Microwave-assisted intercalation: exploring electronic and structural features of metastable MMo 6 S 8 (M = Ag, Sn)

Smiley, Rose E.; Mason, Konstantina G.; Lam, Rose A.; Giem, Alice; Ingargiola, Daniella; Wuille Bille, Brian A.; Prendergast, David; Velázquez, Jesús M.

doi:10.1039/D4MA01090F

Title: Microwave-assisted intercalation: exploring electronic and structural features of metastable MMo ₆ S ₈ (M = Ag, Sn)

Journal Article · 17 March 2025 · Materials Advances

DOI: https://doi.org/10.1039/D4MA01090F · OSTI ID:2526270

Smiley, Rose E. ^[1]; Mason, Konstantina G. ^[1]; Lam, Rose A. ^[1];

^[2]; Ingargiola, Daniella ^[1]; Wuille Bille, Brian A. ^[3];

^[4];

^[1]

Department of Chemistry, University of California, One Shields Ave, Davis, California, 95616, USA
Department of Chemistry, Texas A&M University, College Station, TC 77843, USA
Department of Inorganic Spectroscopy, Max Planck Institute for Chemical Energy Conversion, Müheim an der Ruhur, 45470, Germany
Molecular Foundry, Lawrence Berkley National Laboratory, Berkeley, California, 94720, USA

This study presents a facile method to synthesize Type I Chevrel phases and utilizes X-ray absorption spectroscopy to reveal how intercalant identity can modify charge transfer and cluster anisotropy.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-76SF00515; SC0012704; AC02-05CH11231

OSTI ID:: 2526270

Journal Information:: Materials Advances, Journal Name: Materials Advances Journal Issue: 6 Vol. 6; ISSN MAADC9; ISSN 2633-5409

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

References (44)

