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Title: Amine groups alter product selectivity and rate of catalytic hydride transfer reactions

Journal Article · · Chemical Science
DOI: https://doi.org/10.1039/D4SC07359B · OSTI ID:2516781
 [1];  [1];  [1]; ORCiD logo [1]; ORCiD logo [1]
  1. Department of Chemistry, University of California, Davis, CA 95616, USA
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An electrocatalyst is modified with amines at the surface, to model a common reaction environment. The most prominent effect of the amines is hydrogen bonding with the catalyst-hydride intermediate, and alterations to product selectivity.

Sponsoring Organization:
USDOE
Grant/Contract Number:
SC0016395
OSTI ID:
2516781
Journal Information:
Chemical Science, Journal Name: Chemical Science; ISSN 2041-6520; ISSN CSHCBM
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English

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