Shifting the MLCT of d6 metal complexes to the red and NIR

Sorsche, Dieter; Lima, Marco A. L.; Meitinger, Nicolas; Prasad, Krishna; Mandal, Subrata; Glusac, Ksenija D.; Rau, Sven; Pannwitz, Andrea

doi:10.1016/j.ccr.2025.216454

Title: Shifting the MLCT of d⁶ metal complexes to the red and NIR

Journal Article · 02 February 2025 · Coordination Chemistry Reviews

DOI: https://doi.org/10.1016/j.ccr.2025.216454 · OSTI ID:2510903

^[1];

^[2];

^[1]; Prasad, Krishna ^[3];

^[1];

^[4];

^[1];

^[2]

Universität Ulm (Germany)
Universität Ulm (Germany); Friedrich Schiller Universität, Jena (Germany)
University of Illinois, Chicago, IL (United States)
University of Illinois, Chicago, IL (United States); Argonne National Laboratory (ANL), Argonne, IL (United States)

Light-active d⁶-coordination compounds hold great promise for light energy conversion, sensors and therapeutic applications. However, the activity in the red-to-NIR spectral region is highly desirable to convert solar light more efficiently, use low-cost red-light sources and activate these chromophores in biological tissue environment. Due to their versatility, tunability and broad intense absorption, d⁶-coordination compounds with metalto-ligand charge transfer (MLCT) transitions are especially interesting. This review article offers a comprehensive collection of strategies to tune MLCT excited states in d⁶ metal complexes and gives insights on group 6 to group 9 transition metals and their respective state-of-the-art MLCT engineering towards red-shifted absorption and emission properties with long-lived excited states. Strategies comprise lowering the π* level of the ligands, destabilizing and mixing of the metal-based HOMO, switching within a group of transition metals, matrix effects and insights into dealing with excited state deactivation in the context of the energy gap law.

View Journal Article

Cite

Export

Save

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division (CSGB)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 2510903

Journal Information:: Coordination Chemistry Reviews, Journal Name: Coordination Chemistry Reviews Vol. 530; ISSN 0010-8545

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (206)

