Water‐Induced Modulation of Bipolaron Formation in N-type Polymeric Mixed Conductors

Surgailis, Jokūbas; Nayak, Prem D.; Flagg, Lucas Q.; Kousseff, Christina J.; McCulloch, Iain; Richter, Lee J.; Inal, Sahika

doi:10.1016/j.mser.2025.100944

Title: Water‐Induced Modulation of Bipolaron Formation in N-type Polymeric Mixed Conductors

Journal Article · 31 March 2025 · Materials Science and Engineering. R, Reports

DOI: https://doi.org/10.1016/j.mser.2025.100944 · OSTI ID:2528116

; Nayak, Prem D.;

;

; McCulloch, Iain; Richter, Lee J.; Inal, Sahika

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Sponsoring Organization:: USDOE

Grant/Contract Number:: SC0012704

OSTI ID:: 2528116

Journal Information:: Materials Science and Engineering. R, Reports, Journal Name: Materials Science and Engineering. R, Reports Journal Issue: C Vol. 163; ISSN 0927-796X

Publisher:: ElsevierCopyright Statement

Country of Publication:: Netherlands

Language:: English

References (44)

Synthesis, Electronic Structure, and Charge Transport Characteristics of Naphthalenediimide-Based Co-Polymers with Different Oligothiophene Donor Units Luzio, Alessandro; Fazzi, Daniele; Natali, Dario Advanced Functional Materials, Vol. 24, Issue 8 https://doi.org/10.1002/adfm.201302297	journal	October 2013
Balancing Ionic and Electronic Conduction for High‐Performance Organic Electrochemical Transistors Savva, Achilleas; Hallani, Rawad; Cendra, Camila Advanced Functional Materials, Vol. 30, Issue 11 https://doi.org/10.1002/adfm.201907657	journal	January 2020
Single‐Material OECT‐Based Flexible Complementary Circuits Featuring Polyaniline in Both Conducting Channels Travaglini, Lorenzo; Micolich, Adam P.; Cazorla, Claudio Advanced Functional Materials, Vol. 31, Issue 4 https://doi.org/10.1002/adfm.202007205	journal	October 2020
Mixed Conduction in an N‐Type Organic Semiconductor in the Absence of Hydrophilic Side‐Chains Surgailis, Jokubas; Savva, Achilleas; Druet, Victor Advanced Functional Materials, Vol. 31, Issue 21 https://doi.org/10.1002/adfm.202010165	journal	March 2021
All‐Solid‐State Vertical Three‐Terminal N‐Type Organic Synaptic Devices for Neuromorphic Computing Xie, Zhichao; Zhuge, Chenyu; Zhao, Yanfei Advanced Functional Materials, Vol. 32, Issue 21 https://doi.org/10.1002/adfm.202107314	journal	February 2022
Direct Measurement of Ion Mobility in a Conducting Polymer Stavrinidou, Eleni; Leleux, Pierre; Rajaona, Harizo Advanced Materials, Vol. 25, Issue 32 https://doi.org/10.1002/adma.201301240	journal	June 2013
Mixed Ionic–Electronic Conduction, a Multifunctional Property in Organic Conductors Tan, Siew Ting Melissa; Gumyusenge, Aristide; Quill, Tyler James Advanced Materials, Vol. 34, Issue 21 https://doi.org/10.1002/adma.202110406	journal	April 2022
Impact of Side‐Chain Hydrophilicity on Packing, Swelling, and Ion Interactions in Oxy‐Bithiophene Semiconductors Siemons, Nicholas; Pearce, Drew; Cendra, Camila Advanced Materials, Vol. 34, Issue 39 https://doi.org/10.1002/adma.202204258	journal	August 2022
Charge Carrier Induced Structural Ordering And Disordering in Organic Mixed Ionic Electronic Conductors Quill, Tyler J.; LeCroy, Garrett; Marks, Adam Advanced Materials, Vol. 36, Issue 15 https://doi.org/10.1002/adma.202310157	journal	January 2024
The Role of Side Chains and Hydration on Mixed Charge Transport in n‐Type Polymer Films Surgailis, Jokūbas; Flagg, Lucas Q.; Richter, Lee J. Advanced Materials https://doi.org/10.1002/adma.202313121	journal	April 2024
Low‐Power/High‐Gain Flexible Complementary Circuits Based on Printed Organic Electrochemical Transistors Yang, Chi‐Yuan; Tu, Deyu; Ruoko, Tero‐Petri Advanced Electronic Materials, Vol. 8, Issue 3 https://doi.org/10.1002/aelm.202100907	journal	December 2021
Operation Mechanism of n‐Type Organic Electronic Metabolite Sensors Druet, Victor; Nayak, Prem D.; Koklu, Anil Advanced Electronic Materials, Vol. 8, Issue 10 https://doi.org/10.1002/aelm.202200065	journal	June 2022
