Isolation and characterization of a new polyoxometalate ligand, H3SbW14O5010-, and its interactions with f-elements

Colliard, Ian; Deblonde, Gauthier J.-P.

doi:10.1039/d4cc05558f

Title: Isolation and characterization of a new polyoxometalate ligand, H₃SbW₁₄O₅₀^10-, and its interactions with f-elements

Journal Article · 10 December 2024 · ChemComm

DOI: https://doi.org/10.1039/d4cc05558f · OSTI ID:2516795

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Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)

We report the synthesis and characterization (Raman, FTIR, DLS, single crystal XRD) of Cs₁₀H₃SbW₁₄O₅₀·6H₂O, which contains a new polyoxometalate building block: H₃SbW₁₄O₅₀^10- (SbW₁₄). Solution-state fluorescence, DLS, and UV-vis absorbance results with Nd³⁺, Eu³⁺, Am³⁺, and Cm³⁺ confirm that SbW₁₄ acts as an efficient complexant and fluorescence sensitizer for f-elements.

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Research Organization:: Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA); USDOE Office of Science (SC)

Grant/Contract Number:: AC52-07NA27344

OSTI ID:: 2516795

Report Number(s):: LLNL--JRNL-870910; 1108118

Journal Information:: ChemComm, Journal Name: ChemComm Journal Issue: 5 Vol. 61; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Title: Isolation and characterization of a new polyoxometalate ligand, H3SbW14O5010-, and its interactions with f-elements

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Title: Isolation and characterization of a new polyoxometalate ligand, H₃SbW₁₄O₅₀^10-, and its interactions with f-elements