Non-Luminescent 1,2-Diiminetricarbonylrhenium(I) Chloride Complexes – Synthesis, Electrochemical and Spectroscopic Properties of Re(DIAN)(CO)3Cl with DIAN =p-Substituted Bis(arylimino)acenaphthene Knör, Günther; Leirer, Markus; Keyes, Tia E. European Journal of Inorganic Chemistry, Vol. 2000, Issue 4 https://doi.org/10.1002/(SICI)1099-0682(200004)2000:4<749::AID-EJIC749>3.0.CO;2-B	journal	April 2000
Luminescent Mesoporous Molecular Materials Based on Neutral Tetrametallic Rectangles Benkstein, Kurt D.; Hupp, Joseph T.; Stern, Charlotte L. Angewandte Chemie, Vol. 39, Issue 16 https://doi.org/10.1002/1521-3773(20000818)39:16<2891::AID-ANIE2891>3.0.CO;2-Q	journal	August 2000
Archetype Cationic Iridium Complexes and Their Use in Solid-State Light-Emitting Electrochemical Cells Costa, RubÃ©n D.; OrtÃ, Enrique; Bolink, Henk J. Advanced Functional Materials, Vol. 19, Issue 21 https://doi.org/10.1002/adfm.200900911	journal	November 2009
Recent Progress in Ionic Iridium(III) Complexes for Organic Electronic Devices Ma, Dongxin; Tsuboi, Taiju; Qiu, Yong Advanced Materials, Vol. 29, Issue 3 https://doi.org/10.1002/adma.201603253	journal	November 2016
Functionalizing Collagen with Vessel‐Penetrating Two‐Photon Phosphorescence Probes: A New In Vivo Strategy to Map Oxygen Concentration in Tumor Microenvironment and Tissue Ischemia Wu, Cheng‐Ham; Kisel, Kristina S.; Thangavel, Muthu Kumar Advanced Science, Vol. 8, Issue 20 https://doi.org/10.1002/advs.202102788	journal	August 2021
d⁶‐Metal Complexes of 4,4′‐Bipyrimidine, an Ambident Ligand with High π‐Acceptor Ability Ernst, Sylvia; Kaim, Wolfgang Angewandte Chemie International Edition in English, Vol. 24, Issue 5 https://doi.org/10.1002/anie.198504301	journal	May 1985
Palladium versus Platinum: The Metal in the Catalytic Center of a Molecular Photocatalyst Determines the Mechanism of the Hydrogen Production with Visible Light Pfeffer, Michael G.; Schäfer, Bernhard; Smolentsev, Grigory Angewandte Chemie International Edition, Vol. 54, Issue 17 https://doi.org/10.1002/anie.201409438	journal	January 2015
A Molybdenum(0) Isocyanide Analogue of Ru(2,2′-Bipyridine) ₃ ²⁺ : A Strong Reductant for Photoredox Catalysis Büldt, Laura A.; Guo, Xingwei; Prescimone, Alessandro Angewandte Chemie International Edition, Vol. 55, Issue 37 https://doi.org/10.1002/anie.201605571	journal	July 2016
A Red‐Light‐Activated Ruthenium‐Caged NAMPT Inhibitor Remains Phototoxic in Hypoxic Cancer Cells Lameijer, Lucien N.; Ernst, Daniël; Hopkins, Samantha L. Angewandte Chemie International Edition, Vol. 56, Issue 38 https://doi.org/10.1002/anie.201703890	journal	August 2017
Ruthenium and Osmium Complexes That Bear Functional Azolate Chelates for Dye-Sensitized Solar Cells Chi, Yun; Wu, Kuan-Lin; Wei, Tzu-Chien Chemistry - An Asian Journal, Vol. 10, Issue 5 https://doi.org/10.1002/asia.201403261	journal	January 2015
Near‐IR Absorbing Ruthenium Complexes of Non‐Innocent 6,12‐Di(pyridin‐2‐yl)indolo[3,2‐ b ]carbazole: Variation as a Function of Co‐Ligands Panda, Sanjib; Ansari, Md Asif; Mandal, Abhishek Chemistry – An Asian Journal, Vol. 14, Issue 24 https://doi.org/10.1002/asia.201900719	journal	July 2019
Photophysics of an Intramolecular Hydrogen-Evolving Ru-Pd Photocatalyst Tschierlei, Stefanie; Presselt, Martin; Kuhnt, Christian Chemistry - A European Journal, Vol. 15, Issue 31 https://doi.org/10.1002/chem.200900457	journal	August 2009
Synthesis and Characterization of a Trisheteroleptic Ru^II‐Based Molecular Switch Monczak, Katharina; Peuntinger, Katrin; Sorsche, Dieter Chemistry – A European Journal, Vol. 20, Issue 47 https://doi.org/10.1002/chem.201403418	journal	October 2014
Optical Sensing of Anions via Supramolecular Recognition with Biimidazole Complexes Rommel, Sebastian A.; Sorsche, Dieter; Fleischmann, Maximilian Chemistry – A European Journal, Vol. 23, Issue 72 https://doi.org/10.1002/chem.201605782	journal	October 2017
Boosting Vis/NIR Charge-Transfer Absorptions of Iron(II) Complexes by N-Alkylation and N-Deprotonation in the Ligand Backbone Mengel, Andreas K. C.; Bissinger, Christian; Dorn, Matthias Chemistry - A European Journal, Vol. 23, Issue 33 https://doi.org/10.1002/chem.201700959	journal	May 2017
Effects of the Bidentate Ligand on the Photophysical Properties, Cellular Uptake, and (Photo)cytotoxicity of Glycoconjugates Based on the [Ru(tpy)(NN)(L)] ²⁺ Scaffold Lameijer, Lucien N.; Brevé, Tobias G.; van Rixel, Vincent H. S. Chemistry - A European Journal, Vol. 24, Issue 11 https://doi.org/10.1002/chem.201705388	journal	January 2018
Controlling Second Coordination Sphere Effects in Luminescent Ruthenium Complexes by Means of External Pressure Pannwitz, Andrea; Poirier, Stéphanie; Bélanger‐Desmarais, Nicolas Chemistry – A European Journal, Vol. 24, Issue 31 https://doi.org/10.1002/chem.201800703	journal	May 2018
NIR‐Emissive Chromium(0), Molybdenum(0), and Tungsten(0) Complexes in the Solid State at Room Temperature Boden, Pit; Di Martino‐Fumo, Patrick; Bens, Tobias Chemistry – A European Journal, Vol. 27, Issue 51 https://doi.org/10.1002/chem.202102208	journal	August 2021
Mechanistic and Kinetic Investigations of ON/OFF (Photo)Switchable Binding of Carbon Monoxide by Chromium(0), Molybdenum(0) and Tungsten(0) Carbonyl Complexes with a Pyridyl‐Mesoionic Carbene Ligand Boden, Pit J.; Di Martino‐Fumo, Patrick; Bens, Tobias Chemistry – A European Journal, Vol. 28, Issue 51 https://doi.org/10.1002/chem.202202543	journal	September 2022
Prediction of Strong Solvatochromism in a Molecular Photocatalyst** Putra, Miftahussurur Hamidi; Bagemihl, Benedikt; Rau, Sven Chemistry – A European Journal, Vol. 30, Issue 1 https://doi.org/10.1002/chem.202302643	journal	November 2023
Two-Electron Carbon Dioxide Reduction Catalyzed by Rhenium(I) Bis(imino)acenaphthene Carbonyl Complexes Portenkirchner, Engelbert; Kianfar, Elham; Sariciftci, Niyazi Serdar ChemSusChem, Vol. 7, Issue 5 https://doi.org/10.1002/cssc.201301116	journal	April 2014
Ligand Variations in [ReX(diimine)(CO)3] Complexes: Effects on Photocatalytic CO2 Reduction Kurz, Philipp; Probst, Benjamin; Spingler, Bernhard European Journal of Inorganic Chemistry, Vol. 2006, Issue 15 https://doi.org/10.1002/ejic.200600166	journal	August 2006
Electronic Structures of the Electron Transfer Series [M(bpy) ₃ ] ⁿ , [M(tpy) ₂ ] ⁿ , and [Fe( ^t bpy) ₃ ] ⁿ (M = Fe, Ru; n = 3+, 2+, 1+, 0, 1-): A Mössbauer Spectroscopic and DFT Study : [M(bpy) England, Jason; Scarborough, Christopher C.; Weyhermüller, Thomas European Journal of Inorganic Chemistry, Vol. 2012, Issue 29 https://doi.org/10.1002/ejic.201200232	journal	June 2012
Rhenium Complexes with Red‐Light‐Induced Anticancer Activity Wähler, Kathrin; Ludewig, Anja; Szabo, Patrick European Journal of Inorganic Chemistry, Vol. 2014, Issue 5 https://doi.org/10.1002/ejic.201301474	journal	January 2014
Protonation‐Dependent Luminescence of an Iridium(III) Bibenzimidazole Chromophore Rommel, Sebastian A.; Sorsche, Dieter; Rockstroh, Nils European Journal of Inorganic Chemistry, Vol. 2015, Issue 22 https://doi.org/10.1002/ejic.201500234	journal	July 2015
Synthesis and Assessment of CO-Release Capacity of Manganese Carbonyl Complexes Derived from Rigid α-Diimine Ligands of Varied Complexity: Synthesis and CO-Release Capacity of Mn Carbonyl Complexes Jimenez, Jorge; Chakraborty, Indranil; Mascharak, Pradip K. European Journal of Inorganic Chemistry, Vol. 2015, Issue 30 https://doi.org/10.1002/ejic.201500816	journal	September 2015
Correlation of MLCTs of Group 7 fac -[M(CO) ₃ ] ⁺ Complexes (M = Mn, Re) with Bipyridine, Pyridinylpyrazine, Azopyridine, and Pyridin-2-ylmethanimine Type Ligands for Rational photoCORM Design : Correlation of MLCTs of Group 7 fac-[M(CO)3]+ Complexes (M = Mn, Re) with Bipyridine, Pyridinylpyrazine, Azopyridine, and Pyridin-2-ylmethanimine Type Kottelat, Emmanuel; Lucarini, Fiorella; Crochet, Aurelien European Journal of Inorganic Chemistry, Vol. 2019, Issue 33 https://doi.org/10.1002/ejic.201900568	journal	August 2019
