Kinetic Modeling of Secondary Organic Aerosol in a Weather-Chemistry Model: Parameterizations, Processes, and Predictions for GOAmazon

He, Yicong; Bilsback, Kelsey R.; Shrivastava, Manish; Zaveri, Rahul A.; Shilling, John E.; Seinfeld, John H.; Zhao, Bin; Wang, Shuxiao; Cappa, Christopher D.; Pierce, Jeffrey R.; Jathar, Shantanu H.

doi:10.1021/acsestair.4c00240

Title: Kinetic Modeling of Secondary Organic Aerosol in a Weather-Chemistry Model: Parameterizations, Processes, and Predictions for GOAmazon

Journal Article · 23 January 2025 · ACS ES&T Air

DOI: https://doi.org/10.1021/acsestair.4c00240 · OSTI ID:2519662

He, Yicong ^[1];

^[2];

^[3];

^[4];

^[5];

^[6];

^[7];

^[6]

Colorado State Univ., Fort Collins, CO (United States); Tsinghua Univ., Beijing (China); State Environmental Protection Key Laboratory of Sources and Control of Air Pollution Complex, Beijing (China)
Colorado State Univ., Fort Collins, CO (United States); PSE Healthy Energy, Oakland, CA (United States)
Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
California Institute of Technology (CalTech), Pasadena, CA (United States)
Tsinghua Univ., Beijing (China); State Environmental Protection Key Laboratory of Sources and Control of Air Pollution Complex, Beijing (China)
Colorado State Univ., Fort Collins, CO (United States)
Univ. of California, Davis, CA (United States)

Secondary organic aerosol (SOA) forms and evolves in the atmosphere through many pathways and processes, over diverse spatial and time scales. Hence, there is a need to represent these widely-varying kinetic processes in large-scale atmospheric models to allow for accurate predictions of the abundance, properties, and impacts of SOA. In this work, we integrated a kinetic, process-level model (simpleSOM-MOSAIC) into a weather-chemistry model (WRF-Chem) to simulate the oxidation chemistry and microphysics of atmospheric SOA. simpleSOM-MOSAIC simulates multigenerational gas-phase chemistry, autoxidation reactions, heterogeneous oxidation, oligomerization, and phase-state-influenced gas/particle partitioning of SOA. As a case study, the integrated WRF-Chem-simpleSOM-MOSAIC (WC-SSM) model was used to simulate the photochemical evolution downwind of a large city (Manaus, Brazil) in the Amazon and, in turn, study the anthropogenic and biogenic interactions in an otherwise pristine environment. Consistent with previous work, we found that OA was enhanced by up to a factor of four in the urban plume due to elevated hydroxyl radical (OH) concentrations, relative to the background, and that this OA was dominated by SOA from biogenic precursors (80%). Further, in addition to accurately simulating the OA enhancement in the urban plume, the model reproduced the magnitude of the OA oxygen-to-carbon (O:C) ratio and broadly tracked the evolution of the aerosol size distribution. Our work highlights the importance of including an integrated, kinetic representation of SOA processes in an atmospheric model

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: National Natural Science Foundation of China (NSFC); National Oceanic and Atmospheric Administration (NOAA); National Science Foundation (NSF); USDOE

Grant/Contract Number:: AC05-76RL01830; SC0017975; SC0019000

OSTI ID:: 2519662

Report Number(s):: PNNL--SA-203442

Journal Information:: ACS ES&T Air, Journal Name: ACS ES&T Air Journal Issue: 2 Vol. 2; ISSN 2837-1402

Publisher:: ACS PublicationsCopyright Statement

Country of Publication:: United States

Language:: English

References (93)

