Role of H2O in Catalytic Conversion of C1 Molecules

Jiang, Lei; Li, Kongzhai; Porter, William N.; Wang, Hua; Li, Gengnan; Chen, Jingguang G.

doi:10.1021/jacs.3c13374

Title: Role of H₂O in Catalytic Conversion of C₁ Molecules

Journal Article · 24 January 2024 · Journal of the American Chemical Society

DOI: https://doi.org/10.1021/jacs.3c13374 · OSTI ID:2514405

^[1]; Li, Kongzhai ^[2];

^[3]; Wang, Hua ^[1]; Li, Gengnan ^[4];

^[3]

Kunming University of Science and Technology (China)
Kunming University of Science and Technology (China); Southwest United Graduate School, Kunming (China)
Columbia Univ., New York, NY (United States)
Argonne National Laboratory (ANL), Argonne, IL (United States). Center for Nanoscale Materials (CNM)

Due to their role in controlling global climate change, the selective conversion of C₁ molecules such as CH₄, CO, and CO₂ has attracted widespread attention. Typically, H₂O competes with the reactant molecules to adsorb on the active sites and therefore inhibits the reaction or causes catalyst deactivation. However, H₂O can also participate in the catalytic conversion of C₁ molecules as a reactant or a promoter. Herein, we provide a perspective on recent progress in the mechanistic studies of H₂O-mediated conversion of C₁ molecules. We aim to provide an in-depth and systematic understanding of H₂O as a promoter, a proton-transfer agent, an oxidant, a direct source of hydrogen or oxygen, and its influence on the catalytic activity, selectivity, and stability. We also summarize strategies for modifying catalysts or catalytic microenvironments by chemical or physical means to optimize the positive effects and minimize the negative effects of H₂O on the reactions of C₁ molecules. Finally, we discuss challenges and opportunities in catalyst design, characterization techniques, and theoretical modeling of the H₂O-mediated catalytic conversion of C₁ molecules.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: National Natural Science Foundation of China (NSFC); USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357; SC0012704

OSTI ID:: 2514405

Journal Information:: Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 5 Vol. 146; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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High-Efficiency Water Gas Shift Reaction Catalysis on α-MoC Promoted by Single-Atom Ir Species Sun, Li; Xu, Junkang; Liu, Xiaoyan ACS Catalysis, Vol. 11, Issue 10 https://doi.org/10.1021/acscatal.1c00231	journal	April 2021
Reaction Pathway for Coke-Free Methane Steam Reforming on a Ni/CeO ₂ Catalyst: Active Sites and the Role of Metal–Support Interactions Salcedo, Agustín; Lustemberg, Pablo G.; Rui, Ning ACS Catalysis, Vol. 11, Issue 13 https://doi.org/10.1021/acscatal.1c01604	journal	June 2021
Complete CO Oxidation by O₂ and H₂O over Pt–CeO_2–δ/MgO Following Langmuir–Hinshelwood and Mars–van Krevelen Mechanisms, Respectively Wang, Yanru; Ma, Jiamin; Wang, Xiuyi ACS Catalysis, Vol. 11, Issue 19, 11820-11830 https://doi.org/10.1021/acscatal.1c02507	journal	September 2021
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Effects of N₂O and Water on Activity and Selectivity in the Oxidative Coupling of Methane over Mn–Na₂WO₄/SiO₂: Role of Oxygen Species Aydin, Zeynep; Zanina, Anna; Kondratenko, Vita A. ACS Catalysis, Vol. 12, Issue 2 https://doi.org/10.1021/acscatal.1c04915	journal	January 2022
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Title: Role of H2O in Catalytic Conversion of C1 Molecules

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