Resolving Oxidation States and X–site Composition of Sn Perovskites through Auger Parameter Analysis in XPS Wieczorek, Alexander; Lai, Huagui; Pious, Johnpaul Advanced Materials Interfaces, Vol. 10, Issue 7 https://doi.org/10.1002/admi.202201828	journal	December 2022
Magnetic susceptibility observation of removing oxygen from some Chevrel compounds Wright, W. H.; Ginsberg, D. M. Journal of Low Temperature Physics, Vol. 64, Issue 1-2 https://doi.org/10.1007/BF00681543	journal	July 1986
The effects of tungsten doping on the tin Chevrel-phase compound SnMo6S8 Wright, W. H.; Ginsberg, D. M. Journal of Low Temperature Physics, Vol. 69, Issue 3-4 https://doi.org/10.1007/BF00682657	journal	November 1987
A review on the problems of the solid state ions diffusion in cathodes for rechargeable Mg batteries Levi, E.; Levi, M. D.; Chasid, O. Journal of Electroceramics, Vol. 22, Issue 1-3 https://doi.org/10.1007/s10832-007-9370-5	journal	December 2007
Hydrodesulfurization catalysis by Chevrel phase compounds Mccarty, K. Journal of Catalysis, Vol. 93, Issue 2 https://doi.org/10.1016/0021-9517(85)90185-X	journal	June 1985
Reduced molybdenum formal oxidation states in hydrodesulfurization catalysis by Chevrel phases Ekman, M. Journal of Catalysis, Vol. 117, Issue 1 https://doi.org/10.1016/0021-9517(89)90234-0	journal	May 1989
Stoichiometry and physical properties of ternary molybdenum chalcogenides MxMo6X8 (X = S, Se; M = Li, Sn, Pb) Tarascon, J. M.; Disalvo, F. J.; Murphy, D. W. Journal of Solid State Chemistry, Vol. 54, Issue 2 https://doi.org/10.1016/0022-4596(84)90147-6	journal	September 1984
The structure of SnMo6S8 and the superconducting properties of the series SnxMo6S8 and MySnxMo6S8 (M  La, Ce, Pr, Eu, Gd, Ho, Lu, Y, In, U) Chevrel, R.; Rossel, C.; Sergent, M. Journal of the Less Common Metals, Vol. 72, Issue 1 https://doi.org/10.1016/0022-5088(80)90250-7	journal	July 1980
Crystallography of mixed Chevrel phases Fradin, F. Y.; Downey, J. W. Materials Research Bulletin, Vol. 14, Issue 12 https://doi.org/10.1016/0025-5408(72)90221-8	journal	December 1979
Speciation of sulfur in humic and fulvic acids using X-ray absorption near-edge structure (XANES) spectroscopy Morra, Matthew J.; Fendorf, Scott E.; Brown, Paul D. Geochimica et Cosmochimica Acta, Vol. 61, Issue 3 https://doi.org/10.1016/S0016-7037(97)00003-3	journal	February 1997
Thermoelectric properties of MxMo6Te8 (M=Ag, Cu) Shi, Xiao-ya; Wang, Li; Chen, Li-dong Transactions of Nonferrous Metals Society of China, Vol. 19, Issue 3 https://doi.org/10.1016/S1003-6326(08)60326-X	journal	June 2009
Structure–reactivity relationships in Chevrel phase electrocatalysts for small-molecule reduction reactions Ortiz-Rodríguez, Jessica C.; Velázquez, Jesús M. Current Opinion in Electrochemistry, Vol. 34 https://doi.org/10.1016/j.coelec.2022.101002	journal	August 2022
Molybdenum X-ray absorption edges from 200 to 20,000eV: The benefits of soft X-ray spectroscopy for chemical speciation George, Simon J.; Drury, Owen B.; Fu, Juxia Journal of Inorganic Biochemistry, Vol. 103, Issue 2 https://doi.org/10.1016/j.jinorgbio.2008.09.008	journal	February 2009
Sulfur K-edge XANES of lazurite: Toward determining the provenance of lapis lazuli Gambardella, Alessa A.; Schmidt Patterson, Catherine M.; Webb, Samuel M. Microchemical Journal, Vol. 125 https://doi.org/10.1016/j.microc.2015.11.030	journal	March 2016
A Synergistic Approach to Unraveling the Thermodynamic Stability of Binary and Ternary Chevrel Phase Sulfides Lilova, Kristina; Perryman, Joseph T.; Singstock, Nicholas R. Chemistry of Materials, Vol. 32, Issue 16 https://doi.org/10.1021/acs.chemmater.0c02648	journal	July 2020
Design Principles for Multinary Metal Chalcogenides: Toward Programmable Reactivity in Energy Conversion Perryman, Joseph T.; Velázquez, Jesús M. Chemistry of Materials, Vol. 33, Issue 18 https://doi.org/10.1021/acs.chemmater.1c01983	journal	September 2021
