The origin of the superior fast-charging performance of hybrid graphite/hard carbon anodes for Li-ion batteries

Goel, Vishwas; Masel, Kevin; Chen, Kuan-Hung; Safdari, Ammar; Dasgupta, Neil P.; Thornton, Katsuyo

doi:10.1016/j.ensm.2025.104053

Title: The origin of the superior fast-charging performance of hybrid graphite/hard carbon anodes for Li-ion batteries

Journal Article · 28 February 2025 · Energy Storage Materials

DOI: https://doi.org/10.1016/j.ensm.2025.104053 · OSTI ID:2507470

Goel, Vishwas; Masel, Kevin; Chen, Kuan-Hung; Safdari, Ammar; Dasgupta, Neil P.;

Not Available

View Journal Article

Cite

Export

Save

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE); USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI ID:: 2507470

Journal Information:: Energy Storage Materials, Journal Name: Energy Storage Materials Journal Issue: C Vol. 76; ISSN 2405-8297

Publisher:: ElsevierCopyright Statement

Country of Publication:: Netherlands

Language:: English

References (59)

Tortuosity Anisotropy in Lithium-Ion Battery Electrodes Ebner, Martin; Chung, Ding-Wen; García, R. Edwin Advanced Energy Materials, Vol. 4, Issue 5 https://doi.org/10.1002/aenm.201301278	journal	October 2013
Diffusion‐Limited C‐Rate: A Fundamental Principle Quantifying the Intrinsic Limits of Li‐Ion Batteries Heubner, Christian; Schneider, Michael; Michaelis, Alexander Advanced Energy Materials, Vol. 10, Issue 2 https://doi.org/10.1002/aenm.201902523	journal	November 2019
Enabling 6C Fast Charging of Li‐Ion Batteries with Graphite/Hard Carbon Hybrid Anodes Chen, Kuan‐Hung; Goel, Vishwas; Namkoong, Min Ji Advanced Energy Materials, Vol. 11, Issue 5 https://doi.org/10.1002/aenm.202003336	journal	December 2020
Porous-electrode theory with battery applications Newman, John; Tiedemann, William AIChE Journal, Vol. 21, Issue 1 https://doi.org/10.1002/aic.690210103	journal	January 1975
Understanding Component‐Specific Contributions and Internal Dynamics in Silicon/Graphite Blended Electrodes for High‐Energy Lithium‐Ion Batteries Heubner, Christian; Liebmann, Tobias; Lohrberg, Oliver Batteries & Supercaps, Vol. 5, Issue 1 https://doi.org/10.1002/batt.202100182	journal	October 2021
Einflüsse der Strömung, Diffusion und des Wärmeüberganges auf die Leistung von Reaktionsöfen.: I. Allgemeine Gesichtspunkte für die Übertragung eines chemischen Prozesses aus dem Kleinen ins Große Damköhler, Gerhard Zeitschrift für Elektrochemie und angewandte physikalische Chemie, Vol. 42, Issue 12 https://doi.org/10.1002/bbpc.19360421203	journal	December 1936
Understanding limiting factors in thick electrode performance as applied to high energy density Li-ion batteries Du, Zhijia; Wood, D. L.; Daniel, C. Journal of Applied Electrochemistry, Vol. 47, Issue 3 https://doi.org/10.1007/s10800-017-1047-4	journal	February 2017
Nanoporous carbon microspheres as anode material for enhanced capacity of lithium ion batteries Xu, Shuntao; Zhang, Zhengfu; Wu, Tianya Ionics, Vol. 24, Issue 1 https://doi.org/10.1007/s11581-017-2191-x	journal	June 2017
Improving Li-ion battery charge rate acceptance through highly ordered hierarchical electrode design Kim, Yunsung; Drews, Andy; Chandrasekaran, Rajeswari Ionics, Vol. 24, Issue 10 https://doi.org/10.1007/s11581-018-2502-x	journal	March 2018
The Materials Commons: A Collaboration Platform and Information Repository for the Global Materials Community Puchala, Brian; Tarcea, Glenn; Marquis, Emmanuelle. A. JOM, Vol. 68, Issue 8 https://doi.org/10.1007/s11837-016-1998-7	journal	July 2016
On tortuosity and the tortuosity factor in flow and diffusion through porous media Epstein, Norman Chemical Engineering Science, Vol. 44, Issue 3 https://doi.org/10.1016/0009-2509(89)85053-5	journal	January 1989
The importance of the lithium ion transference number in lithium/polymer cells Doyle, Marc; Fuller, Thomas F.; Newman, John Electrochimica Acta, Vol. 39, Issue 13 https://doi.org/10.1016/0013-4686(94)85091-7	journal	September 1994
Modeling the performance of rechargeable lithium-based cells: design correlations for limiting cases Doyle, Marc; Newman, John Journal of Power Sources, Vol. 54, Issue 1 https://doi.org/10.1016/0378-7753(94)02038-5	journal	March 1995
Electrochemical characterisation and modelling of the mass transport phenomena in LiPF6–EC–EMC electrolyte Nyman, Andreas; Behm, Mårten; Lindbergh, Göran Electrochimica Acta, Vol. 53, Issue 22 https://doi.org/10.1016/j.electacta.2008.04.023	journal	September 2008
