Fabrication, morphology, and performance of fiber mat cathode MEAs with a MOF-based PGM-free catalyst

Xu, Xiaomin; Zulevi, Barr; Serov, Alexey; Pintauro, Peter N.

doi:10.1016/j.ijhydene.2025.01.356

Title: Fabrication, morphology, and performance of fiber mat cathode MEAs with a MOF-based PGM-free catalyst

Journal Article · 01 March 2025 · International Journal of Hydrogen Energy

DOI: https://doi.org/10.1016/j.ijhydene.2025.01.356 · OSTI ID:2510899

; Zulevi, Barr; Serov, Alexey;

Not Available

View Journal Article

Cite

Export

Save

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

OSTI ID:: 2510899

Journal Information:: International Journal of Hydrogen Energy, Journal Name: International Journal of Hydrogen Energy Journal Issue: C Vol. 105; ISSN 0360-3199

Publisher:: ElsevierCopyright Statement

Country of Publication:: United Kingdom

Language:: English

References (43)

Unraveling the Nature of Sites Active toward Hydrogen Peroxide Reduction in Fe-N-C Catalysts Choi, Chang Hyuck; Choi, Won Seok; Kasian, Olga Angewandte Chemie International Edition, Vol. 56, Issue 30 https://doi.org/10.1002/anie.201704356	journal	June 2017
Electrospun Fiber Mat Cathode with Platinum‐Group‐Metal‐Free Catalyst Powder and Nafion/PVDF Binder Slack, John; Halevi, Barr; McCool, Geoff ChemElectroChem, Vol. 5, Issue 12 https://doi.org/10.1002/celc.201800283	journal	April 2018
Process influences on the structure, piezoelectric, and gas-barrier properties of PVDF-TrFE copolymer Oliveira, Fabiane; Leterrier, Yves; Månson, Jan-Anders Journal of Polymer Science Part B: Polymer Physics, Vol. 52, Issue 7 https://doi.org/10.1002/polb.23443	journal	January 2014
Design of PGM-free cathodic catalyst layers for advanced PEM fuel cells Reshetenko, Tatyana; Odgaard, Madeleine; Randolf, Günter Applied Catalysis B: Environmental, Vol. 312 https://doi.org/10.1016/j.apcatb.2022.121424	journal	September 2022
Durability challenges and perspective in the development of PGM-free electrocatalysts for the oxygen reduction reaction Martinez, Ulises; Komini Babu, Siddharth; Holby, Edward F. Current Opinion in Electrochemistry, Vol. 9 https://doi.org/10.1016/j.coelec.2018.04.010	journal	June 2018
Optimization of gas diffusion electrode for polybenzimidazole-based high temperature proton exchange membrane fuel cell: Evaluation of polymer binders in catalyst layer Su, Huaneng; Pasupathi, Sivakumar; Bladergroen, Bernard International Journal of Hydrogen Energy, Vol. 38, Issue 26 https://doi.org/10.1016/j.ijhydene.2013.06.107	journal	August 2013
Novel superhydrophobic microporous layers for enhanced performance and efficient water management in PEM fuel cells Latorrata, Saverio; Gallo Stampino, Paola; Cristiani, Cinzia International Journal of Hydrogen Energy, Vol. 39, Issue 10 https://doi.org/10.1016/j.ijhydene.2013.12.199	journal	March 2014
Influence of FEP nanoparticles in catalyst layer on water management and performance of PEM fuel cell with high Pt loading Avcioglu, Gokce S.; Ficicilar, Berker; Eroglu, Inci International Journal of Hydrogen Energy, Vol. 42, Issue 1 https://doi.org/10.1016/j.ijhydene.2016.11.037	journal	January 2017