Insight into the properties and redox states of n-dopable conjugated polymers based on naphtalene diimide units Ledwon, Przemyslaw; Ovsiannikova, Daria; Jarosz, Tomasz Electrochimica Acta, Vol. 307 https://doi.org/10.1016/j.electacta.2019.03.169	journal	June 2019
Organic mixed conductors for electrochemical transistors Tropp, Joshua; Meli, Dilara; Rivnay, Jonathan Matter, Vol. 6, Issue 10 https://doi.org/10.1016/j.matt.2023.05.001	journal	October 2023
Fluorene based electrochromic conjugated polymers: A review Bezgin Carbas, Buket Polymer, Vol. 254 https://doi.org/10.1016/j.polymer.2022.125040	journal	July 2022
Microfluidics integrated n-type organic electrochemical transistor for metabolite sensing Koklu, Anil; Ohayon, David; Wustoni, Shofarul Sensors and Actuators B: Chemical, Vol. 329 https://doi.org/10.1016/j.snb.2020.129251	journal	February 2021
Conjugated Polymers in Bioelectronics Inal, Sahika; Rivnay, Jonathan; Suiu, Andreea-Otilia Accounts of Chemical Research, Vol. 51, Issue 6 https://doi.org/10.1021/acs.accounts.7b00624	journal	May 2018
Resonant X-ray Diffraction Reveals the Location of Counterions in Doped Organic Mixed Ionic Conductors Flagg, Lucas Q.; Onorato, Jonathan W.; Luscombe, Christine K. Chemistry of Materials, Vol. 35, Issue 10 https://doi.org/10.1021/acs.chemmater.3c00180	journal	May 2023
Crystallinity Determines Ion Injection Kinetics and Local Ion Density in Organic Mixed Conductors Jackson, Seth R.; Kingsford, Rand L.; Collins, Garrett W. Chemistry of Materials, Vol. 35, Issue 14 https://doi.org/10.1021/acs.chemmater.3c00657	journal	July 2023
The Role of the Side Chain on the Performance of N-type Conjugated Polymers in Aqueous Electrolytes Giovannitti, Alexander; Maria, Iuliana P.; Hanifi, David Chemistry of Materials, Vol. 30, Issue 9 https://doi.org/10.1021/acs.chemmater.8b00321	journal	April 2018
Influence of Water on the Performance of Organic Electrochemical Transistors Savva, Achilleas; Cendra, Camila; Giugni, Andrea Chemistry of Materials, Vol. 31, Issue 3 https://doi.org/10.1021/acs.chemmater.8b04335	journal	January 2019
From Isotropic to Anisotropic Conductivities in P(NDI2OD-T₂) by (Electro-)Chemical Doping Strategies Gross, Yannic M.; Trefz, Daniel; Dingler, Carsten Chemistry of Materials, Vol. 31, Issue 9 https://doi.org/10.1021/acs.chemmater.9b00977	journal	April 2019
Electrochemical Investigations of the N-Type Semiconducting Polymer P(NDI2OD-T2) and Its Monomer: New Insights in the Reduction Behavior Trefz, Daniel; Ruff, Adrian; Tkachov, Roman The Journal of Physical Chemistry C, Vol. 119, Issue 40 https://doi.org/10.1021/acs.jpcc.5b05756	journal	September 2015
High Performance, Flexible, and Thermally Stable All-Solid-State Organic Electrochemical Transistor Based on Thermoplastic Polyurethane Ion Gel Hou, Kunqi; Chen, Shuai; Moudgil, Akshay ACS Applied Electronic Materials, Vol. 5, Issue 4 https://doi.org/10.1021/acsaelm.3c00091	journal	April 2023
Efficient n-Type Small-Molecule Mixed Ion-Electron Conductors and Application in Hydrogen Peroxide Sensors Liao, Hailiang; Chen, Junxin; Lan, Liuyuan ACS Applied Materials & Interfaces, Vol. 14, Issue 14 https://doi.org/10.1021/acsami.1c24267	journal	March 2022
Polarons, Bipolarons, And Absorption Spectroscopy of PEDOT Zozoulenko, Igor; Singh, Amritpal; Singh, Sandeep Kumar ACS Applied Polymer Materials, Vol. 1, Issue 1 https://doi.org/10.1021/acsapm.8b00061	journal	December 2018
Redox-Active Polymers Designed for the Circular Economy of Energy Storage Devices Tan, Siew Ting Melissa; Quill, Tyler J.; Moser, Maximilian ACS Energy Letters, Vol. 6, Issue 10 https://doi.org/10.1021/acsenergylett.1c01625	journal	September 2021
Microfluidic Integrated Organic Electrochemical Transistor with a Nanoporous Membrane for Amyloid-β Detection Koklu, Anil; Wustoni, Shofarul; Musteata, Valentina-Elena ACS Nano, Vol. 15, Issue 5 https://doi.org/10.1021/acsnano.0c09893	journal	March 2021