Influence of Hetero‐Biaryl Ligands on the Photo‐Electrochemical Properties of [Re^INCS(N^∩N)(CO)₃]‐Type Photosensitizers Mosberger, Mathias; Probst, Benjamin; Spingler, Bernhard European Journal of Inorganic Chemistry, Vol. 2019, Issue 30 https://doi.org/10.1002/ejic.201900652	journal	August 2019
Extending the π‐System in Mn^I Diimine Tricarbonyl Complexes: Impacts on Photochemistry, Electrochemistry, and CO₂ Catalytic Reduction Activity Cohen, Kailyn Y.; Evans, Rebecca; Bocarsly, Andrew B. European Journal of Inorganic Chemistry, Vol. 26, Issue 32 https://doi.org/10.1002/ejic.202300435	journal	September 2023
Spectroscopic studies of preferential and asymmetric solvation in substituted cyanoiron(II) complexes Toma, Henrique E.; Takasugi, Maria S. Journal of Solution Chemistry, Vol. 12, Issue 8 https://doi.org/10.1007/BF01150847	journal	August 1983
Fabrication of photovoltaic cells using rhenium diimine complex containing polyelectrolytes by the layer-by-layer electrostatic self-assembly method Man, Ka Yan Kitty; Tse, Chui Wan; Cheng, Kai Wing Journal of Inorganic and Organometallic Polymers and Materials, Vol. 17, Issue 1 https://doi.org/10.1007/s10904-007-9138-z	journal	March 2007
Synthesis of Hyperbranched Polymers with Rhenium(I) Bis(Stilbazoylimino)Acephthalene Complexes at the Branching Units Tse, Chui Wan; Cheng, Kai Wing; Chan, Wai Kin Journal of Inorganic and Organometallic Polymers and Materials, Vol. 18, Issue 1 https://doi.org/10.1007/s10904-007-9187-3	journal	November 2007
Medium effects on fluorescence quantum yields and lifetimes for coumarin laser dyes Jones, Guilford; Jackson, William R.; Halpern, Arthur M. Chemical Physics Letters, Vol. 72, Issue 2 https://doi.org/10.1016/0009-2614(80)80314-9	journal	June 1980
Ru(II) polypyridine complexes: photophysics, photochemistry, eletrochemistry, and chemiluminescence Juris, A.; Balzani, V.; Barigelletti, F. Coordination Chemistry Reviews, Vol. 84 https://doi.org/10.1016/0010-8545(88)80032-8	journal	March 1988
Elektrontransfer-katalysierte carbonyl-substitution Olbrich-Deussner, Barbara; Kaim, Wolfgang Journal of Organometallic Chemistry, Vol. 340, Issue 1 https://doi.org/10.1016/0022-328X(88)80555-2	journal	February 1988
cis-Dicarbonylbis(tributylphosphan)molybdän-Komplexe der vier isomeren bidiazine Ernst, Sylvia; Kohlmann, Stephan; Kaim, Wolfgang Journal of Organometallic Chemistry, Vol. 354, Issue 2 https://doi.org/10.1016/0022-328X(88)87044-X	journal	October 1988
Synthesis, electrochemistry and emission spectroscopy in fluid solution of four isomeric (α-diimine)Re(CO)3Hal complexes Kaim, Wolfgang; Kramer, Horst E. A.; Vogler, Conny Journal of Organometallic Chemistry, Vol. 367, Issue 1-2 https://doi.org/10.1016/0022-328X(89)87212-2	journal	May 1989
Metal-to-ligand charge transfer absorption in a rhenium(I) complex that contains a π-conjugated bipyridine acceptor ligand Walters, Keith A.; Premvardhan, Lavanya L.; Liu, Yao Chemical Physics Letters, Vol. 339, Issue 3-4 https://doi.org/10.1016/S0009-2614(01)00318-9	journal	May 2001
Synthesis and characterization of osmium(II) complexes incorporating polypyridyl bridging ligands Richter, Mark M.; Brewer, Karen J. Inorganica Chimica Acta, Vol. 180, Issue 1 https://doi.org/10.1016/S0020-1693(00)83076-5	journal	February 1991
3,3′-Bipyridazine: the ‘second-best’ bidiazine ligand for M(CO)4 fragments (M = Cr, Mo, W) Ernst, Sylvia; Kaim, Wolfgang Inorganica Chimica Acta, Vol. 114, Issue 2 https://doi.org/10.1016/S0020-1693(00)86442-7	journal	April 1986
Synthesis and protonation-deprotonation reactions of ruthenium(II) complexes containing 2, 2′-bibenzimidazole and related ligands Haga, Masa-Aki Inorganica Chimica Acta, Vol. 75 https://doi.org/10.1016/S0020-1693(00)91186-1	journal	January 1983
Structures and spectroelectrochemistry (UV–vis, IR, EPR) of complexes [(OC)3ClRe]n(abpy), n=1, 2; abpy=2,2′-azobispyridine Hartmann, Heiko; Scheiring, Thomas; Fiedler, Jan Journal of Organometallic Chemistry, Vol. 604, Issue 2 https://doi.org/10.1016/S0022-328X(00)00282-5	journal	June 2000
Synthesis, characterization and spectroscopic properties of 1,2-diiminetricarbonylrhenium(I)chloride complexes with o-benzoquinone diimines as ligands Knör, Günther; Leirer, Markus; Vogler, Arnd Journal of Organometallic Chemistry, Vol. 610, Issue 1-2 https://doi.org/10.1016/S0022-328X(00)00347-8	journal	September 2000
Eilatin, a novel alkaloid from the marine tunicate Rudi, Amira; Benayahu, Yehuda; Goldberg, Israel Tetrahedron Letters, Vol. 29, Issue 50 https://doi.org/10.1016/S0040-4039(00)82422-3	journal	January 1988
Measurement of the penetration depths of red and near infrared light in human “ex vivo” tissues Stolik, S.; Delgado, J. A.; Pérez, A. Journal of Photochemistry and Photobiology B: Biology, Vol. 57, Issue 2-3 https://doi.org/10.1016/S1011-1344(00)00082-8	journal	September 2000
Synthesis and photosensitizing properties of conjugated polymers that contain chlorotricarbonyl bis(phenylimino)acenaphthene rhenium(I) complexes Chan, Wai Kin; Hui, Ching Sum; Man, Ka Yan Kitty Coordination Chemistry Reviews, Vol. 249, Issue 13-14 https://doi.org/10.1016/j.ccr.2004.10.006	journal	July 2005
Toward more efficient photochemical CO2 reduction: Use of scCO2 or photogenerated hydrides Doherty, Mark D.; Grills, David C.; Muckerman, James T. Coordination Chemistry Reviews, Vol. 254, Issue 21-22 https://doi.org/10.1016/j.ccr.2009.12.013	journal	November 2010
Electronic structures, photophysical properties, and electrochemistry of ruthenium(II)(bpy)2 pyridylimidazole complexes Lancaster, Kyle M.; Gerken, James B.; Durrell, Alec C. Coordination Chemistry Reviews, Vol. 254, Issue 15-16 https://doi.org/10.1016/j.ccr.2010.04.005	journal	August 2010
Ru(II) dyads derived from α-oligothiophenes: A new class of potent and versatile photosensitizers for PDT Shi, Ge; Monro, Susan; Hennigar, Robie Coordination Chemistry Reviews, Vol. 282-283 https://doi.org/10.1016/j.ccr.2014.04.012	journal	January 2015
Over the LEC rainbow: Colour and stability tuning of cyclometallated iridium(III) complexes in light-emitting electrochemical cells Housecroft, Catherine E.; Constable, Edwin C. Coordination Chemistry Reviews, Vol. 350 https://doi.org/10.1016/j.ccr.2017.06.016	journal	November 2017
Heteroleptic diimine–diphosphine Cu(I) complexes as an alternative towards noble-metal based photosensitizers: Design strategies, photophysical properties and perspective applications Zhang, Ying; Schulz, Martin; Wächtler, Maria Coordination Chemistry Reviews, Vol. 356 https://doi.org/10.1016/j.ccr.2017.10.016	journal	February 2018
Luminescent Ni(0) complexes Malzkuhn, Sabine; Wenger, Oliver S. Coordination Chemistry Reviews, Vol. 359 https://doi.org/10.1016/j.ccr.2018.01.003	journal	March 2018
Transition metal complexes as photosensitisers in one- and two-photon photodynamic therapy McKenzie, Luke K.; Bryant, Helen E.; Weinstein, Julia A. Coordination Chemistry Reviews, Vol. 379 https://doi.org/10.1016/j.ccr.2018.03.020	journal	January 2019
Photofunctionality of iron(III) N-heterocyclic carbenes and related d transition metal complexes Chábera, Pavel; Lindh, Linnea; Rosemann, Nils W. Coordination Chemistry Reviews, Vol. 426 https://doi.org/10.1016/j.ccr.2020.213517	journal	January 2021
Ruthenium tris(bipyridine) complexes: Interchange between photons and electrons in molecular-scale devices and machines Balzani, Vincenzo; Ceroni, Paola; Credi, Alberto Coordination Chemistry Reviews, Vol. 433 https://doi.org/10.1016/j.ccr.2020.213758	journal	April 2021
Earth-abundant-metal complexes as photosensitizers in molecular systems for light-driven CO2 reduction Ma, Fan; Luo, Zhi-Mei; Wang, Jia-Wei Coordination Chemistry Reviews, Vol. 500 https://doi.org/10.1016/j.ccr.2023.215529	journal	February 2024
Harnessing high-energy MLCT excited states for artificial photosynthesis Cotic, Agustina; Ramírez-Wierzbicki, Ivana; Cadranel, Alejandro Coordination Chemistry Reviews, Vol. 514 https://doi.org/10.1016/j.ccr.2024.215878	journal	September 2024
Synthesis and properties of Re(I) tricarbonyl complexes of 6,6′-disubstituted-4,4′-bipyrimidines with high energy excited states suitable for incorporation into polynuclear arrays Ioachim, Elena; Medlycott, Elaine A.; Hanan, Garry S. Inorganica Chimica Acta, Vol. 359, Issue 9 https://doi.org/10.1016/j.ica.2005.09.042	journal	June 2006
