038/s41467-020-20823-8	journal	January 2021
Charge-transfer regulated visible light driven photocatalytic H2 production and CO2 reduction in tetrathiafulvalene based coordination polymer gel Verma, Parul; Singh, Ashish; Rahimi, Faruk Ahamed Nature Communications, Vol. 12, Issue 1 https://doi.org/10.1038/s41467-021-27457-4	journal	December 2021
Photodriven quantum teleportation of an electron spin state in a covalent donor–acceptor–radical system Rugg, Brandon K.; Krzyaniak, Matthew D.; Phelan, Brian T. Nature Chemistry, Vol. 11, Issue 11 https://doi.org/10.1038/s41557-019-0332-8	journal	September 2019
Tailored self-assembled photocatalytic nanofibres for visible-light-driven hydrogen production Tian, Jia; Zhang, Yifan; Du, Lili Nature Chemistry, Vol. 12, Issue 12 https://doi.org/10.1038/s41557-020-00580-3	journal	November 2020
Multi-responsive hydrogel structures from patterned droplet networks Downs, Florence G.; Lunn, David J.; Booth, Michael J. Nature Chemistry, Vol. 12, Issue 4 https://doi.org/10.1038/s41557-020-0444-1	journal	March 2020
H2O2 generation from O2 and H2O on a near-infrared absorbing porphyrin supramolecular photocatalyst Zhang, Yaning; Pan, Chengsi; Bian, Gaoming Nature Energy, Vol. 8, Issue 4 https://doi.org/10.1038/s41560-023-01218-7	journal	March 2023
Resorcinol–formaldehyde resins as metal-free semiconductor photocatalysts for solar-to-hydrogen peroxide energy conversion Shiraishi, Yasuhiro; Takii, Takahiro; Hagi, Takumi Nature Materials, Vol. 18, Issue 9 https://doi.org/10.1038/s41563-019-0398-0	journal	July 2019
Viscoelastic surface electrode arrays to interface with viscoelastic tissues Tringides, Christina M.; Vachicouras, Nicolas; de Lázaro, Irene Nature Nanotechnology, Vol. 16, Issue 9 https://doi.org/10.1038/s41565-021-00926-z	journal	June 2021
Packing-induced selectivity switching in molecular nanoparticle photocatalysts for hydrogen and hydrogen peroxide production Yang, Haofan; Li, Chao; Liu, Tao Nature Nanotechnology, Vol. 18, Issue 3 https://doi.org/10.1038/s41565-022-01289-9	journal	January 2023
Fundamentals of double network hydrogels Chen, Qiang; Chen, Hong; Zhu, Lin Journal of Materials Chemistry B, Vol. 3, Issue 18 https://doi.org/10.1039/C5TB00123D	journal	January 2015
Direct local solvent probing by transient infrared spectroscopy reveals the mechanism of hydrogen-bond induced nonradiative deactivation Dereka, Bogdan; Vauthey, Eric Chemical Science, Vol. 8, Issue 7 https://doi.org/10.1039/C7SC00437K	journal	January 2017
Boosting photobioredox catalysis by morpholine electron donors under aerobic conditions Gonçalves, Leticia C. P.; Mansouri, Hamid R.; PourMehdi, Shadi Catalysis Science & Technology, Vol. 9, Issue 10 https://doi.org/10.1039/C9CY00496C	journal	January 2019
Universal quenching of common fluorescent probes by water and alcohols Maillard, Jimmy; Klehs, Kathrin; Rumble, Christopher Chemical Science, Vol. 12, Issue 4 https://doi.org/10.1039/D0SC05431C	journal	January 2021
The bionic sunflower: a bio-inspired autonomous light tracking photocatalytic system Qin, Jingjing; Chu, Kaibin; Huang, Yunpeng Energy & Environmental Science, Vol. 14, Issue 7 https://doi.org/10.1039/D1EE00587A	journal	January 2021
Recent developments in photocatalytic production of hydrogen peroxide Fang, Xiao; Huang, Xi; Hu, Qiyu Chemical Communications, Vol. 60, Issue 41 https://doi.org/10.1039/D4CC01577K	journal	January 2024
Self-assembled π-conjugated chromophores: preparation of one- and two-dimensional nanostructures and their use in photocatalysis Cappelletti, David; Barbieri, Marianna; Aliprandi, Alessandro Nanoscale, Vol. 16, Issue 19 https://doi.org/10.1039/D4NR00383G	journal	January 2024