Reversible Electrochemical Charging of n-Type Conjugated Polymer Electrodes in Aqueous Electrolytes Szumska, Anna A.; Maria, Iuliana P.; Flagg, Lucas Q. Journal of the American Chemical Society, Vol. 143, Issue 36 https://doi.org/10.1021/jacs.1c06713	journal	September 2021
A single n-type semiconducting polymer-based photo-electrochemical transistor Druet, Victor; Ohayon, David; Petoukhoff, Christopher E. Nature Communications, Vol. 14, Issue 1 https://doi.org/10.1038/s41467-023-41313-7	journal	September 2023
Organic mixed ionic–electronic conductors Paulsen, Bryan D.; Tybrandt, Klas; Stavrinidou, Eleni Nature Materials, Vol. 19, Issue 1 https://doi.org/10.1038/s41563-019-0435-z	journal	August 2019
Organic mixed conductors for bioinspired electronics Gkoupidenis, P.; Zhang, Y.; Kleemann, H. Nature Reviews Materials, Vol. 9, Issue 2 https://doi.org/10.1038/s41578-023-00622-5	journal	December 2023
A solution-processed n-type conducting polymer with ultrahigh conductivity Tang, Haoran; Liang, Yuanying; Liu, Chunchen Nature, Vol. 611, Issue 7935 https://doi.org/10.1038/s41586-022-05295-8	journal	September 2022
Vertical organic electrochemical transistors for complementary circuits Huang, Wei; Chen, Jianhua; Yao, Yao Nature, Vol. 613, Issue 7944 https://doi.org/10.1038/s41586-022-05592-2	journal	January 2023
An organic electrochemical transistor for multi-modal sensing, memory and processing Wang, Shijie; Chen, Xi; Zhao, Chao Nature Electronics, Vol. 6, Issue 4 https://doi.org/10.1038/s41928-023-00950-y	journal	April 2023
Design and evaluation of conjugated polymers with polar side chains as electrode materials for electrochemical energy storage in aqueous electrolytes Moia, Davide; Giovannitti, Alexander; Szumska, Anna A. Energy & Environmental Science, Vol. 12, Issue 4 https://doi.org/10.1039/C8EE03518K	journal	January 2019
n-Type organic semiconducting polymers: stability limitations, design considerations and applications Griggs, Sophie; Marks, Adam; Bristow, Helen Journal of Materials Chemistry C, Vol. 9, Issue 26 https://doi.org/10.1039/D1TC02048J	journal	January 2021
Impact of varying side chain structure on organic electrochemical transistor performance: a series of oligoethylene glycol-substituted polythiophenes Chen, Shinya E.; Flagg, Lucas Q.; Onorato, Jonathan W. Journal of Materials Chemistry A, Vol. 10, Issue 19 https://doi.org/10.1039/D2TA00683A	journal	January 2022
Origins of hydrogen peroxide selectivity during oxygen reduction on organic mixed ionic–electronic conducting polymers De La Fuente Durán, Ana; Liang, Allen Yu-Lun; Denti, Ilaria Energy & Environmental Science, Vol. 16, Issue 11 https://doi.org/10.1039/D3EE02102E	journal	January 2023
Stable organic electrochemical neurons based on p-type and n-type ladder polymers Wu, Han-Yan; Huang, Jun-Da; Jeong, Sang Young Materials Horizons, Vol. 10, Issue 10 https://doi.org/10.1039/D3MH00858D	journal	January 2023
On the fundamentals of organic mixed ionic/electronic conductors Fabiano, Simone; Flagg, Lucas; Hidalgo Castillo, Tania C. Journal of Materials Chemistry C, Vol. 11, Issue 42 https://doi.org/10.1039/D3TC03058J	journal	January 2023
Controlling swelling in mixed transport polymers through alkyl side-chain physical cross-linking Siemons, Nicholas; Pearce, Drew; Yu, Hang Proceedings of the National Academy of Sciences, Vol. 120, Issue 35 https://doi.org/10.1073/pnas.2306272120	journal	August 2023
Direct metabolite detection with an n-type accumulation mode organic electrochemical transistor Pappa, Anna Maria; Ohayon, David; Giovannitti, Alexander Science Advances, Vol. 4, Issue 6 https://doi.org/10.1126/sciadv.aat0911	journal	June 2018
Electronic, Ionic, and Mixed Conduction in Polymeric Systems Thomas, Elayne M.; Nguyen, Phong H.; Jones, Seamus D. Annual Review of Materials Research, Vol. 51, Issue 1 https://doi.org/10.1146/annurev-matsci-080619-110405	journal	July 2021

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