Impact of ionomer resistance in nanofiber-nanoparticle electrodes for ultra-low platinum fuel cells Hwang, Monica; Elabd, Yossef A. International Journal of Hydrogen Energy, Vol. 44, Issue 12 https://doi.org/10.1016/j.ijhydene.2019.01.083	journal	March 2019
Water management characteristics of electrospun micro-porous layer in PEMFC under normal temperature and cold start conditions Li, Chaoming; Si, Dechun; Liu, Yadi International Journal of Hydrogen Energy, Vol. 46, Issue 19 https://doi.org/10.1016/j.ijhydene.2020.05.271	journal	March 2021
Cold start capability and durability of electrospun catalyst layer for proton exchange membrane fuel cell Liu, Han; Si, Dechun; Ding, Han International Journal of Hydrogen Energy, Vol. 46, Issue 19 https://doi.org/10.1016/j.ijhydene.2020.06.032	journal	March 2021
Highly durable platinum group metal-free catalyst fiber cathode MEAs for proton exchange membrane fuel cells Xu, Xiaomin; Kang, Nalae; Zulevi, Barr Journal of Power Sources, Vol. 586 https://doi.org/10.1016/j.jpowsour.2023.233679	journal	December 2023
Nafion/PVDF nanofiber composite membranes for regenerative hydrogen/bromine fuel cells Park, Jun Woo; Wycisk, Ryszard; Pintauro, Peter N. Journal of Membrane Science, Vol. 490 https://doi.org/10.1016/j.memsci.2015.04.044	journal	September 2015
Electrospun Nafion/PVDF single-fiber blended membranes for regenerative H2/Br2 fuel cells Woo Park, Jun; Wycisk, Ryszard; Lin, Guangyu Journal of Membrane Science, Vol. 541 https://doi.org/10.1016/j.memsci.2017.06.086	journal	November 2017
Spectroscopic insights into the nature of active sites in iron–nitrogen–carbon electrocatalysts for oxygen reduction in acid Jia, Qingying; Ramaswamy, Nagappan; Tylus, Urszula Nano Energy, Vol. 29 https://doi.org/10.1016/j.nanoen.2016.03.025	journal	November 2016
Engineering nanostructures of PGM-free oxygen-reduction catalysts using metal-organic frameworks Zhang, Hanguang; Osgood, Hannah; Xie, Xiaohong Nano Energy, Vol. 31 https://doi.org/10.1016/j.nanoen.2016.11.033	journal	January 2017
Improving the bulk gas transport of Fe-N-C platinum group metal-free nanofiber electrodes via electrospinning for fuel cell applications Kabir, Sadia; Medina, Samantha; Wang, Guanxiong Nano Energy, Vol. 73 https://doi.org/10.1016/j.nanoen.2020.104791	journal	July 2020
Free volume and permeabilities of O2 and H2 in Nafion membranes for polymer electrolyte fuel cells Mohamed, Hamdy F. M.; Ito, K.; Kobayashi, Y. Polymer, Vol. 49, Issue 13-14 https://doi.org/10.1016/j.polymer.2008.05.003	journal	June 2008
ElectroCat: DOE's approach to PGM-free catalyst and electrode R&D Thompson, Simon T.; Wilson, Adria R.; Zelenay, Piotr Solid State Ionics, Vol. 319 https://doi.org/10.1016/j.ssi.2018.01.030	journal	June 2018
Fourteen-Membered Macrocyclic Fe Complexes Inspired by FeN₄-Center-Embedded Graphene for Oxygen Reduction Catalysis Moriya, Makoto; Takahama, Ryo; Kamoi, Kazuki The Journal of Physical Chemistry C, Vol. 124, Issue 38 https://doi.org/10.1021/acs.jpcc.0c05536	journal	August 2020
Role of Local Carbon Structure Surrounding FeN ₄ Sites in Boosting the Catalytic Activity for Oxygen Reduction Liu, Kexi; Wu, Gang; Wang, Guofeng The Journal of Physical Chemistry C, Vol. 121, Issue 21 https://doi.org/10.1021/acs.jpcc.7b00913	journal	May 2017
