Hybrid and Inorganic Vacancy-Ordered Double Perovskites A2WCl6

Morgan, Emily E.; Kent, Greggory T.; Zohar, Arava; O’Dea, Anthony; Wu, Guang; Cheetham, Anthony K.; Seshadri, Ram

doi:10.1021/acs.chemmater.3c01300

Title: Hybrid and Inorganic Vacancy-Ordered Double Perovskites A₂WCl₆

Journal Article · 16 August 2023 · Chemistry of Materials

DOI: https://doi.org/10.1021/acs.chemmater.3c01300 · OSTI ID:2521019

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^[1]; O’Dea, Anthony ^[1]; Wu, Guang ^[1];

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University of California, Santa Barbara, CA (United States)
University of California, Santa Barbara, CA (United States); National University of Singapore (Singapore)

We report hybrid and all-inorganic, vacancy-ordered double perovskites of d² W⁴⁺ with the formula A₂WCl₆ (A = CH₃NH₃⁺, Rb⁺, and Cs⁺). These compounds, which are reddish in color, can be distinguished from structurally similar compounds obtained by hydrothermal methods on the basis of structure, spectroscopic, and magnetic properties. The latter are green and incorporate oxygen, with the actual formula Cs₂WO_xCl_6–x and distinct optical absorption and emission behavior. Furthermore, the local-moment magnetism of the pure-red d² compounds reported here does not correspond to the appropriate Kotani model, suggesting as-yet undiscovered physics in these systems.

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Research Organization:: University of California, Santa Barbara, CA (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357; SC0012541

OSTI ID:: 2521019

Journal Information:: Chemistry of Materials, Journal Name: Chemistry of Materials Journal Issue: 17 Vol. 35; ISSN 0897-4756

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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