Recent advances in understanding secondary organic aerosol: Implications for global climate forcing: Advances in Secondary Organic Aerosol Shrivastava, Manish; Cappa, Christopher D.; Fan, Jiwen Reviews of Geophysics, Vol. 55, Issue 2 https://doi.org/10.1002/2016RG000540	journal	June 2017
Time scales to achieve atmospheric gas-aerosol equilibrium for volatile species Meng, Zhaoyue; Seinfeld, John H. Atmospheric Environment, Vol. 30, Issue 16 https://doi.org/10.1016/1352-2310(95)00493-9	journal	August 1996
Chemistry of secondary organic aerosol: Formation and evolution of low-volatility organics in the atmosphere Kroll, Jesse H.; Seinfeld, John H. Atmospheric Environment, Vol. 42, Issue 16 https://doi.org/10.1016/j.atmosenv.2008.01.003	journal	May 2008
1.5-Dimensional volatility basis set approach for modeling organic aerosol in CAMx and CMAQ Koo, Bonyoung; Knipping, Eladio; Yarwood, Greg Atmospheric Environment, Vol. 95 https://doi.org/10.1016/j.atmosenv.2014.06.031	journal	October 2014
Modeling regional secondary organic aerosol using the Master Chemical Mechanism Li, Jingyi; Cleveland, Meredith; Ziemba, Luke D. Atmospheric Environment, Vol. 102 https://doi.org/10.1016/j.atmosenv.2014.11.054	journal	February 2015
Observations of Manaus urban plume evolution and interaction with biogenic emissions in GoAmazon 2014/5 Cirino, Glauber; Brito, Joel; Barbosa, Henrique M. J. Atmospheric Environment, Vol. 191 https://doi.org/10.1016/j.atmosenv.2018.08.031	journal	October 2018
Gas-Phase Reactions of Isoprene and Its Major Oxidation Products Wennberg, Paul O.; Bates, Kelvin H.; Crounse, John D. Chemical Reviews, Vol. 118, Issue 7 https://doi.org/10.1021/acs.chemrev.7b00439	journal	February 2018
Highly Oxygenated Organic Molecules (HOM) from Gas-Phase Autoxidation Involving Peroxy Radicals: A Key Contributor to Atmospheric Aerosol Bianchi, Federico; Kurtén, Theo; Riva, Matthieu Chemical Reviews, Vol. 119, Issue 6 https://doi.org/10.1021/acs.chemrev.8b00395	journal	January 2019
Particle Size Distribution Dynamics Can Help Constrain the Phase State of Secondary Organic Aerosol He, Yicong; Akherati, Ali; Nah, Theodora Environmental Science & Technology, Vol. 55, Issue 3 https://doi.org/10.1021/acs.est.0c05796	journal	January 2021
Impact of Urban Pollution on Organic-Mediated New-Particle Formation and Particle Number Concentration in the Amazon Rainforest Zhao, Bin; Fast, Jerome D.; Donahue, Neil M. Environmental Science & Technology, Vol. 55, Issue 8 https://doi.org/10.1021/acs.est.0c07465	journal	March 2021
Representation of Multiphase OH Oxidation of Amorphous Organic Aerosol for Tropospheric Conditions Li, Jienan; Knopf, Daniel A. Environmental Science & Technology, Vol. 55, Issue 11 https://doi.org/10.1021/acs.est.0c07668	journal	May 2021
Process-Level Modeling Can Simultaneously Explain Secondary Organic Aerosol Evolution in Chambers and Flow Reactors He, Yicong; Lambe, Andrew T.; Seinfeld, John H. Environmental Science & Technology, Vol. 56, Issue 10 https://doi.org/10.1021/acs.est.1c08520	journal	May 2022
Vapors Are Lost to Walls, Not to Particles on the Wall: Artifact-Corrected Parameters from Chamber Experiments and Implications for Global Secondary Organic Aerosol Bilsback, Kelsey R.; He, Yicong; Cappa, Christopher D. Environmental Science & Technology, Vol. 57, Issue 1 https://doi.org/10.1021/acs.est.2c03967	journal	December 2022
Secondary Organic Aerosol Formation from Volatile Chemical Product Emissions: Model Parameters and Contributions to Anthropogenic Aerosol Sasidharan, Sreejith; He, Yicong; Akherati, Ali Environmental Science & Technology, Vol. 57, Issue 32 https://doi.org/10.1021/acs.est.3c00683	journal	August 2023
Fostering a Holistic Understanding of the Full Volatility Spectrum of Organic Compounds from Benzene Series Precursors through Mechanistic Modeling Yin, Dejia; Zhao, Bin; Wang, Shuxiao Environmental Science & Technology, Vol. 58, Issue 19 https://doi.org/10.1021/acs.est.3c07128	journal	May 2024
Heating-Induced Evaporation of Nine Different Secondary Organic Aerosol Types Kolesar, Katheryn R.; Li, Ziyue; Wilson, Kevin R. Environmental Science & Technology, Vol. 49, Issue 20 https://doi.org/10.1021/acs.est.5b03038	journal	October 2015