Biopolymer-supramolecular polymer hybrids for photocatalytic hydrogen production Kupferberg, Jacob E.; Syrgiannis, Zois; Đorđević, Luka Soft Matter, Vol. 20, Issue 31 https://doi.org/10.1039/D4SM00373J	journal	January 2024
Colorimetric and fluorescent anion sensors: an overview of recent developments in the use of 1,8-naphthalimide-based chemosensors Duke, Rebecca M.; Veale, Emma B.; Pfeffer, Frederick M. Chemical Society Reviews, Vol. 39, Issue 10 https://doi.org/10.1039/b910560n	journal	January 2010
Fluorescence behaviour of 2-, 3- and 4-amino-1,8-naphthalimides: effects of the substitution positions of the amino functionality on the photophysical properties Wang, Lei; Fujii, Mayu; Yamaji, Minoru Photochemical & Photobiological Sciences, Vol. 17, Issue 10 https://doi.org/10.1039/c8pp00302e	journal	October 2018
Reactivity of HO ₂ /O ⁻ ₂ Radicals in Aqueous Solution Bielski, Benon H. J.; Cabelli, Diane E.; Arudi, Ravindra L. Journal of Physical and Chemical Reference Data, Vol. 14, Issue 4 https://doi.org/10.1063/1.555739	journal	October 1985
Detachment of affinity-captured bioparticles by elastic deformation of a macroporous hydrogel Dainiak, Maria B.; Kumar, Ashok; Galaev, Igor Yu. Proceedings of the National Academy of Sciences, Vol. 103, Issue 4 https://doi.org/10.1073/pnas.0508432103	journal	January 2006
Active scaffolds for on-demand drug and cell delivery Zhao, Xuanhe; Kim, Jaeyun; Cezar, Christine A. Proceedings of the National Academy of Sciences, Vol. 108, Issue 1 https://doi.org/10.1073/pnas.1007862108	journal	December 2010
A solar-to-chemical conversion efficiency up to 0.26% achieved in ambient conditions Ye, Yu-Xin; Pan, Jinhui; Shen, Yong Proceedings of the National Academy of Sciences, Vol. 118, Issue 46 https://doi.org/10.1073/pnas.2115666118	journal	November 2021
Stomatal control of photosynthesis and transpiration Jones, H. G. Journal of Experimental Botany, Vol. 49, Issue Special https://doi.org/10.1093/jxb/49.Special_Issue.387	journal	March 1998
Phototropism: Some History, Some Puzzles, and a Look Ahead Briggs, W. R. PLANT PHYSIOLOGY, Vol. 164, Issue 1 https://doi.org/10.1104/pp.113.230573	journal	January 2014
Plant-inspired TransfOrigami microfluidics Pan, Yi; Yang, Zhenyu; Li, Chang Science Advances, Vol. 8, Issue 18 https://doi.org/10.1126/sciadv.abo1719	journal	May 2022
Circadian regulation of sunflower heliotropism, floral orientation, and pollinator visits Atamian, Hagop S.; Creux, Nicky M.; Brown, Evan A. Science, Vol. 353, Issue 6299 https://doi.org/10.1126/science.aaf9793	journal	August 2016
Mechanisms for Leaf Control of Gas Exchange Mansfield, T. A.; Davies, W. J. BioScience, Vol. 35, Issue 3 https://doi.org/10.2307/1309865	journal	March 1985
Single-Metal-Atom Polymeric Unimolecular Micelles for Switchable Photocatalytic H ₂ Evolution Zuo, Quan; Feng, Kun; Zhong, Jun CCS Chemistry, Vol. 3, Issue 7 https://doi.org/10.31635/ccschem.020.202000486	journal	July 2021

Similar Records

Fast Photoactuation Driven by Supramolecular Polymers Integrated into Covalent Networks

Journal Article · 2024 · Advanced Functional Materials · OSTI ID:2479399

Cezan, S. Doruk; Li, Chuang; Kupferberg, Jacob; +5 more

Chromophore amphiphile–polyelectrolyte hybrid hydrogels for photocatalytic hydrogen production

Journal Article · 2019 · Journal of Materials Chemistry. A · OSTI ID:1822444

Sai, Hiroaki; Erbas, Aykut; Dannenhoffer, Adam; +8 more

Supramolecular–covalent hybrid polymers for light-activated mechanical actuation

Journal Article · 2020 · Nature Materials · OSTI ID:1798324

Li, Chuang; Iscen, Aysenur; Sai, Hiroaki; +7 more

Title: Mechanical and Light Activation of Materials for Chemical Production

Citation Formats

References (75)

Similar Records

Related Subjects