High Power Density Platinum Group Metal-free Cathodes for Polymer Electrolyte Fuel Cells Uddin, Aman; Dunsmore, Lisa; Zhang, Hanguang ACS Applied Materials & Interfaces, Vol. 12, Issue 2 https://doi.org/10.1021/acsami.9b13945	journal	December 2019
High Durability of a 14-Membered Hexaaza Macrocyclic Fe Complex for an Acidic Oxygen Reduction Reaction Revealed by In Situ XAS Analysis Ohyama, Junya; Moriya, Makoto; Takahama, Ryo JACS Au, Vol. 1, Issue 10 https://doi.org/10.1021/jacsau.1c00309	journal	September 2021
Kinetic Analysis of Oxygen Reduction on Pt(111) in Acid Solutions: Intrinsic Kinetic Parameters and Anion Adsorption Effects Wang, J. X.; Markovic, N. M.; Adzic, R. R. The Journal of Physical Chemistry B, Vol. 108, Issue 13, p. 4127-4133 https://doi.org/10.1021/jp037593v	journal	April 2004
Effect of Water on the Low Temperature Conductivity of Polymer Electrolytes Siu, Ana; Schmeisser, Jennifer; Holdcroft, Steven The Journal of Physical Chemistry B, Vol. 110, Issue 12 https://doi.org/10.1021/jp0531208	journal	March 2006
O ₂ Reduction Mechanism on Non-Noble Metal Catalysts for PEM Fuel Cells. Part I: Experimental Rates of O ₂ Electroreduction, H ₂ O ₂ Electroreduction, and H ₂ O ₂ Disproportionation Jaouen, Frédéric; Dodelet, Jean-Pol The Journal of Physical Chemistry C, Vol. 113, Issue 34 https://doi.org/10.1021/jp900837e	journal	July 2009
Atomically dispersed iron sites with a nitrogen–carbon coating as highly active and durable oxygen reduction catalysts for fuel cells Liu, Shengwen; Li, Chenzhao; Zachman, Michael J. Nature Energy, Vol. 7, Issue 7 https://doi.org/10.1038/s41560-022-01062-1	journal	July 2022
Identification of durable and non-durable FeNx sites in Fe–N–C materials for proton exchange membrane fuel cells Li, Jingkun; Sougrati, Moulay Tahar; Zitolo, Andrea Nature Catalysis, Vol. 4, Issue 1 https://doi.org/10.1038/s41929-020-00545-2	journal	December 2020
Tuning the thermal activation atmosphere breaks the activity–stability trade-off of Fe–N–C oxygen reduction fuel cell catalysts Zeng, Yachao; Li, Chenzhao; Li, Boyang Nature Catalysis, Vol. 6, 1215-1227 https://doi.org/10.1038/s41929-023-01062-8	journal	December 2023
Following ORR intermediates adsorbed on a Pt cathode catalyst during break-in of a PEM fuel cell by in operando X-ray absorption spectroscopy Ramaker, D. E.; Korovina, A.; Croze, V. Phys. Chem. Chem. Phys., Vol. 16, Issue 27 https://doi.org/10.1039/C4CP00192C	journal	January 2014
A review of recent developments in membrane separators for rechargeable lithium-ion batteries Lee, Hun; Yanilmaz, Meltem; Toprakci, Ozan Energy Environ. Sci., Vol. 7, Issue 12 https://doi.org/10.1039/C4EE01432D	journal	January 2014
Size-controlled large-diameter and few-walled carbon nanotube catalysts for oxygen reduction Wang, Xianliang; Li, Qing; Pan, Hengyu Nanoscale, Vol. 7, Issue 47 https://doi.org/10.1039/C5NR05864C	journal	January 2015
Structural and mechanistic basis for the high activity of Fe–N–C catalysts toward oxygen reduction Li, Jingkun; Ghoshal, Shraboni; Liang, Wentao Energy & Environmental Science, Vol. 9, Issue 7 https://doi.org/10.1039/C6EE01160H	journal	January 2016