Molecular Composition and Volatility of Organic Aerosol in the Southeastern U.S.: Implications for IEPOX Derived SOA Lopez-Hilfiker, F. D.; Mohr, C.; D’Ambro, E. L. Environmental Science & Technology, Vol. 50, Issue 5 https://doi.org/10.1021/acs.est.5b04769	journal	February 2016
Quantification of Gas-Wall Partitioning in Teflon Environmental Chambers Using Rapid Bursts of Low-Volatility Oxidized Species Generated in Situ Krechmer, Jordan E.; Pagonis, Demetrios; Ziemann, Paul J. Environmental Science & Technology, Vol. 50, Issue 11 https://doi.org/10.1021/acs.est.6b00606	journal	May 2016
Unified Theory of Vapor–Wall Mass Transport in Teflon-Walled Environmental Chambers Huang, Yuanlong; Zhao, Ran; Charan, Sophia M. Environmental Science & Technology, Vol. 52, Issue 4 https://doi.org/10.1021/acs.est.7b05575	journal	January 2018
Particle-Phase Diffusion Modulates Partitioning of Semivolatile Organic Compounds to Aged Secondary Organic Aerosol Zaveri, Rahul A.; Shilling, John E.; Zelenyuk, Alla Environmental Science & Technology, Vol. 54, Issue 5 https://doi.org/10.1021/acs.est.9b05514	journal	January 2020
Photolysis Controls Atmospheric Budgets of Biogenic Secondary Organic Aerosol Zawadowicz, Maria A.; Lee, Ben H.; Shrivastava, Manish Environmental Science & Technology, Vol. 54, Issue 7 https://doi.org/10.1021/acs.est.9b07051	journal	March 2020
Formation of Low-Volatility Organic Compounds in the Atmosphere: Recent Advancements and Insights Barsanti, Kelley C.; Kroll, Jesse H.; Thornton, Joel A. The Journal of Physical Chemistry Letters, Vol. 8, Issue 7 https://doi.org/10.1021/acs.jpclett.6b02969	journal	March 2017
Measurements of Kinetics and Equilibria for the Condensed Phase Reactions of Hydroperoxides with Carbonyls to Form Peroxyhemiacetals Bakker-Arkema, Julia G.; Ziemann, Paul J. ACS Earth and Space Chemistry, Vol. 4, Issue 3 https://doi.org/10.1021/acsearthspacechem.0c00008	journal	February 2020
Quantifying Atmospheric Parameter Ranges for Ambient Secondary Organic Aerosol Formation Porter, William C.; Jimenez, Jose L.; Barsanti, Kelley C. ACS Earth and Space Chemistry, Vol. 5, Issue 9 https://doi.org/10.1021/acsearthspacechem.1c00090	journal	July 2021
Modeling the Size Distribution and Chemical Composition of Secondary Organic Aerosols during the Reactive Uptake of Isoprene-Derived Epoxydiols under Low-Humidity Condition Octaviani, Mega; Shrivastava, Manish; Zaveri, Rahul A. ACS Earth and Space Chemistry, Vol. 5, Issue 11 https://doi.org/10.1021/acsearthspacechem.1c00303	journal	November 2021
Isothermal Evaporation of α-Pinene Ozonolysis SOA: Volatility, Phase State, and Oligomeric Composition D’Ambro, Emma L.; Schobesberger, Siegfried; Zaveri, Rahul A. ACS Earth and Space Chemistry, Vol. 2, Issue 10 https://doi.org/10.1021/acsearthspacechem.8b00084	journal	September 2018
Measurements of Secondary Organic Aerosol from Oxidation of Cycloalkenes, Terpenes, and m -Xylene Using an Aerodyne Aerosol Mass Spectrometer Bahreini, R.; Keywood, M. D.; Ng, N. L. Environmental Science & Technology, Vol. 39, Issue 15 https://doi.org/10.1021/es048061a	journal	August 2005
Effects of Dilution on Fine Particle Mass and Partitioning of Semivolatile Organics in Diesel Exhaust and Wood Smoke Lipsky, Eric M.; Robinson, Allen L. Environmental Science & Technology, Vol. 40, Issue 1 https://doi.org/10.1021/es050319p	journal	January 2006
Products and Mechanism of Secondary Organic Aerosol Formation from Reactions of n -Alkanes with OH Radicals in the Presence of NO _x Lim, Yong Bin; Ziemann, Paul J. Environmental Science & Technology, Vol. 39, Issue 23 https://doi.org/10.1021/es051447g	journal	December 2005
Contribution of First- versus Second-Generation Products to Secondary Organic Aerosols Formed in the Oxidation of Biogenic Hydrocarbons Ng, Nga L.; Kroll, Jesse H.; Keywood, Melita D. Environmental Science & Technology, Vol. 40, Issue 7 https://doi.org/10.1021/es052269u	journal	April 2006
