A Systematic Study on Enhancing Curing Times and Thermomechanical Properties of SYLGARD™ 186

Journal Article · 03 March 2025 · Results in Materials

DOI: https://doi.org/10.1016/j.rinma.2025.100681 · OSTI ID:2526272

Stockdale, John Robert  ^[1]; Adhikari, Santosh  ^[1]; Torres, Xavier Malachi  ^[1]; Pacheco, Adam ^[1]; Legett, Shelbie Annette  ^[1]; Labouriau, Andrea  ^[1]

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1. Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

Sylgard 186 is a versatile polydimethylsiloxane (PDMS) elastomer that is cured via a hydrosilylation reaction. Its room temperature curing time is long, leaving much to be desired in terms of application timeframe. Curing the resin at higher temperatures overcomes this problem, but mechanical properties of the cured elastomer tend to deteriorate. Thus, the present work evaluated chemical modifications to the standard Sylgard 186 with the goal to decrease room temperature curing time while maintaining or improving thermomechanical properties. A modified Sylgard 186 formulation that combines the base component of Sylgard 186 with the curing agent of Sylgard 184 in a 30:1 ratio is introduced. The modified Sylgard 186 elastomer displays, after 4 hours of curing at 25 ºC, Shore A hardness of 29.5 ± 2.8. These results point to a new, readily available, fast curing Sylgard 186 formulation that has the potential to aid in a wide range of applications including potting within microelectronics, mechanobiology, and aerospace components.

• Research Organization: Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
• Sponsoring Organization: USDOE National Nuclear Security Administration (NNSA)
• Grant/Contract Number: 89233218CNA000001
• OSTI ID: 2526272
• Report Number(s): LA-UR--24-22536
• Journal Information: Results in Materials, Journal Name: Results in Materials Vol. 26; ISSN 2590-048X
• Publisher: ElsevierCopyright Statement
• Country of Publication: United States
• Language: English