Multivalent Ion Conduction in Inorganic Solids Iton, Zachery W. B.; See, Kimberly A. Chemistry of Materials, Vol. 34, Issue 3 https://doi.org/10.1021/acs.chemmater.1c04178	journal	January 2022
Charge Transport Dynamics in Microwave Synthesized One-Dimensional Molybdenum Chalcogenides Ortiz-Rodríguez, Jessica C.; Perryman, Joseph T.; Velázquez, Jesús M. Industrial & Engineering Chemistry Research, Vol. 60, Issue 45 https://doi.org/10.1021/acs.iecr.1c02825	journal	November 2021
Charge Transfer Mechanism into the Chevrel Phase Mo₆S₈ during Mg Intercalation Richard, J.; Benayad, A.; Colin, J. -F. The Journal of Physical Chemistry C, Vol. 121, Issue 32 https://doi.org/10.1021/acs.jpcc.7b03979	journal	August 2017
Charge Distribution on S and Intercluster Bond Evolution in Mo ₆ S ₈ during the Electrochemical Insertion of Small Cations Studied by X-ray Absorption Spectroscopy Yu, Pengfei; Long, Xinghui; Zhang, Nian The Journal of Physical Chemistry Letters, Vol. 10, Issue 6 https://doi.org/10.1021/acs.jpclett.8b03622	journal	February 2019
Intercalated Chevrel Phase Mo ₆ S ₈ as a Janus Material for Energy Generation and Storage Agiorgousis, Michael L.; Sun, Yi-Yang; West, Damien ACS Applied Energy Materials, Vol. 1, Issue 2 https://doi.org/10.1021/acsaem.7b00092	journal	February 2018
Stabilizing Hydrogen Adsorption through Theory-Guided Chalcogen Substitution in Chevrel-Phase Mo ₆ X ₈ (X=S, Se, Te) Electrocatalysts Ortiz-Rodríguez, Jessica C.; Singstock, Nicholas R.; Perryman, Joseph T. ACS Applied Materials & Interfaces, Vol. 12, Issue 32 https://doi.org/10.1021/acsami.0c07207	journal	July 2020
Chevrel Phases, M _x Mo ₆ T ₈ (M = Metals, T = S, Se, Te) as a Structural Chameleon: Changes in the Rhombohedral Framework and Triclinic Distortion Levi, Elena; Aurbach, Doron Chemistry of Materials, Vol. 22, Issue 12 https://doi.org/10.1021/cm100422z	journal	May 2010
New Insight on the Unusually High Ionic Mobility in Chevrel Phases Levi, E.; Gershinsky, G.; Aurbach, D. Chemistry of Materials, Vol. 21, Issue 7 https://doi.org/10.1021/cm900033v	journal	April 2009
Sulfur Speciation in Soil by S K -Edge XANES Spectroscopy: Comparison of Spectral Deconvolution and Linear Combination Fitting Prietzel, Jörg; Botzaki, Anna; Tyufekchieva, Nora Environmental Science & Technology, Vol. 45, Issue 7 https://doi.org/10.1021/es102180a	journal	April 2011
Hydrodesulfurization by reduced molybdenum sulfides: activity and selectivity of Chevrel phase catalysts McCarty, Kevin F.; Schrader, Glenn L. Industrial & Engineering Chemistry Product Research and Development, Vol. 23, Issue 4 https://doi.org/10.1021/i300016a002	journal	December 1984
Effect of chalcogen nonstoichiometry on superconductivity in Chevrel-phase tin molybdenum sulfides Delk, Frank S.; Sienko, M. J. Inorganic Chemistry, Vol. 19, Issue 3 https://doi.org/10.1021/ic50205a046	journal	March 1980
Crystallography of Chevrel Phases, MMo ₆ T ₈ (M = Cd, Na, Mn, and Zn, T = S, Se) and Their Cation Mobility Levi, E.; Gershinsky, G.; Aurbach, D. Inorganic Chemistry, Vol. 48, Issue 18 https://doi.org/10.1021/ic900805g	journal	August 2009
Molybdenum chalcogenides: clusters, chains, and extended solids. The approach to bonding in three dimensions Hughbanks, Timothy; Hoffmann, Roald Journal of the American Chemical Society, Vol. 105, Issue 5 https://doi.org/10.1021/ja00343a014	journal	March 1983
Machine Learning Guided Synthesis of Multinary Chevrel Phase Chalcogenides Singstock, Nicholas R.; Ortiz-Rodríguez, Jessica C.; Perryman, Joseph T. Journal of the American Chemical Society, Vol. 143, Issue 24 https://doi.org/10.1021/jacs.1c02971	journal	June 2021
How the Bioinspired Fe₂Mo₆S₈ Chevrel Breaks Electrocatalytic Nitrogen Reduction Scaling Relations Singstock, Nicholas R.; Musgrave, Charles B. Journal of the American Chemical Society, Vol. 144, Issue 28 https://doi.org/10.1021/jacs.2c03661	journal	July 2022