Coupled Partitioning, Dilution, and Chemical Aging of Semivolatile Organics Donahue, N. M.; Robinson, A. L.; Stanier, C. O. Environmental Science & Technology, Vol. 40, Issue 8 https://doi.org/10.1021/es052297c	journal	April 2006
Known and Unexplored Organic Constituents in the Earth's Atmosphere Goldstein, Allen H.; Galbally, Ian E. Environmental Science & Technology, Vol. 41, Issue 5 https://doi.org/10.1021/es072476p	journal	March 2007
Epoxide Pathways Improve Model Predictions of Isoprene Markers and Reveal Key Role of Acidity in Aerosol Formation Pye, Havala O. T.; Pinder, Robert W.; Piletic, Ivan R. Environmental Science & Technology, Vol. 47, Issue 19 https://doi.org/10.1021/es402106h	journal	September 2013
Aqueous Organic Chemistry in the Atmosphere: Sources and Chemical Processing of Organic Aerosols McNeill, V. Faye Environmental Science & Technology, Vol. 49, Issue 3 https://doi.org/10.1021/es5043707	journal	January 2015
O/C and OM/OC Ratios of Primary, Secondary, and Ambient Organic Aerosols with High-Resolution Time-of-Flight Aerosol Mass Spectrometry Aiken, Allison C.; DeCarlo, Peter F.; Kroll, Jesse H. Environmental Science & Technology, Vol. 42, Issue 12 https://doi.org/10.1021/es703009q	journal	June 2008
Laboratory observation of oligomers in the aerosol from isoprene/NO _x photooxidation Dommen, J.; Metzger, A.; Duplissy, J. Geophysical Research Letters, Vol. 33, Issue 13 https://doi.org/10.1029/2006GL026523	journal	January 2006
Equilibration timescale of atmospheric secondary organic aerosol partitioning Shiraiwa, Manabu; Seinfeld, John H. Geophysical Research Letters, Vol. 39, Issue 24 https://doi.org/10.1029/2012GL054008	journal	December 2012
Evaluation of Biogenic Organic Aerosols in the Amazon Rainforest Using WRF‐Chem With MOSAIC Mao, Jingying; Zhou, Luxi; Wu, Liqing Journal of Geophysical Research: Atmospheres, Vol. 126, Issue 23 https://doi.org/10.1029/2021JD034913	journal	December 2021
Urban pollution greatly enhances formation of natural aerosols over the Amazon rainforest Shrivastava, Manish; Andreae, Meinrat O.; Artaxo, Paulo Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-08909-4	journal	March 2019
Secondary organic aerosol association with cardiorespiratory disease mortality in the United States Pye, Havala O. T.; Ward-Caviness, Cavin K.; Murphy, Ben N. Nature Communications, Vol. 12, Issue 1 https://doi.org/10.1038/s41467-021-27484-1	journal	December 2021
Secondary organic aerosol formation from evaporated biofuels: comparison to gasoline and correction for vapor wall losses He, Yicong; King, Brandon; Pothier, Matson Environmental Science: Processes & Impacts, Vol. 22, Issue 7 https://doi.org/10.1039/D0EM00103A	journal	January 2020
A computationally efficient model to represent the chemistry, thermodynamics, and microphysics of secondary organic aerosols (simpleSOM): model development and application to α-pinene SOA Jathar, Shantanu H.; Cappa, Christopher D.; He, Yicong Environmental Science: Atmospheres, Vol. 1, Issue 6 https://doi.org/10.1039/D1EA00014D	journal	January 2021
Measurement of fragmentation and functionalization pathways in the heterogeneous oxidation of oxidized organic aerosol Kroll, Jesse H.; Smith, Jared D.; Che, Dung L. Physical Chemistry Chemical Physics, Vol. 11, Issue 36 https://doi.org/10.1039/b905289e	journal	January 2009
Kinetics, products, and mechanisms of secondary organic aerosol formation Ziemann, Paul J.; Atkinson, Roger Chemical Society Reviews, Vol. 41, Issue 19 https://doi.org/10.1039/c2cs35122f	journal	January 2012
Evaporation kinetics and phase of laboratory and ambient secondary organic aerosol Vaden, T. D.; Imre, D.; Beranek, J. Proceedings of the National Academy of Sciences, Vol. 108, Issue 6 https://doi.org/10.1073/pnas.1013391108	journal	January 2011
Aging of biogenic secondary organic aerosol via gas-phase OH radical reactions Donahue, N. M.; Henry, K. M.; Mentel, T. F. Proceedings of the National Academy of Sciences, Vol. 109, Issue 34 https://doi.org/10.1073/pnas.1115186109	journal	August 2012