Is the rapid initial performance loss of Fe/N/C non precious metal catalysts due to micropore flooding? Choi, Ja-Yeon; Yang, Lijun; Kishimoto, Takeaki Energy & Environmental Science, Vol. 10, Issue 1 https://doi.org/10.1039/C6EE03005J	journal	January 2017
The Achilles' heel of iron-based catalysts during oxygen reduction in an acidic medium Choi, Chang Hyuck; Lim, Hyung-Kyu; Chung, Min Wook Energy & Environmental Science, Vol. 11, Issue 11 https://doi.org/10.1039/C8EE01855C	journal	January 2018
High-performance fuel cell cathodes exclusively containing atomically dispersed iron active sites Zhang, Hanguang; Chung, Hoon T.; Cullen, David A. Energy & Environmental Science, Vol. 12, Issue 8 https://doi.org/10.1039/C9EE00877B	journal	January 2019
Recent developments in nanostructured anode materials for rechargeable lithium-ion batteries Ji, Liwen; Lin, Zhan; Alcoutlabi, Mataz Energy & Environmental Science, Vol. 4, Issue 8, p. 2682-2699 https://doi.org/10.1039/c0ee00699h	journal	January 2011
Direct atomic-level insight into the active sites of a high-performance PGM-free ORR catalyst Chung, Hoon T.; Cullen, David A.; Higgins, Drew Science, Vol. 357, Issue 6350 https://doi.org/10.1126/science.aan2255	journal	August 2017
Thermodynamics and Proton Transport in Nafion Choi, Pyoungho; Jalani, Nikhil H.; Datta, Ravindra Journal of The Electrochemical Society, Vol. 152, Issue 3 https://doi.org/10.1149/1.1855872	journal	January 2005
Electrospun Nanofiber Electrodes for High and Low Humidity PEMFC Operation Waldrop, Krysta; Slack, John J.; Gumeci, Cenk Journal of The Electrochemical Society, Vol. 170, Issue 2 https://doi.org/10.1149/1945-7111/acb8e2	journal	February 2023
Nanofiber Fuel Cell MEAs with a PtCo/C Cathode Slack, J. J.; Gumeci, C.; Dale, N. Journal of The Electrochemical Society, Vol. 166, Issue 7 https://doi.org/10.1149/2.0151907jes	journal	January 2019
Power Output and Durability of Electrospun Fuel Cell Fiber Cathodes with PVDF and Nafion/PVDF Binders Brodt, Matthew; Wycisk, Ryszard; Dale, Nilesh Journal of The Electrochemical Society, Vol. 163, Issue 5 https://doi.org/10.1149/2.0711605jes	journal	January 2016
Varipore™: A Powerful Manufacturing Platform for Fuel Cell and Electrolyzer Applications Serov, Alexey; Lubers, Alia; McCool, Geoffrey ECS Meeting Abstracts, Vol. MA2019-02, Issue 37, p. 1734-1734 https://doi.org/10.1149/MA2019-02/37/1734	journal	September 2019

Similar Records

Effects of MEA Fabrication and Ionomer Composition on Fuel Cell Performance of PGM-Free ORR Catalyst

Journal Article · 2017 · ECS Transactions (Online) · OSTI ID:1463547

Yin, Xi; Lin, Ling; Chung, Hoon T.; +4 more

Impact of Fabrication and Testing Parameters on the Performance of a Polymer Electrolyte Fuel Cell with Platinum Group Metal (PGM)-Free Cathode Catalyst

Journal Article · 2021 · Journal of the Electrochemical Society (Online) · OSTI ID:1756466

Osmieri, Luigi; Wang, Hao; Neyerlin, Kenneth C.

Mesoporous Carbon-Based PGM-Free Catalyst Cathodes

Technical Report · 2022 · OSTI ID:2373188

Xie, Jian

Title: Fabrication, morphology, and performance of fiber mat cathode MEAs with a MOF-based PGM-free catalyst

Citation Formats

References (43)

Similar Records

Related Subjects