Spectroscopic Evidence for Ag(III) in Highly Oxidized Silver Films by X-ray Photoelectron Spectroscopy Kaspar, Tiffany C.; Droubay, Tim; Chambers, Scott A. The Journal of Physical Chemistry C, Vol. 114, Issue 49 https://doi.org/10.1021/jp107914e	journal	November 2010
Use of XPS method in determination of chemical environment and oxidation state of sulfur and silver atoms in Ag₆S₃O₄and Ag₈S₄O₄compounds Tomaszewicz, E.; Kurzawa, M. Journal of Materials Science, Vol. 39, Issue 6 https://doi.org/10.1023/B:JMSC.0000017783.47669.4e	journal	March 2004
Re-examining the Chevrel phase Mo ₆ S ₈ cathode for Mg intercalation from an electronic structure perspective Thöle, Florian; Wan, Liwen F.; Prendergast, David Physical Chemistry Chemical Physics, Vol. 17, Issue 35 https://doi.org/10.1039/C5CP03046C	journal	January 2015
Revealing electronic structure changes in Chevrel phase cathodes upon Mg insertion using X-ray absorption spectroscopy Wan, Liwen F.; Wright, Joshua; Perdue, Brian R. Physical Chemistry Chemical Physics, Vol. 18, Issue 26 https://doi.org/10.1039/C6CP02412B	journal	January 2016
Metal-promoted Mo ₆ S ₈ clusters: a platform for probing ensemble effects on the electrochemical conversion of CO ₂ and CO to methanol Perryman, Joseph T.; Ortiz-Rodríguez, Jessica C.; Jude, Joshua W. Materials Horizons, Vol. 7, Issue 1 https://doi.org/10.1039/C9MH00745H	journal	January 2020
Direct solid-state nucleation and charge-transport dynamics of alkali metal-intercalated M₂Mo₆S₆ (M = K, Rb, Cs) nanorods Perryman, Joseph T.; Kulkarni, Ambarish R.; Velázquez, Jesús M. Journal of Materials Chemistry C, Vol. 8, Issue 31 https://doi.org/10.1039/D0TC01674H	journal	January 2020
X-ray absorption spectroscopy insights on the structure anisotropy and charge transfer in Chevrel Phase chalcogenides Hyler, Forrest P.; Wuille Bille, Brian A.; Ortíz-Rodríguez, Jessica C. Physical Chemistry Chemical Physics, Vol. 24, Issue 28, p. 17289-17294 https://doi.org/10.1039/D1CP04851A	journal	July 2022
Electrochemical control over stoichiometry via cation intercalation into Chevrel-phase sulphides (Cu_xMo₆S₈, x = 1–3) Ritter, Kabian A.; Mason, Konstantina G.; Yew, Suxuen Journal of Materials Chemistry A, Vol. 12, Issue 12 https://doi.org/10.1039/D3TA07333E	journal	January 2024
Effect of oxygen impurities on properties of the ternary superconductorSnMo6S8: Extended x-ray-absorption fine-structure determination of bond distances and local-density cluster calculations Guenzburger, Diana; Ellis, D. E.; Montano, P. A. Physical Review B, Vol. 32, Issue 7 https://doi.org/10.1103/PhysRevB.32.4398	journal	October 1985
Multiband Superconductivity in the Chevrel Phases SnMo 6 S 8 and PbMo 6 S 8 Petrović, A. P.; Lortz, R.; Santi, G. Physical Review Letters, Vol. 106, Issue 1 https://doi.org/10.1103/PhysRevLett.106.017003	journal	January 2011
Lattice Softening and Anisotropy atSn119Sites in SnMo6S8 Kimball, C. W.; Weber, L.; Van Landuyt, G. Physical Review Letters, Vol. 36, Issue 8 https://doi.org/10.1103/PhysRevLett.36.412	journal	February 1976
Rechargeable Lithium Batteries Based on the Ternary Chevrel Phase AgMo6 S 8 as the Cathode Tarascon, J. M.; Orlando, T. P.; Neal, M. J. Journal of The Electrochemical Society, Vol. 135, Issue 4 https://doi.org/10.1149/1.2095779	journal	April 1988
Thermoelectric Properties of Chevrel-Type Sulfides AMo6S8. (A = Fe, Ni, Ag, Zn, Sn, Pb, Cu). Tsubota, Toshiki; Ohtaki, Michitaka; Eguchi, Koichi Journal of the Ceramic Society of Japan, Vol. 107, Issue 1248 https://doi.org/10.2109/jcersj.107.697	journal	January 1999

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Title: Microwave-assisted intercalation: exploring electronic and structural features of metastable MMo ₆ S ₈ (M = Ag, Sn)