Size distribution dynamics reveal particle-phase chemistry in organic aerosol formation Shiraiwa, M.; Yee, L. D.; Schilling, K. A. Proceedings of the National Academy of Sciences, Vol. 110, Issue 29 https://doi.org/10.1073/pnas.1307501110	journal	July 2013
Unspeciated organic emissions from combustion sources and their influence on the secondary organic aerosol budget in the United States Jathar, S. H.; Gordon, T. D.; Hennigan, C. J. Proceedings of the National Academy of Sciences, Vol. 111, Issue 29 https://doi.org/10.1073/pnas.1323740111	journal	July 2014
Influence of vapor wall loss in laboratory chambers on yields of secondary organic aerosol Zhang, X.; Cappa, C. D.; Jathar, S. H. Proceedings of the National Academy of Sciences, Vol. 111, Issue 16 https://doi.org/10.1073/pnas.1404727111	journal	April 2014
Volatile chemical product emissions enhance ozone and modulate urban chemistry Coggon, Matthew M.; Gkatzelis, Georgios I.; McDonald, Brian C. Proceedings of the National Academy of Sciences, Vol. 118, Issue 32 https://doi.org/10.1073/pnas.2026653118	journal	August 2021
Gas-Wall Partitioning of Organic Compounds in a Teflon Film Chamber and Potential Effects on Reaction Product and Aerosol Yield Measurements Matsunaga, Aiko; Ziemann ‡, Paul J. Aerosol Science and Technology, Vol. 44, Issue 10 https://doi.org/10.1080/02786826.2010.501044	journal	August 2010
Diffusion-Limited Versus Quasi-Equilibrium Aerosol Growth Zhang, Xi; Pandis, Spyros N.; Seinfeld, John H. Aerosol Science and Technology, Vol. 46, Issue 8 https://doi.org/10.1080/02786826.2012.679344	journal	August 2012
Rapid growth of anthropogenic organic nanoparticles greatly alters cloud life cycle in the Amazon rainforest Zaveri, Rahul A.; Wang, Jian; Fan, Jiwen Science Advances, Vol. 8, Issue 2 https://doi.org/10.1126/sciadv.abj0329	journal	January 2022
Can we achieve atmospheric chemical environments in the laboratory? An integrated model-measurement approach to chamber SOA studies Kenagy, Hannah S.; Heald, Colette L.; Tahsini, Nadia Science Advances, Vol. 10, Issue 37 https://doi.org/10.1126/sciadv.ado1482	journal	September 2024
Identification of Polymers as Major Components of Atmospheric Organic Aerosols Kalberer, M. Science, Vol. 303, Issue 5664 https://doi.org/10.1126/science.1092185	journal	March 2004
Rethinking Organic Aerosols: Semivolatile Emissions and Photochemical Aging Robinson, A. L.; Donahue, N. M.; Shrivastava, M. K. Science, Vol. 315, Issue 5816 https://doi.org/10.1126/science.1133061	journal	March 2007
Evolution of Organic Aerosols in the Atmosphere Jimenez, J. L.; Canagaratna, M. R.; Donahue, N. M. Science, Vol. 326, Issue 5959 https://doi.org/10.1126/science.1180353	journal	December 2009
The NCEP Climate Forecast System Reanalysis Saha, Suranjana; Moorthi, Shrinivas; Pan, Hua-Lu Bulletin of the American Meteorological Society, Vol. 91, Issue 8 https://doi.org/10.1175/2010BAMS3001.1	journal	August 2010
Air quality forecasting system for Southeastern Brazil Andrade, Maria de Fatima; Ynoue, Rita Y.; Freitas, Edmilson Dias Frontiers in Environmental Science, Vol. 3 https://doi.org/10.3389/fenvs.2015.00009	journal	February 2015
Quantitative estimates of the volatility of ambient organic aerosol Cappa, C. D.; Jimenez, J. L. Atmospheric Chemistry and Physics, Vol. 10, Issue 12 https://doi.org/10.5194/acp-10-5409-2010	journal	January 2010
Secondary organic aerosol formation in cloud droplets and aqueous particles (aqSOA): a review of laboratory, field and model studies Ervens, B.; Turpin, B. J.; Weber, R. J. Atmospheric Chemistry and Physics, Vol. 11, Issue 21 https://doi.org/10.5194/acp-11-11069-2011	journal	January 2011
Elemental composition and oxidation of chamber organic aerosol Chhabra, P. S.; Ng, N. L.; Canagaratna, M. R. Atmospheric Chemistry and Physics, Vol. 11, Issue 17 https://doi.org/10.5194/acp-11-8827-2011	journal	January 2011
Understanding global secondary organic aerosol amount and size-resolved condensational behavior D'Andrea, S. D.; Häkkinen, S. A. K.; Westervelt, D. M. Atmospheric Chemistry and Physics, Vol. 13, Issue 22 https://doi.org/10.5194/acp-13-11519-2013	journal	January 2013
