Title: Petrology and geochemistry of the Middle Pennsylvanian (Langsettian) Clintwood coalbed, Pike County, Kentucky

Journal Article · · International Journal of Coal Science & Technology

Abstract The Middle Pennsylvanian, Langsettian sub-stage Clintwood coal, along with its correlatives, was one of the more important energy resources in eastern Kentucky. The coal thickens from the NE-SW-trending Belfry anticline in central Pike County to the southeast, towards the Virginia-Kentucky border. Much of the thickness increase is in the bright lithotypes below a dull lithology. The bright lithologies transition from a bright clarain + vitrain + fusain lithology to a clarain + fusain lithology to the southeast. Half of the lithotypes in the three analyzed sections exceed 1000-µg/g Rare earth elements + Y + Sc (REYSc) (ash basis). The La N /Sm N vs. Gd N /Yb N and La N /Sm N vs. Ce N /Ce N * plots suggest that the top lithotype may have had best indication of an oxidizing environment. Positive Gd N /Gd N * and Eu N /Eu N * in some of the lithologies suggests that there may have been a hydrothermal influence in the sediment sources and/or in the diagenesis of the coal. Consideration of La N /Sm N and Zr (µg/g; ash basis), Zr vs. Sr, and V/Cr vs. inertinite/(inertinite + vitrinite) indicates that the dull lithotypes existed in a distinct geochemical environment compared to the brighter lithotypes. The isolation of the dull lithotypes from the bright lithotypes is supported by principal components analysis on inertinite/(inertinite + vitrinite), La N /Sm N , V/Cr, Sr, and either Zr or Ln(100(TiO 2 )/Al 2 O 3 ).

Sponsoring Organization:
USDOE
Grant/Contract Number:
FE0032054
OSTI ID:
2528120
Journal Information:
International Journal of Coal Science & Technology, Journal Name: International Journal of Coal Science & Technology Journal Issue: 1 Vol. 12; ISSN 2095-8293
Publisher:
Springer Science + Business MediaCopyright Statement
Country of Publication:
China
Language:
English

References (39)

Zirconium and hafnium in Bulgarian coals journal December 1987
Rare earth elements and yttrium in lithotypes of Bulgarian coals journal January 1987
A test for the analogy of tropical domed peat deposits to “dulling up” sequences in coal beds—Preliminary results journal January 1989
Rare earth elements in a sampled coal from the Pirin deposit, Bulgaria journal March 1987
Distributions and associations of selected trace elements in the lower Kittanning seam, western Pennsylvania, U.S.A. journal June 1991
Palynologic, petrographic and geochemical characteristics of the Manchester coal bed in Eastern Kentucky journal March 1995
Origin and significance of high nickel and chromium concentrations in Pliocene lignite of the Kosovo Basin, Serbia journal March 1996
Rare earth element-bearing coals from the Russian Far East deposits journal June 1996
Distribution of yttrium and rare-earth elements in the Penge and Kuruman iron-formations, Transvaal Supergroup, South Africa journal July 1996
The new inertinite classification (ICCP System 1994) journal March 2001
The new vitrinite classification (ICCP System 1994) journal April 1998
The organic geochemistry of coal: from plant materials to coal journal November 1997
Low-ash peat deposits from a dendritic, intermontane basin in the tropics: a new model for good quality coals journal May 2001
Aspects of the geochemistry of rare earth elements in coal: an experimental approach journal January 1999
Lanthanide, yttrium, and zirconium anomalies in the Fire Clay coal bed, Eastern Kentucky journal March 1999
Aspects of rare earth element enrichment in Central Appalachian coals journal September 2020
Rare earth element patterns: A tool for identifying trace metal sources during wetland soil reduction journal May 2011
Notes on the marginal enrichment of Germanium in coal beds journal December 2003
Estimations of Clarkes for Carbonaceous biolithes: World averages for trace element contents in black shales and coals journal April 2009
Coal deposits as potential alternative sources for lanthanides and yttrium journal May 2012
Mineralogical and geochemical anomalies of late Permian coals from the Fusui Coalfield, Guangxi Province, southern China: Influences of terrigenous materials and hydrothermal fluids journal January 2013
Factors controlling geochemical and mineralogical compositions of coals preserved within marine carbonate successions: A case study from the Heshan Coalfield, southern China journal April 2013
A review of anomalous rare earth elements and yttrium in coal journal April 2016
Classification of liptinite – ICCP System 1994 journal January 2017
Mineralogy of a rare earth element-rich Manchester coal lithotype, Clay County, Kentucky journal March 2020
Petrology, palynology, and geochemistry of the Pond Creek coal (Pennsylvanian, Duckmantian), Pike County, Kentucky: Overprints of penecontemporaneous tectonism and peat doming journal June 2022
Geochemistry of the Leatherwood coal in eastern Kentucky with an emphasis on enrichment and modes of occurrence of rare earth elements journal December 2023
Is hyperaccumulation a viable hypothesis for organic associations of minor elements in coals? journal July 2024
Metal loading effect on rare earth element binding to humic acid: Experimental and modelling evidence journal March 2010
Metalliferous coal deposits in East Asia (Primorye of Russia and South China): A review of geodynamic controls and styles of mineralization journal January 2016
Dynamic structure of humic substances: Rare earth elements as a fingerprint journal May 2010
Petrological, geochemical, and mineralogical compositions of the low-Ge coals from the Shengli Coalfield, China: A comparative study with Ge-rich coals and a formation model for coal-hosted Ge ore deposit journal December 2015
Enrichment of U-Re-V-Cr-Se and rare earth elements in the Late Permian coals of the Moxinpo Coalfield, Chongqing, China: Genetic implications from geochemical and mineralogical data journal January 2017
Anomalies of rare metals in Lopingian super-high-organic-sulfur coals from the Yishan Coalfield, Guangxi, China journal August 2017
Minor Element Distribution in Coal Samples of the Interior Coal Province book January 1966
Hydrothermal Mobilisation of the Rare Earth Elements - a Tale of "Ceria" and "Yttria" journal October 2012
Analysis of Rare Earth Elements in Geologic Samples using Inductively Coupled Plasma Mass Spectrometry; US DOE Topical Report - DOE/NETL-2016/1794 report April 2016
Geologic map of the Belfry Quadrangle, Pike County, Kentucky report January 1976
Rare Earth Elements: Their Importance in Understanding Soil Genesis journal May 2012