Correlations between photophysical and electrochemical properties for a series of new Mn carbonyl complexes containing substituted phenanthroline ligands Kurtz, Daniel A.; Dhakal, Badrinath; Hulme, Richard J. Inorganica Chimica Acta, Vol. 427 https://doi.org/10.1016/j.ica.2014.12.009	journal	March 2015
New photo-CORMs: Deeply-coloured biocompatible rhenium complexes for the controlled release of carbon monoxide Kianfar, Elham; Schäfer, Christine; Lornejad-Schäfer, Mohammad Reza Inorganica Chimica Acta, Vol. 435 https://doi.org/10.1016/j.ica.2015.05.035	journal	August 2015
The BIAN ligand 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene: An electron sponge or a “normal” α-diimine ligand? Löw, Isabell; Bubrin, Martina; Paretzki, Alexa Inorganica Chimica Acta, Vol. 455 https://doi.org/10.1016/j.ica.2016.05.054	journal	January 2017
Towards near-IR emissive rhenium tricarbonyl complexes: Synthesis and characterisation of unusual 2,2′-biquinoline complexes Hallett, Andrew J.; Pope, Simon J. A. Inorganic Chemistry Communications, Vol. 14, Issue 10 https://doi.org/10.1016/j.inoche.2011.06.021	journal	October 2011
A complete series of tricarbonylhalidorhenium(I) complexes (abpy)Re(CO)3(Hal), Hal=F, Cl, Br, I; abpy=2,2′-azobispyridine: Structures, spectroelectrochemistry and EPR of reduced forms Frantz, Stéphanie; Fiedler, Jan; Hartenbach, Ingo Journal of Organometallic Chemistry, Vol. 689, Issue 19 https://doi.org/10.1016/j.jorganchem.2004.06.047	journal	September 2004
Structure, electrochemistry, spectroscopy, and magnetic resonance, including high-field EPR, of {(μ-abpy)[Re(CO)3X]2}o/•−, where abpy=2,2′-azobispyridine and X=F, Cl, Br, I Frantz, Stéphanie; Sieger, Monika; Hartenbach, Ingo Journal of Organometallic Chemistry, Vol. 694, Issue 7-8 https://doi.org/10.1016/j.jorganchem.2008.09.034	journal	April 2009
The use of sublimable chlorotricarbonyl bis(phenylimino)acenaphthene rhenium(I) complexes as photosensitizers in bulk-heterojunction photovoltaic devices Mak, Chris S. K.; Wong, Hei Ling; Leung, Qing Yun Journal of Organometallic Chemistry, Vol. 694, Issue 17 https://doi.org/10.1016/j.jorganchem.2009.04.037	journal	August 2009
Luminescence and spectroscopic studies of organometallic rhodium and rhenium multichromophore systems carrying polypyridyl acceptor sites and phenylethynyl antenna subunits Oppelt, Kerstin; Egbe, Daniel. A. M.; Monkowius, Uwe Journal of Organometallic Chemistry, Vol. 696, Issue 10 https://doi.org/10.1016/j.jorganchem.2010.11.008	journal	May 2011
Synthesis and characterization of novel cyclometalated iridium(III) complexes for nanocrystalline TiO2-based dye-sensitized solar cells Shinpuku, Yoshiki; Inui, Fumiaki; Nakai, Misaki Journal of Photochemistry and Photobiology A: Chemistry, Vol. 222, Issue 1 https://doi.org/10.1016/j.jphotochem.2011.05.023	journal	July 2011
Design of perylene diimides for organic solar cell: Effect of molecular steric hindrance and extended conjugation Kozma, Erika; Kotowski, Dariusz; Catellani, Marinella Materials Chemistry and Physics, Vol. 163 https://doi.org/10.1016/j.matchemphys.2015.07.025	journal	August 2015
X-ray structure, spectroscopic characterisation and DFT calculations of the [Re(CO)3(2,2′-biquinoline)Cl] complex Machura, B.; Kruszynski, R. Polyhedron, Vol. 26, Issue 13 https://doi.org/10.1016/j.poly.2007.03.014	journal	August 2007
Synthesis and study of Re(I) tricarbonyl complexes based on octachloro-1,10-phenanthroline: Towards deep red-to-NIR emitters Artem'ev, Alexander V.; Petyuk, Maxim Yu.; Berezin, Alexey S. Polyhedron, Vol. 209 https://doi.org/10.1016/j.poly.2021.115484	journal	November 2021
Manganese Carbonyl Complexes as Selective Electrocatalysts for CO₂ Reduction in Water and Organic Solvents Siritanaratkul, Bhavin; Eagle, Catherine; Cowan, Alexander J. Accounts of Chemical Research, Vol. 55, Issue 7 https://doi.org/10.1021/acs.accounts.1c00692	journal	March 2022
Luminescent Rhenium(I) and Iridium(III) Polypyridine Complexes as Biological Probes, Imaging Reagents, and Photocytotoxic Agents Lo, Kenneth Kam-Wing Accounts of Chemical Research, Vol. 48, Issue 12 https://doi.org/10.1021/acs.accounts.5b00211	journal	July 2015
New Ru(II) Complexes for Dual Photoreactivity: Ligand Exchange and ¹ O ₂ Generation Knoll, Jessica D.; Albani, Bryan A.; Turro, Claudia Accounts of Chemical Research, Vol. 48, Issue 8 https://doi.org/10.1021/acs.accounts.5b00227	journal	July 2015
Photocatalysis in the Life Science Industry Candish, Lisa; Collins, Karl D.; Cook, Gemma C. Chemical Reviews, Vol. 122, Issue 2 https://doi.org/10.1021/acs.chemrev.1c00416	journal	September 2021
Ultrafast Electron Dynamics in Solar Energy Conversion Ponseca, Carlito S.; Chábera, Pavel; Uhlig, Jens Chemical Reviews, Vol. 117, Issue 16 https://doi.org/10.1021/acs.chemrev.6b00807	journal	May 2017
When Donors Turn into Acceptors: Ground and Excited State Properties of Fe^II Complexes with Amine-Substituted Tridentate Bis-imidazole-2-ylidene Pyridine Ligands Vukadinovic, Yannik; Burkhardt, Lukas; Päpcke, Ayla Inorganic Chemistry, Vol. 59, Issue 13 https://doi.org/10.1021/acs.inorgchem.0c00393	journal	June 2020
Modulation of Osmium(II) Tris(2,2′-bipyridine) Photophysics through Encapsulation within Zinc(II) Trimesic Acid Metal Organic Frameworks Mayers, Jacob M.; Larsen, Randy W. Inorganic Chemistry, Vol. 59, Issue 11 https://doi.org/10.1021/acs.inorgchem.0c00807	journal	May 2020
Molecular Scylla and Charybdis: Maneuvering between pH Sensitivity and Excited-State Localization in Ruthenium Bi(benz)imidazole Complexes Mengele, Alexander K.; Müller, Carolin; Nauroozi, Djawed Inorganic Chemistry, Vol. 59, Issue 17 https://doi.org/10.1021/acs.inorgchem.0c01022	journal	August 2020
In-Depth Study of the Electronic Properties of NIR-Emissive κ³N Terpyridine Rhenium(I) Dicarbonyl Complexes Auvray, Thomas; Del Secco, Benedetta; Dubreuil, Amélie Inorganic Chemistry, Vol. 60, Issue 1 https://doi.org/10.1021/acs.inorgchem.0c02188	journal	December 2020
Third-Generation W(CNAr)₆ Photoreductants (CNAr = Fused-Ring and Alkynyl-Bridged Arylisocyanides) Fajardo, Javier; Schwan, Josef; Kramer, Wesley W. Inorganic Chemistry, Vol. 60, Issue 6 https://doi.org/10.1021/acs.inorgchem.0c02912	journal	December 2020
Coordination Environment Prevents Access to Intraligand Charge-Transfer States through Remote Substitution in Rhenium(I) Terpyridinedicarbonyl Complexes Fernández-Terán, Ricardo J.; Sévery, Laurent Inorganic Chemistry, Vol. 60, Issue 3 https://doi.org/10.1021/acs.inorgchem.0c02914	journal	December 2020
In Pursuit of Panchromatic Absorption in Metal Coordination Complexes: Experimental Delineation of the HOMO Inversion Model Using Pseudo-Octahedral Complexes of Diarylamido Ligands Braun, Jason D.; Lozada, Issiah B.; Herbert, David E. Inorganic Chemistry, Vol. 59, Issue 23 https://doi.org/10.1021/acs.inorgchem.0c02973	journal	November 2020
Computational Design of Rhenium(I) Carbonyl Complexes for Anticancer Photodynamic Therapy Álvarez, Daniel; Menéndez, M. Isabel; López, Ramón Inorganic Chemistry, Vol. 61, Issue 1 https://doi.org/10.1021/acs.inorgchem.1c03130	journal	December 2021
Photophysical Properties and DNA Binding of Two Intercalating Osmium Polypyridyl Complexes Showing Light-Switch Effects Stitch, Mark; Boota, Rayhaan Z.; Chalkley, Alannah S. Inorganic Chemistry, Vol. 61, Issue 38 https://doi.org/10.1021/acs.inorgchem.2c01231	journal	September 2022
Borylation in the Second Coordination Sphere of Fe^II Cyanido Complexes and Its Impact on Their Electronic Structures and Excited-State Dynamics Schmid, Lucius; Chábera, Pavel; Rüter, Isabelle Inorganic Chemistry, Vol. 61, Issue 40 https://doi.org/10.1021/acs.inorgchem.2c01667	journal	September 2022
Extended π-Conjugated Ligands Tune Excited-State Energies of Iron(II) Polypyridine Dyes Curtin, Gregory M.; Jakubikova, Elena Inorganic Chemistry, Vol. 61, Issue 47 https://doi.org/10.1021/acs.inorgchem.2c02362	journal	November 2022