The AeroCom evaluation and intercomparison of organic aerosol in global models Tsigaridis, K.; Daskalakis, N.; Kanakidou, M. Atmospheric Chemistry and Physics, Vol. 14, Issue 19 https://doi.org/10.5194/acp-14-10845-2014	journal	January 2014
Secondary organic aerosol yields of 12-carbon alkanes Loza, C. L.; Craven, J. S.; Yee, L. D. Atmospheric Chemistry and Physics, Vol. 14, Issue 3 https://doi.org/10.5194/acp-14-1423-2014	journal	January 2014
Oligomer formation within secondary organic aerosols: equilibrium and dynamic considerations Trump, E. R.; Donahue, N. M. Atmospheric Chemistry and Physics, Vol. 14, Issue 7 https://doi.org/10.5194/acp-14-3691-2014	journal	January 2014
Modeling kinetic partitioning of secondary organic aerosol and size distribution dynamics: representing effects of volatility, phase state, and particle-phase reaction Zaveri, R. A.; Easter, R. C.; Shilling, J. E. Atmospheric Chemistry and Physics, Vol. 14, Issue 10 https://doi.org/10.5194/acp-14-5153-2014	journal	January 2014
Simulation of semi-explicit mechanisms of SOA formation from glyoxal in aerosol in a 3-D model Knote, C.; Hodzic, A.; Jimenez, J. L. Atmospheric Chemistry and Physics, Vol. 14, Issue 12 https://doi.org/10.5194/acp-14-6213-2014	journal	January 2014
Investigation of particle and vapor wall-loss effects on controlled wood-smoke smog-chamber experiments Bian, Q.; May, A. A.; Kreidenweis, S. M. Atmospheric Chemistry and Physics, Vol. 15, Issue 19 https://doi.org/10.5194/acp-15-11027-2015	journal	January 2015
HTAP_v2.2: a mosaic of regional and global emission grid maps for 2008 and 2010 to study hemispheric transport of air pollution Janssens-Maenhout, G.; Crippa, M.; Guizzardi, D. Atmospheric Chemistry and Physics, Vol. 15, Issue 19 https://doi.org/10.5194/acp-15-11411-2015	journal	January 2015
Characterization of a real-time tracer for isoprene epoxydiols-derived secondary organic aerosol (IEPOX-SOA) from aerosol mass spectrometer measurements Hu, W. W.; Campuzano-Jost, P.; Palm, B. B. Atmospheric Chemistry and Physics, Vol. 15, Issue 20 https://doi.org/10.5194/acp-15-11807-2015	journal	January 2015
Elemental ratio measurements of organic compounds using aerosol mass spectrometry: characterization, improved calibration, and implications Canagaratna, M. R.; Jimenez, J. L.; Kroll, J. H. Atmospheric Chemistry and Physics, Vol. 15, Issue 1 https://doi.org/10.5194/acp-15-253-2015	journal	January 2015
Effect of oxidant concentration, exposure time, and seed particles on secondary organic aerosol chemical composition and yield Lambe, A. T.; Chhabra, P. S.; Onasch, T. B. Atmospheric Chemistry and Physics, Vol. 15, Issue 6 https://doi.org/10.5194/acp-15-3063-2015	journal	January 2015
Particulate matter, air quality and climate: lessons learned and future needs Fuzzi, S.; Baltensperger, U.; Carslaw, K. Atmospheric Chemistry and Physics, Vol. 15, Issue 14 https://doi.org/10.5194/acp-15-8217-2015	journal	January 2015
Introduction: Observations and Modeling of the Green Ocean Amazon (GoAmazon2014/5) Martin, S. T.; Artaxo, P.; Machado, L. A. T. Atmospheric Chemistry and Physics, Vol. 16, Issue 8 https://doi.org/10.5194/acp-16-4785-2016	journal	January 2016
Rethinking the global secondary organic aerosol (SOA) budget: stronger production, faster removal, shorter lifetime Hodzic, Alma; Kasibhatla, Prasad S.; Jo, Duseong S. Atmospheric Chemistry and Physics, Vol. 16, Issue 12 https://doi.org/10.5194/acp-16-7917-2016	journal	January 2016
Anthropogenic influences on the physical state of submicron particulate matter over a tropical forest Bateman, Adam P.; Gong, Zhaoheng; Harder, Tristan H. Atmospheric Chemistry and Physics, Vol. 17, Issue 3 https://doi.org/10.5194/acp-17-1759-2017	journal	January 2017
Power plant fuel switching and air quality in a tropical, forested environment Medeiros, Adan S. S.; Calderaro, Gisele; Guimarães, Patricia C. Atmospheric Chemistry and Physics, Vol. 17, Issue 14 https://doi.org/10.5194/acp-17-8987-2017	journal	January 2017
Aircraft observations of the chemical composition and aging of aerosol in the Manaus urban plume during GoAmazon 2014/5 Shilling, John E.; Pekour, Mikhail S.; Fortner, Edward C. Atmospheric Chemistry and Physics, Vol. 18, Issue 14 https://doi.org/10.5194/acp-18-10773-2018	journal	January 2018
