Photo-ejected ligands hyperpolarized by parahydrogen in reversible exchange

Brown, Emily E.; Harrison, Rielly J.; Havrylyuk, Dmytro; McBride, Stephen J.; Glazer, Edith C.; Castellano, Felix N.; Theis, Thomas

doi:10.1039/D4CC06807F

Title: Photo-ejected ligands hyperpolarized by parahydrogen in reversible exchange

Journal Article · 19 March 2025 · ChemComm

DOI: https://doi.org/10.1039/D4CC06807F · OSTI ID:2524097

^[1]; Harrison, Rielly J. ^[1]; Havrylyuk, Dmytro ^[1];

^[1];

^[1]

Department of Chemistry, North Carolina State University, Raleigh, North Carolina 27965-8204, USA

Hyperpolarization derived from signal amplification by reversible exchange (SABRE) is a catalytic approach to enhance NMR detection. Here, we introduce light-triggered ejection of heterocyclic ligands to initiate the SABRE process.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: SC0023334; SC0025315

OSTI ID:: 2524097

Journal Information:: ChemComm, Journal Name: ChemComm Journal Issue: 24 Vol. 61; ISSN CHCOFS; ISSN 1359-7345

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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