Proton-Coupled, Low-Energy Pathway for Electrocatalytic CO₂ Reduction at Re(Diimine) Complexes with a Conjugated Pyrazinyl Moiety Chandy, Sruthy K.; Bowers, Scott A.; Yin, Minyang Inorganic Chemistry, Vol. 61, Issue 44 https://doi.org/10.1021/acs.inorgchem.2c02400	journal	October 2022
Enhanced Deep-Red Phosphorescence in Cyclometalated Iridium Complexes with Quinoline-Based Ancillary Ligands Yoon, Sungwon; Gray, Thomas G.; Teets, Thomas S. Inorganic Chemistry, Vol. 62, Issue 20 https://doi.org/10.1021/acs.inorgchem.3c00670	journal	May 2023
Modular Imine Chelates with Variable Anionic Donors Promote Red Phosphorescence in Cyclometalated Iridium Complexes Jiang, Chenggang; Yoon, Sungwon; Nguyen, Yennie H. Inorganic Chemistry, Vol. 62, Issue 28 https://doi.org/10.1021/acs.inorgchem.3c01770	journal	July 2023
Dinuclear PhotoCORMs: Dioxygen-Assisted Carbon Monoxide Uncaging from Long-Wavelength-Absorbing Metal–Metal-Bonded Carbonyl Complexes Li, Zhi; Pierri, Agustin E.; Huang, Po-Ju Inorganic Chemistry, Vol. 56, Issue 11 https://doi.org/10.1021/acs.inorgchem.6b03138	journal	March 2017
Bathochromic Shifts in Rhenium Carbonyl Dyes Induced through Destabilization of Occupied Orbitals Kurtz, Daniel A.; Brereton, Kelsey R.; Ruoff, Kevin P. Inorganic Chemistry, Vol. 57, Issue 9 https://doi.org/10.1021/acs.inorgchem.8b00360	journal	April 2018
Redox “Innocence” of Re(I) in Electrochemical CO ₂ Reduction Catalyzed by Nanographene–Re Complexes Schaugaard, Richard N.; Raghavachari, Krishnan; Li, Liang-shi Inorganic Chemistry, Vol. 57, Issue 17 https://doi.org/10.1021/acs.inorgchem.8b01092	journal	August 2018
Impact of the fac / mer Isomerism on the Excited-State Dynamics of Pyridyl-carbene Fe(II) Complexes Magra, Kevin; Domenichini, Edoardo; Francés-Monerris, Antonio Inorganic Chemistry, Vol. 58, Issue 8 https://doi.org/10.1021/acs.inorgchem.9b00138	journal	March 2019
Ultrafast Spectroscopy of [Mn(CO) ₃ ] Complexes: Tuning the Kinetics of Light-Driven CO Release and Solvent Binding Henke, Wade C.; Otolski, Christopher J.; Moore, William N. G. Inorganic Chemistry, Vol. 59, Issue 4 https://doi.org/10.1021/acs.inorgchem.9b02758	journal	January 2020
Proton-Coupled Electron Transfer in a Ruthenium(II) Bipyrimidine Complex in Its Ground and Excited Electronic States Drummer, Matthew C.; Weerasooriya, Ravindra B.; Gupta, Nikita The Journal of Physical Chemistry A, Vol. 126, Issue 27 https://doi.org/10.1021/acs.jpca.2c02255	journal	June 2022
Photophysical Investigation of Iron(II) Complexes Bearing Bidentate Annulated Isomeric Pyridine-NHC Ligands Magra, Kevin; Darari, Mohamed; Domenichini, Edoardo The Journal of Physical Chemistry C, Vol. 124, Issue 34 https://doi.org/10.1021/acs.jpcc.0c03638	journal	July 2020
Fe ^II Hexa N -Heterocyclic Carbene Complex with a 528 ps Metal-to-Ligand Charge-Transfer Excited-State Lifetime Chábera, Pavel; Kjaer, Kasper S.; Prakash, Om The Journal of Physical Chemistry Letters, Vol. 9, Issue 3 https://doi.org/10.1021/acs.jpclett.7b02962	journal	January 2018
Design Strategies To Improve the Sensitivity of Photoactive Metal Carbonyl Complexes (photoCORMs) to Visible Light and Their Potential as CO-Donors to Biological Targets Chakraborty, Indranil; Carrington, Samantha J.; Mascharak, Pradip K. Accounts of Chemical Research, Vol. 47, Issue 8 https://doi.org/10.1021/ar500172f	journal	July 2014
Dye-Sensitized Solar Cells Hagfeldt, Anders; Boschloo, Gerrit; Sun, Licheng Chemical Reviews, Vol. 110, Issue 11 https://doi.org/10.1021/cr900356p	journal	November 2010
Electrochemistry and absorption and emission spectroscopy of new orthometalated complexes of rhodium(III) and iridium(III) with the ligands 1,4,5,8-tetraazaphenanthrene and 1,4,5,8,9,12-hexaazatriphenylene Didier, P.; Ortmans, I.; Kirsch-De Mesmaeker, A. Inorganic Chemistry, Vol. 32, Issue 23 https://doi.org/10.1021/ic00075a049	journal	November 1993
Black MLCT Absorbers Anderson, Peter A.; Strouse, Geoffrey F.; Treadway, Joseph A. Inorganic Chemistry, Vol. 33, Issue 18 https://doi.org/10.1021/ic00096a007	journal	August 1994
Os(phen)2(dppz)2+: A Red-Emitting DNA Probe Holmlin, R. Erik; Barton, Jacqueline K. Inorganic Chemistry, Vol. 34, Issue 1 https://doi.org/10.1021/ic00105a004	journal	January 1995
Influence Of Electronic Delocalization In Metal-to-Ligand Charge Transfer Excited States Strouse, Geoffrey F.; Schoonover, Jon R.; Duesing, Richard Inorganic Chemistry, Vol. 34, Issue 2 https://doi.org/10.1021/ic00106a009	journal	January 1995
X-ray Structure of fac-IMn(CO)3(bpy) and Electronic Structures and Transitions of the Complexes fac-XMn(CO)3(bpy) (X = Cl, I) and mer-ClMn(CO)3(bpy) Stor, G. J.; Stufkens, D. J.; Vernooijs, P. Inorganic Chemistry, Vol. 34, Issue 6 https://doi.org/10.1021/ic00110a042	journal	March 1995
Redox properties of ruthenium(II) tris chelate complexes containing the ligands 2,2'-bipyrazine, 2,2'-bipyridine, and 2,2'-bipyrimidine Rillema, D. Paul; Allen, G.; Meyer, T. J. Inorganic Chemistry, Vol. 22, Issue 11 https://doi.org/10.1021/ic00153a012	journal	May 1983
Solvent and substituent effects on the lowest energy excited states of M(CO)4(diimine) (M = Cr, Mo, W) complexes Manuta, David M.; Lees, Alistair J. Inorganic Chemistry, Vol. 22, Issue 25 https://doi.org/10.1021/ic00167a031	journal	December 1983
Emission and photochemistry of M(CO)4(diimine) (M = chromium, molybdenum, tungsten) complexes in room-temperature solution Manuta, David M.; Lees, Alistair J. Inorganic Chemistry, Vol. 25, Issue 9 https://doi.org/10.1021/ic00229a012	journal	April 1986
Spectrophotometric and voltammetric characterization of complexes of bis(2,2'-bipyridine)(2,2'-bibenzimidazole)ruthenium and -osmium in oxidation states II, III, and IV in acetonitrile/water mixtures Bond, Alan M.; Haga, Masaaki Inorganic Chemistry, Vol. 25, Issue 25 https://doi.org/10.1021/ic00245a012	journal	December 1986
Four bridging bis chelate ligands with very low lying .pi.* orbitals. MO perturbation calculations, electrochemistry, and spectroscopy of mononuclear and binuclear group 6 metal tetracarbonyl complexes Kaim, Wolfgang; Kohlmann, Stephan Inorganic Chemistry, Vol. 26, Issue 1 https://doi.org/10.1021/ic00248a016	journal	January 1987
Absorption spectra, electrochemical behavior, luminescence spectra, and excited-state lifetimes of mixed-ligand ortho-metalated rhodium(III) complexes Maestri, Mauro; Sandrini, Diana; Balzani, Vincenzo Inorganic Chemistry, Vol. 26, Issue 8 https://doi.org/10.1021/ic00255a025	journal	April 1987
Temperature dependence of the luminescence of cyclometalated palladium(II), rhodium(III), platinum(II), and platinum(IV) complexes Barigelletti, Francesco; Sandrini, Diana; Maestri, Mauro Inorganic Chemistry, Vol. 27, Issue 20 https://doi.org/10.1021/ic00293a041	journal	October 1988
Synthesis and photophysical and electrochemical properties of new halotricarbonyl(polypyridine)rhenium(I) complexes Juris, Alberto; Campagna, Sebastiano; Bidd, Ilesh Inorganic Chemistry, Vol. 27, Issue 22 https://doi.org/10.1021/ic00295a022	journal	November 1988
Energy level tailoring in ruthenium(II) polyazine complexes based on calculated and experimental ligand properties Ernst, Sylvia D.; Kaim, Wolfgang Inorganic Chemistry, Vol. 28, Issue 8 https://doi.org/10.1021/ic00307a020	journal	April 1989
Synthesis and Characterization of Optically Active and Racemic Forms of Cyclometalated Rh(III) Complexes. An Experimental and Theoretical Emission Study Ghizdavu, Liana; Lentzen, Olivier; Schumm, Stephan Inorganic Chemistry, Vol. 42, Issue 6 https://doi.org/10.1021/ic020435i	journal	February 2003
Eilatin as a Bridging Ligand in Ruthenium(II) Complexes: Synthesis, Crystal Structures, Absorption Spectra, and Electrochemical Properties Gut, Dalia; Goldberg, Israel; Kol, Moshe Inorganic Chemistry, Vol. 42, Issue 11 https://doi.org/10.1021/ic020703c	journal	April 2003
Mononuclear and Dinuclear Complexes of Dibenzoeilatin: Synthesis, Structure, and Electrochemical and Photophysical Properties Bergman, Sheba D.; Goldberg, Israel; Barbieri, Andrea Inorganic Chemistry, Vol. 43, Issue 7 https://doi.org/10.1021/ic0354062	journal	February 2004
Mononuclear and Dinuclear Complexes of Isoeilatin Bergman, Sheba D.; Goldberg, Israel; Barbieri, Andrea Inorganic Chemistry, Vol. 44, Issue 7 https://doi.org/10.1021/ic050002q	journal	March 2005