Urban influence on the concentration and composition of submicron particulate matter in central Amazonia de Sá, Suzane S.; Palm, Brett B.; Campuzano-Jost, Pedro Atmospheric Chemistry and Physics, Vol. 18, Issue 16 https://doi.org/10.5194/acp-18-12185-2018	journal	January 2018
Predicting the glass transition temperature and viscosity of secondary organic material using molecular composition DeRieux, Wing-Sy Wong; Li, Ying; Lin, Peng Atmospheric Chemistry and Physics, Vol. 18, Issue 9 https://doi.org/10.5194/acp-18-6331-2018	journal	January 2018
Simulating secondary organic aerosol in a regional air quality model using the statistical oxidation model – Part 3: Assessing the influence of semi-volatile and intermediate-volatility organic compounds and NO _x Akherati, Ali; Cappa, Christopher D.; Kleeman, Michael J. Atmospheric Chemistry and Physics, Vol. 19, Issue 7 https://doi.org/10.5194/acp-19-4561-2019	journal	January 2019
A new model mechanism for atmospheric oxidation of isoprene: global effects on oxidants, nitrogen oxides, organic products, and secondary organic aerosol Bates, Kelvin H.; Jacob, Daniel J. Atmospheric Chemistry and Physics, Vol. 19, Issue 14 https://doi.org/10.5194/acp-19-9613-2019	journal	January 2019
An evaluation of global organic aerosol schemes using airborne observations Pai, Sidhant J.; Heald, Colette L.; Pierce, Jeffrey R. Atmospheric Chemistry and Physics, Vol. 20, Issue 5 https://doi.org/10.5194/acp-20-2637-2020	journal	January 2020
Aerosols from anthropogenic and biogenic sources and their interactions – modeling aerosol formation, optical properties, and impacts over the central Amazon basin Nascimento, Janaína P.; Bela, Megan M.; Meller, Bruno B. Atmospheric Chemistry and Physics, Vol. 21, Issue 9 https://doi.org/10.5194/acp-21-6755-2021	journal	January 2021
Global simulations of monoterpene-derived peroxy radical fates and the distributions of highly oxygenated organic molecules (HOMs) and accretion products Xu, Ruochong; Thornton, Joel A.; Lee, Ben H. Atmospheric Chemistry and Physics, Vol. 22, Issue 8 https://doi.org/10.5194/acp-22-5477-2022	journal	April 2022
Reactive organic carbon air emissions from mobile sources in the United States Murphy, Benjamin N.; Sonntag, Darrell; Seltzer, Karl M. Atmospheric Chemistry and Physics, Vol. 23, Issue 20 https://doi.org/10.5194/acp-23-13469-2023	journal	October 2023
Linking gas, particulate, and toxic endpoints to air emissions in the Community Regional Atmospheric Chemistry Multiphase Mechanism (CRACMM) Pye, Havala O. T.; Place, Bryan K.; Murphy, Benjamin N. Atmospheric Chemistry and Physics, Vol. 23, Issue 9 https://doi.org/10.5194/acp-23-5043-2023	journal	May 2023
Secondary organic aerosol formation from m-xylene, toluene, and benzene Ng, N. L.; Kroll, J. H.; Chan, A. W. H. Atmospheric Chemistry and Physics, Vol. 7, Issue 14 https://doi.org/10.5194/acp-7-3909-2007	journal	January 2007
The Fire INventory from NCAR (FINN): a high resolution global model to estimate the emissions from open burning Wiedinmyer, C.; Akagi, S. K.; Yokelson, R. J. Geoscientific Model Development, Vol. 4, Issue 3 https://doi.org/10.5194/gmd-4-625-2011	journal	January 2011
The Model of Emissions of Gases and Aerosols from Nature version 2.1 (MEGAN2.1): an extended and updated framework for modeling biogenic emissions Guenther, A. B.; Jiang, X.; Heald, C. L. Geoscientific Model Development, Vol. 5, Issue 6 https://doi.org/10.5194/gmd-5-1471-2012	journal	January 2012
CAM-chem: description and evaluation of interactive atmospheric chemistry in the Community Earth System Model Lamarque, J. -F.; Emmons, L. K.; Hess, P. G. Geoscientific Model Development, Vol. 5, Issue 2 https://doi.org/10.5194/gmd-5-369-2012	journal	January 2012
Multi-generational oxidation model to simulate secondary organic aerosol in a 3-D air quality model Jathar, S. H.; Cappa, C. D.; Wexler, A. S. Geoscientific Model Development, Vol. 8, Issue 8 https://doi.org/10.5194/gmd-8-2553-2015	journal	January 2015

