Enhancing electrocatalytic performance of RuO 2 -based catalysts: mechanistic insights, strategic approaches, and recent advances

KC, Binod Raj; Kumar, Dhananjay; Bastakoti, Bishnu Prasad

doi:10.1088/2515-7655/adad9f

Title: Enhancing electrocatalytic performance of RuO ₂ -based catalysts: mechanistic insights, strategic approaches, and recent advances

Journal Article · 30 January 2025 · JPhys Energy

DOI: https://doi.org/10.1088/2515-7655/adad9f · OSTI ID:2507485

; Kumar, Dhananjay;

Abstract Electrochemical water splitting presents the ultimate potential of hydrogen and oxygen production; however, regulating the rate and efficiency of water splitting is highly dependent on the accessibility of extremely efficient electrode materials for slow performance kinetics and large overpotential of both oxygen evolution reaction (OER) and hydrogen evolution reaction (HER). Ruthenium oxide (RuO ₂ ) based materials display high performance for OER and HER because of their capacity to bind oxygen, eminent catalytic activity, low cost compared to other precious metals, and stability in a wide pH range. However, there is still much space to promote the OER and HER activity and stability of RuO ₂ to fulfill the necessity for practical applications in water splitting. Different researchers applied multiple approaches that boosted the catalytic performance of RuO ₂ -based electrocatalysts toward overall water splitting. Herein, this review provides a comprehensive overview of recent advancements in RuO ₂ -based materials in the field of water electrolysis for the generation of alternative energies. It gives a general description of water splitting in acidic and alkaline settings, including reaction mechanisms as well as common evaluation elements for the catalytic function of the materials. Most of the reviews reported based on RuO ₂ materials are only focused on OER performance, but this review highlighted comprehensive ideas on different strategies like morphology design, electronic structure, electrolytes, and compositions for optimizing both electrocatalytic HER and OER functioning of RuO ₂ -based electrocatalysts.

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Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0023415

OSTI ID:: 2507485

Journal Information:: JPhys Energy, Journal Name: JPhys Energy Journal Issue: 2 Vol. 7; ISSN 2515-7655

Publisher:: IOP PublishingCopyright Statement

Country of Publication:: United Kingdom

Language:: English

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