Cationic Bis-cyclometalated Iridium(III) Diimine Complexes and Their Use in Efficient Blue, Green, and Red Electroluminescent Devices Tamayo, Arnold B.; Garon, Simona; Sajoto, Tissa Inorganic Chemistry, Vol. 44, Issue 24 https://doi.org/10.1021/ic050970t	journal	November 2005
Eilatin Complexes of Ruthenium and Osmium. Synthesis, Electrochemical Behavior, and Near-IR Luminescence Bergman, Sheba D.; Gut, Dalia; Kol, Moshe Inorganic Chemistry, Vol. 44, Issue 22 https://doi.org/10.1021/ic051022v	journal	September 2005
Photophysical Properties of Ruthenium(II) Tris(2,2‘-bipyridine) Complexes Bearing Conjugated Thiophene Appendages Harriman, Anthony; Izzet, Guillaume; Goeb, Sébastien Inorganic Chemistry, Vol. 45, Issue 24 https://doi.org/10.1021/ic060921w	journal	October 2006
The Triplet State of fac -Ir(ppy) ₃ Hofbeck, Thomas; Yersin, Hartmut Inorganic Chemistry, Vol. 49, Issue 20 https://doi.org/10.1021/ic100872w	journal	October 2010
Panchromic Cationic Iridium(III) Complexes Hasan, Kamrul; Zysman-Colman, Eli Inorganic Chemistry, Vol. 51, Issue 22 https://doi.org/10.1021/ic301998t	journal	November 2012
The (N ₄ C ₂ ) ^2– Donor Set as Promising Motif for Bis(tridentate) Iron(II) Photoactive Compounds Dixon, Isabelle M.; Alary, Fabienne; Boggio-Pasqua, Martial Inorganic Chemistry, Vol. 52, Issue 23 https://doi.org/10.1021/ic402453p	journal	November 2013
Molecular Orbital Calculation and Spectroscopic Study of the Photochemical Generation of Bis(2,2‘-bipyridine)rhodium(I) from Bis(2,2‘-bipyridine)(oxalato)rhodium(III) Shinozaki, Kazuteru; Takahashi, Naoto Inorganic Chemistry, Vol. 35, Issue 13 https://doi.org/10.1021/ic950939z	journal	January 1996
Effect of Delocalization and Rigidity in the Acceptor Ligand on MLCT Excited-State Decay Treadway, Joseph A.; Loeb, Barbara; Lopez, Rosa Inorganic Chemistry, Vol. 35, Issue 8 https://doi.org/10.1021/ic950961s	journal	January 1996
Synthesis and Liquid-Crystalline Properties of Diazabutadiene Complexes of Rhenium(I) Morrone, Stefania; Guillon, Daniel; Bruce, Duncan W. Inorganic Chemistry, Vol. 35, Issue 24 https://doi.org/10.1021/ic960478x	journal	January 1996
Design of Long-Lived Ru(II) Terpyridine MLCT States. Tricyano Terpyridine Complexes Indelli, Maria Teresa; Bignozzi, Carlo Alberto; Scandola, Franco Inorganic Chemistry, Vol. 37, Issue 23 https://doi.org/10.1021/ic980060u	journal	November 1998
A Bibenzimidazole-Containing Ruthenium(II) Complex Acting as a Cation-Driven Molecular Switch Rau, Sven; Büttner, Torsten; Temme, Christian Inorganic Chemistry, Vol. 39, Issue 7 https://doi.org/10.1021/ic991225h	journal	March 2000
Solvent effects on the photoisomerization rates of the zwitterionic and the cationic forms of rhodamine B in protic solvents Chang, Tzyh Lee; Cheung, Herbert C. The Journal of Physical Chemistry, Vol. 96, Issue 12 https://doi.org/10.1021/j100191a028	journal	June 1992
Solvent effects on emission yield and lifetime for coumarin laser dyes. Requirements for a rotatory decay mechanism Jones, Guilford; Jackson, William R.; Choi, Chol Yoo The Journal of Physical Chemistry, Vol. 89, Issue 2 https://doi.org/10.1021/j100248a024	journal	January 1985
A molecular light switch for DNA: Ru(bpy)2(dppz)2+ Friedman, Alan E.; Chambron, Jean Claude; Sauvage, Jean Pierre Journal of the American Chemical Society, Vol. 112, Issue 12 https://doi.org/10.1021/ja00168a052	journal	June 1990
The effect on MLCT excited states of electronic delocalization in the acceptor ligand Boyde, Stephen; Strouse, Geoffrey F.; Jones, Wayne E. Journal of the American Chemical Society, Vol. 112, Issue 20 https://doi.org/10.1021/ja00176a049	journal	September 1990
Synthetic design of MLCT excited states. Ligand-substituted, mono-2,2'-bipyridine complexes of ruthenium(II) Bargawi, Khaled R.; Llobet, Antoni.; Meyer, Thomas J. Journal of the American Chemical Society, Vol. 110, Issue 23 https://doi.org/10.1021/ja00231a027	journal	November 1988
Coordination characteristics of four isomeric .alpha.-diimine ligands. .pi. Molecular orbital perturbation calculations for the bidiazines and their correlation with the properties of group 6 metal carbonyl complexes Ernst, Sylvia.; Kaim, Wolfgang. Journal of the American Chemical Society, Vol. 108, Issue 13 https://doi.org/10.1021/ja00273a005	journal	June 1986
Engineering of Efficient Panchromatic Sensitizers for Nanocrystalline TiO ₂ -Based Solar Cells Nazeeruddin, Mohammad K.; Péchy, Peter; Renouard, Thierry Journal of the American Chemical Society, Vol. 123, Issue 8 https://doi.org/10.1021/ja003299u	journal	February 2001
Application of the energy gap law to the decay of charge-transfer excited states Caspar, Jonathan V.; Kober, Edward M.; Sullivan, B. Patrick Journal of the American Chemical Society, Vol. 104, Issue 2 https://doi.org/10.1021/ja00366a051	journal	January 1982
Highly Phosphorescence Iridium Complexes and Their Application in Organic Light-Emitting Devices Nazeeruddin, Md. K.; Humphry-Baker, R.; Berner, D. Journal of the American Chemical Society, Vol. 125, Issue 29 https://doi.org/10.1021/ja021413y	journal	July 2003
Ultrafast Processes in Bimetallic Dyads with Extended Aromatic Bridges. Energy and Electron Transfer Pathways in Tetrapyridophenazine-Bridged Complexes Chiorboli, Claudio; Rodgers, Michael A. J.; Scandola, Franco Journal of the American Chemical Society, Vol. 125, Issue 2 https://doi.org/10.1021/ja0284916	journal	January 2003
Photochromic and Luminescence Switching Properties of a Versatile Diarylethene-Containing 1,10-Phenanthroline Ligand and Its Rhenium(I) Complex Yam, Vivian Wing-Wah; Ko, Chi-Chiu; Zhu, Nianyong Journal of the American Chemical Society, Vol. 126, Issue 40 https://doi.org/10.1021/ja047446q	journal	September 2004
Complexed Nitrogen Heterosuperbenzene: The Coordinating Properties of a Remarkable Ligand Draper, Sylvia M.; Gregg, Daniel J.; Schofield, Emma R. Journal of the American Chemical Society, Vol. 126, Issue 28 https://doi.org/10.1021/ja0491634	journal	June 2004
Bespoke Photoreductants: Tungsten Arylisocyanides Sattler, Wesley; Henling, Lawrence M.; Winkler, Jay R. Journal of the American Chemical Society, Vol. 137, Issue 3 https://doi.org/10.1021/ja510973h	journal	January 2015
First Observation of the Key Intermediate in the “Light-Switch” Mechanism of [Ru(phen) ₂ dppz] ²⁺ Olson, E. J. C.; Hu, D.; Hörmann, A. Journal of the American Chemical Society, Vol. 119, Issue 47 https://doi.org/10.1021/ja971151d	journal	November 1997
Effects of Intraligand Electron Delocalization, Steric Tuning, and Excited-State Vibronic Coupling on the Photophysics of Aryl-Substituted Bipyridyl Complexes of Ru(II) Damrauer, Niels H.; Boussie, Thomas R.; Devenney, Martin Journal of the American Chemical Society, Vol. 119, Issue 35 https://doi.org/10.1021/ja971321m	journal	September 1997
Microsecond Photoluminescence and Photoreactivity of a Metal-Centered Excited State in a Hexacarbene–Co(III) Complex Kaufhold, Simon; Rosemann, Nils W.; Chábera, Pavel Journal of the American Chemical Society, Vol. 143, Issue 3 https://doi.org/10.1021/jacs.0c12151	journal	January 2021
A Photorobust Mo(0) Complex Mimicking [Os(2,2′-bipyridine) ₃ ] ²⁺ and Its Application in Red-to-Blue Upconversion Bilger, Jakob B.; Kerzig, Christoph; Larsen, Christopher B. Journal of the American Chemical Society, Vol. 143, Issue 3 https://doi.org/10.1021/jacs.0c12805	journal	January 2021
Strongly Red-Emissive Molecular Ruby [Cr(bpmp) ₂ ] ³⁺ Surpasses [Ru(bpy) ₃ ] ²⁺ Reichenauer, Florian; Wang, Cui; Förster, Christoph Journal of the American Chemical Society, Vol. 143, Issue 30 https://doi.org/10.1021/jacs.1c05971	journal	July 2021
Reduction of Electron Repulsion in Highly Covalent Fe-Amido Complexes Counteracts the Impact of a Weak Ligand Field on Excited-State Ordering Larsen, Christopher B.; Braun, Jason D.; Lozada, Issiah B. Journal of the American Chemical Society, Vol. 143, Issue 49 https://doi.org/10.1021/jacs.1c06429	journal	December 2021