Similar Records

Aerosols from anthropogenic and biogenic sources and their interactions – modeling aerosol formation, optical properties, and impacts over the central Amazon basin

Journal Article · 2021 · Atmospheric Chemistry and Physics (Online) · OSTI ID:1784268

Nascimento, Janaína P.; Bela, Megan M.; Meller, Bruno B.; +12 more

Exploration of oxidative chemistry and secondary organic aerosol formation in the Amazon during the wet season: explicit modeling of the Manaus urban plume with GECKO-A

Journal Article · 2020 · Atmospheric Chemistry and Physics (Online) · OSTI ID:1630199

Mouchel-Vallon, Camille; Lee-Taylor, Julia; Hodzic, Alma; +13 more

Evaluation of New and Proposed Organic Aerosol Sources and Mechanisms using the Aerosol Modeling Testbed: MILAGRO, CARES, CalNex, BEACHON, and GVAX

Technical Report · 2015 · OSTI ID:1177702

Hodzic, Alma; Jimenez, Jose L.

Related Subjects

54 ENVIRONMENTAL SCIENCES
aerosol processes
anthropogenic-biogenic interactions
chemical transport models
kinetic modeling
secondary organic aerosol

Title: Kinetic Modeling of Secondary Organic Aerosol in a Weather-Chemistry Model: Parameterizations, Processes, and Predictions for GOAmazon

Citation Formats

References (93)

Similar Records

Related Subjects