Pyrene-Decoration of a Chromium(0) Tris(diisocyanide) Enhances Excited State Delocalization: A Strategy to Improve the Photoluminescence of 3d⁶ Metal Complexes Wegeberg, Christina; Häussinger, Daniel; Wenger, Oliver S. Journal of the American Chemical Society, Vol. 143, Issue 38, p. 15800-15811 https://doi.org/10.1021/jacs.1c07345	journal	September 2021
A Photoreactive Iron(II) Complex Luminophore Leis, Wolfgang; Argüello Cordero, Miguel A.; Lochbrunner, Stefan Journal of the American Chemical Society, Vol. 144, Issue 3 https://doi.org/10.1021/jacs.1c13083	journal	January 2022
Cobalt(III) Carbene Complex with an Electronic Excited-State Structure Similar to Cyclometalated Iridium(III) Compounds Sinha, Narayan; Pfund, Björn; Wegeberg, Christina Journal of the American Chemical Society, Vol. 144, Issue 22 https://doi.org/10.1021/jacs.2c02592	journal	May 2022
Ligand-Field Spectroscopy of Co(III) Complexes and the Development of a Spectrochemical Series for Low-Spin d⁶Charge-Transfer Chromophores Yarranton, Jonathan T.; McCusker, James K. Journal of the American Chemical Society, Vol. 144, Issue 27 https://doi.org/10.1021/jacs.2c04945	journal	June 2022
Photoactive Metal-to-Ligand Charge Transfer Excited States in 3d⁶ Complexes with Cr⁰, Mn^I, Fe^II, and Co^III Sinha, Narayan; Wenger, Oliver S. Journal of the American Chemical Society, Vol. 145, Issue 9 https://doi.org/10.1021/jacs.2c13432	journal	February 2023
Nanosecond Metal-to-Ligand Charge-Transfer State in an Fe(II) Chromophore: Lifetime Enhancement via Nested Potentials Malme, Justin T.; Clendening, Reese A.; Ash, Ryan Journal of the American Chemical Society, Vol. 145, Issue 11 https://doi.org/10.1021/jacs.2c13532	journal	March 2023
Stable Molybdenum(0) Carbonyl Complex for Upconversion and Photoredox Catalysis Kitzmann, Winald R.; Bertrams, Maria-Sophie; Boden, Pit Journal of the American Chemical Society, Vol. 145, Issue 30 https://doi.org/10.1021/jacs.3c03832	journal	July 2023
Beyond the First Coordination Sphere─Manipulating the Excited-State Landscape in Iron(II) Chromophores with Protons Witas, Kamil; Nair, Shruthi Santhosh; Maisuradze, Tamar Journal of the American Chemical Society, Vol. 146, Issue 29 https://doi.org/10.1021/jacs.4c00552	journal	July 2024
Interfacial Electrochemistry of Catalyst-Coordinated Graphene Nanoribbons Askins, Erik J.; Sarkar, Abdul; Navabi, Pouyan Journal of the American Chemical Society, Vol. 146, Issue 32 https://doi.org/10.1021/jacs.4c05250	journal	August 2024
Well-Defined Nanographene–Rhenium Complex as an Efficient Electrocatalyst and Photocatalyst for Selective CO ₂ Reduction Qiao, Xiaoxiao; Li, Qiqi; Schaugaard, Richard N. Journal of the American Chemical Society, Vol. 139, Issue 11 https://doi.org/10.1021/jacs.6b12530	journal	March 2017
New Rh ₂ (II,II) Complexes for Solar Energy Applications: Panchromatic Absorption and Excited-State Reactivity Whittemore, Tyler J.; Sayre, Hannah J.; Xue, Congcong Journal of the American Chemical Society, Vol. 139, Issue 41 https://doi.org/10.1021/jacs.7b08489	journal	October 2017
New Ligand Design Provides Delocalization and Promotes Strong Absorption throughout the Visible Region in a Ru(II) Complex Whittemore, Tyler J.; White, Travis A.; Turro, Claudia Journal of the American Chemical Society, Vol. 140, Issue 1 https://doi.org/10.1021/jacs.7b09389	journal	December 2017
Highly Efficient Red-Emitting Bis-Cyclometalated Iridium Complexes Lai, Po-Ni; Brysacz, Caroline H.; Alam, Md Kamrul Journal of the American Chemical Society, Vol. 140, Issue 32 https://doi.org/10.1021/jacs.8b04841	journal	July 2018
Photochemical Resolution of a Thermally Inert Cyclometalated Ru(phbpy)(N–N)(Sulfoxide) ⁺ Complex Lameijer, Lucien N.; van de Griend, Corjan; Hopkins, Samantha L. Journal of the American Chemical Society, Vol. 141, Issue 1 https://doi.org/10.1021/jacs.8b10264	journal	December 2018
Ligand Mediated Luminescence Enhancement in Cyclometalated Rhodium(III) Complexes and Their Applications in Efficient Organic Light-Emitting Devices Wei, Fangfang; Lai, Shiu-Lun; Zhao, Shunan Journal of the American Chemical Society, Vol. 141, Issue 32 https://doi.org/10.1021/jacs.9b06308	journal	July 2019
The Effect of Reduction on Rhenium(I) Complexes with Binaphthyridine and Biquinoline Ligands: A Spectroscopic and Computational Study Howell, Sarah L.; Scott, Sonya M.; Flood, Amar H. The Journal of Physical Chemistry A, Vol. 109, Issue 16 https://doi.org/10.1021/jp0502252	journal	March 2005
The δ in 18 + δ Electron Complexes: Importance of the Metal/Ligand Interface for the Substitutional Reactivity of “Re(0)” Complexes (α-diimine ^- )Re ^I (CO) ₃ (X) Klein, Axel; Vogler, Conny; Kaim, Wolfgang Organometallics, Vol. 15, Issue 1 https://doi.org/10.1021/om950500e	journal	January 1996
A low-spin Fe(iii) complex with 100-ps ligand-to-metal charge transfer photoluminescence Chábera, Pavel; Liu, Yizhu; Prakash, Om Nature, Vol. 543, Issue 7647 https://doi.org/10.1038/nature21430	journal	March 2017
Iron(ii) coordination complexes with panchromatic absorption and nanosecond charge-transfer excited state lifetimes Braun, Jason D.; Lozada, Issiah B.; Kolodziej, Charles Nature Chemistry, Vol. 11, Issue 12 https://doi.org/10.1038/s41557-019-0357-z	journal	November 2019
Manganese(i) complexes with metal-to-ligand charge transfer luminescence and photoreactivity Herr, Patrick; Kerzig, Christoph; Larsen, Christopher B. Nature Chemistry, Vol. 13, Issue 10 https://doi.org/10.1038/s41557-021-00744-9	journal	August 2021
Active repair of a dinuclear photocatalyst for visible-light-driven hydrogen production Pfeffer, Michael G.; Müller, Carolin; Kastl, Evelyn T. E. Nature Chemistry, Vol. 14, Issue 5 https://doi.org/10.1038/s41557-021-00860-6	journal	February 2022
Photoredox-active Cr(0) luminophores featuring photophysical properties competitive with Ru(II) and Os(II) complexes Sinha, Narayan; Wegeberg, Christina; Häussinger, Daniel Nature Chemistry https://doi.org/10.1038/s41557-023-01297-9	journal	August 2023
Solving the oxygen sensitivity of sensitized photon upconversion in life science applications Askes, Sven H. C.; Bonnet, Sylvestre Nature Reviews Chemistry, Vol. 2, Issue 12 https://doi.org/10.1038/s41570-018-0057-z	journal	November 2018
Triplet–triplet annihilation photon upconversion-mediated photochemical reactions Huang, Ling; Han, Gang Nature Reviews Chemistry, Vol. 8, Issue 4 https://doi.org/10.1038/s41570-024-00585-3	journal	March 2024
Photoinduced electron transfer across molecular bridges: electron- and hole-transfer superexchange pathways Natali, Mirco; Campagna, Sebastiano; Scandola, Franco Chem. Soc. Rev., Vol. 43, Issue 12 https://doi.org/10.1039/C3CS60463B	journal	January 2014
Exceptionally rapid CO release from a manganese(i) tricarbonyl complex derived from bis(4-chloro-phenylimino)acenaphthene upon exposure to visible light Carrington, Samantha J.; Chakraborty, Indranil; Mascharak, Pradip K. Dalton Transactions, Vol. 44, Issue 31 https://doi.org/10.1039/C5DT01007A	journal	January 2015
Proton coupled electron transfer from the excited state of a ruthenium( ii ) pyridylimidazole complex Pannwitz, Andrea; Wenger, Oliver S. Physical Chemistry Chemical Physics, Vol. 18, Issue 16 https://doi.org/10.1039/C6CP00437G	journal	January 2016
A new record excited state ³ MLCT lifetime for metalorganic iron( ii ) complexes Liu, Li; Duchanois, Thibaut; Etienne, Thibaud Physical Chemistry Chemical Physics, Vol. 18, Issue 18 https://doi.org/10.1039/C6CP01418F	journal	January 2016
The photophysics of photoredox catalysis: a roadmap for catalyst design Arias-Rotondo, Daniela M.; McCusker, James K. Chemical Society Reviews, Vol. 45, Issue 21 https://doi.org/10.1039/C6CS00526H	journal	January 2016
Red-light activated photoCORMs of Mn(i) species bearing electron deficient 2,2′-azopyridines Kottelat, E.; Ruggi, A.; Zobi, F. Dalton Transactions, Vol. 45, Issue 16 https://doi.org/10.1039/C6DT00858E	journal	January 2016
Ruthenium(ii) complexes with dppz: from molecular photoswitch to biological applications Li, Guanying; Sun, Lingli; Ji, Liangnian Dalton Transactions, Vol. 45, Issue 34 https://doi.org/10.1039/C6DT01624C	journal	January 2016
Manipulating charge transfer excited state relaxation and spin crossover in iron coordination complexes with ligand substitution Zhang, Wenkai; Kjær, Kasper S.; Alonso-Mori, Roberto Chemical Science, Vol. 8, Issue 1 https://doi.org/10.1039/C6SC03070J	journal	January 2017
Solvent control of charge transfer excited state relaxation pathways in [Fe(2,2′-bipyridine)(CN) ₄ ] ²⁻ Kjær, Kasper S.; Kunnus, Kristjan; Harlang, Tobias C. B. Physical Chemistry Chemical Physics, Vol. 20, Issue 6 https://doi.org/10.1039/C7CP07838B	journal	January 2018
Exploiting the benefit of S₀ → T₁ excitation in triplet–triplet annihilation upconversion to attain large anti-stokes shifts: tuning the triplet state lifetime of a tris(2,2′-bipyridine) osmium(ii) complex Liu, Dongyi; Zhao, Yingjie; Wang, Zhijia Dalton Transactions, Vol. 47, Issue 26 https://doi.org/10.1039/C7DT04803C	journal	January 2018
A cyanide-bridged di-manganese carbonyl complex that photochemically reduces CO ₂ to CO Kuo, Hsin-Ya; Lee, Tia S.; Chu, An T. Dalton Transactions, Vol. 48, Issue 4 https://doi.org/10.1039/C8DT03358G	journal	January 2019
Conjugated, rigidified bibenzimidazole ancillary ligands for enhanced photoluminescence quantum yields of orange/red-emitting iridium(iii) complexes Henwood, Adam F.; Antón-García, Daniel; Morin, Mégane Dalton Transactions, Vol. 48, Issue 26 https://doi.org/10.1039/C9DT00423H	journal	January 2019
Iron( ii ) complexes with diazinyl-NHC ligands: impact of π-deficiency of the azine core on photophysical properties Darari, Mohamed; Domenichini, Edoardo; Francés-Monerris, Antonio Dalton Transactions, Vol. 48, Issue 29 https://doi.org/10.1039/C9DT01731C	journal	January 2019
Efficient near-infrared luminescence from bis-cyclometalated iridium(iii) complexes with rigid quinoline-derived ancillary ligands Lai, Po-Ni; Yoon, Sungwon; Teets, Thomas S. Chemical Communications, Vol. 56, Issue 62 https://doi.org/10.1039/D0CC02745F	journal	January 2020
Red to near-infrared phosphorescent Ir(iii) complexes with electron-rich chelating ligands Yoon, Sungwon; Teets, Thomas S. Chemical Communications, Vol. 57, Issue 16 https://doi.org/10.1039/D0CC08067E	journal	January 2021
Panchromatic dirhodium photocatalysts for dihydrogen generation with red light Huang, Jie; Gallucci, Judith C.; Turro, Claudia Chemical Science, Vol. 11, Issue 36 https://doi.org/10.1039/D0SC03114C	journal	January 2020
Dye-sensitized solar cells based on Fe N-heterocyclic carbene photosensitizers with improved rod-like push-pull functionality Lindh, Linnea; Gordivska, Olga; Persson, Samuel Chemical Science, Vol. 12, Issue 48 https://doi.org/10.1039/D1SC02963K	journal	January 2021
Balancing the interplay between ligand ejection and therapeutic window light absorption in ruthenium polypyridyl complexes McCullough, Annie B.; Chen, Jiaqi; Valentine, Nathaniel P. Dalton Transactions, Vol. 51, Issue 26 https://doi.org/10.1039/D2DT01237E	journal	January 2022
Designing tridentate ligands for ruthenium(ii) complexes with prolonged room temperature luminescence lifetimes Medlycott, Elaine A.; Hanan, Garry S. Chemical Society Reviews, Vol. 34, Issue 2 https://doi.org/10.1039/b316486c	journal	January 2005
Contemporary progresses on neutral, highly emissive Os(ii) and Ru(ii) complexes Chi, Yun; Chou, Pi-Tai Chemical Society Reviews, Vol. 36, Issue 9 https://doi.org/10.1039/b608951h	journal	January 2007
Photoinduced CO release, cellular uptake and cytotoxicity of a tris(pyrazolyl)methane (tpm) manganese tricarbonyl complex Niesel, Johanna; Pinto, Antonio; Peindy N'Dongo, Harmel W. Chemical Communications, Issue 15 https://doi.org/10.1039/b719075a	journal	January 2008
The Golden Rule. Application for fun and profit in electron transfer, energy transfer, and excited-state decay Ito, Akitaka; Meyer, Thomas J. Physical Chemistry Chemical Physics, Vol. 14, Issue 40 https://doi.org/10.1039/c2cp41658a	journal	January 2012
Rapid CO release from a Mn(i) carbonyl complex derived from azopyridine upon exposure to visible light and its phototoxicity toward malignant cells Carrington, Samantha J.; Chakraborty, Indranil; Mascharak, Pradip K. Chemical Communications, Vol. 49, Issue 96 https://doi.org/10.1039/c3cc46558f	journal	January 2013
Near infra-red emission from a mer-Ru(ii) complex: consequences of strong σ-donation from a neutral, flexible ligand with dual binding modes Pal, Amlan K.; Zaccheroni, Nelsi; Campagna, Sebastiano Chemical Communications, Vol. 50, Issue 52 https://doi.org/10.1039/c3cc49880h	journal	January 2014
Bright orange/red-emitting rhodium(iii) and iridium(iii) complexes: tridentate N^C^N-cyclometallating ligands lead to high luminescence efficiencies Gildea, Louise F.; Batsanov, Andrei S.; Williams, J. A. Gareth Dalton Transactions, Vol. 42, Issue 29 https://doi.org/10.1039/c3dt51211h	journal	January 2013
Intriguing aspects of lanthanide luminescence Bünzli, Jean-Claude G.; Eliseeva, Svetlana V. Chemical Science, Vol. 4, Issue 5 https://doi.org/10.1039/c3sc22126a	journal	January 2013
Characterization of electronic transitions in complex molecules Kasha, Michael Discussions of the Faraday Society, Vol. 9 https://doi.org/10.1039/df9500900014	journal	January 1950
Effect of solvent polarity on a rotational isomerization mechanism of rhodamine-B in normal alcohols Chang, Tzyh-Lee; Borst, Walter L. The Journal of Chemical Physics, Vol. 93, Issue 7 https://doi.org/10.1063/1.458662	journal	October 1990
The energy gap law for radiationless transitions in large molecules Englman, Robert; Jortner, Joshua Molecular Physics, Vol. 18, Issue 2 https://doi.org/10.1080/00268977000100171	journal	February 1970
Luminescence and reactivity of a charge-transfer excited iron complex with nanosecond lifetime Kjær, Kasper Skov; Kaul, Nidhi; Prakash, Om Science, Vol. 363, Issue 6424 https://doi.org/10.1126/science.aau7160	journal	November 2018
When is a pyridine not a pyridine? Benzannulated N-heterocyclic ligands in molecular materials chemistry Herbert, David E. Canadian Journal of Chemistry, Vol. 101, Issue 12 https://doi.org/10.1139/cjc-2022-0314	journal	December 2023
Red Light Activation of Ru(II) Polypyridyl Prodrugs via Triplet-Triplet Annihilation Upconversion: Feasibility in Air and through Meat Askes, Sven; Meijer, Michael; Bouwens, Tessel Molecules, Vol. 21, Issue 11 https://doi.org/10.3390/molecules21111460	journal	November 2016
Red Light Absorption of [ReI(CO)3(α-diimine)Cl] Complexes through Extension of the 4,4′-Bipyrimidine Ligand’s π-System Meitinger, Nicolas; Mandal, Subrata; Sorsche, Dieter Molecules, Vol. 28, Issue 4 https://doi.org/10.3390/molecules28041905	journal	February 2023
Pyridinamides in Asymmetric Catalysis. Moberg, Christina; Adolfsson, Hans; Wärnmark, Kenneth Acta Chemica Scandinavica, Vol. 50 https://doi.org/10.3891/acta.chem.scand.50-0195	journal	January 1996
Synthesis and Characterization of Novel Re(BIAN)(CO)₃Cl Derivatives Including the First Example of a Water-soluble Tricarbonyl Rhenium(I) Complex with Bis(imino)acenaphthene Ligands Kianfar, Elham; Monkowius, Uwe; Portenkirchner, Engelbert Zeitschrift für Naturforschung B, Vol. 69, Issue 6 https://doi.org/10.5560/znb.2014-4016	journal	June 2014

Similar Records

Time-resolved infrared spectroscopy of MLCT excited states

Conference · 1997 · OSTI ID:560206

Omberg, K M; Schoonover, J R; Dyer, R B; +1 more

Electronic structure and photophysics of a supermolecular iron complex having a long MLCT-state lifetime and panchromatic absorption

Journal Article · 2020 · Proceedings of the National Academy of Sciences of the United States of America · OSTI ID:1801488

Jiang, Ting; Bai, Yusong; Zhang, Peng; +3 more

Energy Migration Processes in Re(I) MLCT Complexes Featuring a Chromophoric Ancillary Ligand

Journal Article · 2020 · Inorganic Chemistry · OSTI ID:1633645

Wells, Kaylee A.; Yarnell, James E.; Palmer, Jonathan R.; +3 more

Related Subjects

Metal to ligand charge transfer (MLCT)
NIR
Photochemistry
Red-shift
d6 metal complexes

Title: Shifting the MLCT of d6 metal complexes to the red and NIR

Citation Formats

References (206)

Similar Records

Related Subjects

Title: Shifting the MLCT of d⁶ metal complexes to the red and NIR