Impedance Spectroscopic Studies of the Porous Structure of Electrodes containing Graphite Materials with Different Particle Size and Shape Cericola, Dario; Spahr, Michael E. Electrochimica Acta, Vol. 191 https://doi.org/10.1016/j.electacta.2016.01.121	journal	February 2016
Dynamics of a Blended Lithium-Ion Battery Electrode During Galvanostatic Intermittent Titration Technique Mao, Z.; Farkhondeh, M.; Pritzker, M. Electrochimica Acta, Vol. 222 https://doi.org/10.1016/j.electacta.2016.11.169	journal	December 2016
Electrode scale and electrolyte transport effects on extreme fast charging of lithium-ion cells Colclasure, Andrew M.; Tanim, Tanvir R.; Jansen, Andrew N. Electrochimica Acta, Vol. 337 https://doi.org/10.1016/j.electacta.2020.135854	journal	March 2020
Enabling fast charging of lithium-ion batteries through secondary-/dual- pore network: Part II - numerical model Mai, Weijie; Usseglio-Viretta, Francois L. E.; Colclasure, Andrew M. Electrochimica Acta, Vol. 341 https://doi.org/10.1016/j.electacta.2020.136013	journal	May 2020
Control oriented 1D electrochemical model of lithium ion battery Smith, Kandler A.; Rahn, Christopher D.; Wang, Chao-Yang Energy Conversion and Management, Vol. 48, Issue 9 https://doi.org/10.1016/j.enconman.2007.03.015	journal	September 2007
Li+ concentration waves in a liquid electrolyte of Li-ion batteries with porous graphite-based electrodes Chen, Zhiqiang; Danilov, Dmitri L.; Eichel, Rüdiger-A. Energy Storage Materials, Vol. 48 https://doi.org/10.1016/j.ensm.2022.03.037	journal	June 2022
Optimization of laser-patterned electrode architectures for fast charging of Li-ion batteries using simulations parameterized by machine learning Goel, Vishwas; Chen, Kuan-Hung; Dasgupta, Neil P. Energy Storage Materials, Vol. 57 https://doi.org/10.1016/j.ensm.2023.01.050	journal	March 2023
Li4Ti5O12-Hard carbon composite anode for fast-charging Li-Ion batteries Saneifar, Hamidreza; Liu, Jian Journal of Electroanalytical Chemistry, Vol. 929 https://doi.org/10.1016/j.jelechem.2022.117100	journal	January 2023
Asymmetric Temperature Modulation for Extreme Fast Charging of Lithium-Ion Batteries Yang, Xiao-Guang; Liu, Teng; Gao, Yue Joule, Vol. 3, Issue 12 https://doi.org/10.1016/j.joule.2019.09.021	journal	December 2019
Simplification and order reduction of lithium-ion battery model based on porous-electrode theory Dao, Thanh-Son; Vyasarayani, Chandrika P.; McPhee, John Journal of Power Sources, Vol. 198 https://doi.org/10.1016/j.jpowsour.2011.09.034	journal	January 2012
An extended homogenized porous electrode model for lithium-ion cell electrodes Ender, Moses Journal of Power Sources, Vol. 282 https://doi.org/10.1016/j.jpowsour.2015.02.098	journal	May 2015
Microstructural effects on the average properties in porous battery electrodes García-García, Ramiro; García, R. Edwin Journal of Power Sources, Vol. 309 https://doi.org/10.1016/j.jpowsour.2015.11.058	journal	March 2016
Insights into the buffer effect observed in blended lithium insertion electrodes Heubner, C.; Liebmann, T.; Lämmel, C. Journal of Power Sources, Vol. 363 https://doi.org/10.1016/j.jpowsour.2017.07.108	journal	September 2017
Electrochemical-mechanical coupled modeling and parameterization of swelling and ionic transport in lithium-ion batteries Sauerteig, Daniel; Hanselmann, Nina; Arzberger, Arno Journal of Power Sources, Vol. 378 https://doi.org/10.1016/j.jpowsour.2017.12.044	journal	February 2018
Li plating as unwanted side reaction in commercial Li-ion cells – A review Waldmann, Thomas; Hogg, Björn-Ingo; Wohlfahrt-Mehrens, Margret Journal of Power Sources, Vol. 384 https://doi.org/10.1016/j.jpowsour.2018.02.063	journal	April 2018
Understanding the trilemma of fast charging, energy density and cycle life of lithium-ion batteries Yang, Xiao-Guang; Wang, Chao-Yang Journal of Power Sources, Vol. 402 https://doi.org/10.1016/j.jpowsour.2018.09.069	journal	October 2018
Fast-charging effects on ageing for energy-optimized automotive LiNi1/3Mn1/3Co1/3O2/graphite prismatic lithium-ion cells Mussa, Abdilbari Shifa; Liivat, Anti; Marzano, Fernanda Journal of Power Sources, Vol. 422 https://doi.org/10.1016/j.jpowsour.2019.02.095	journal	May 2019
Efficient fast-charging of lithium-ion batteries enabled by laser-patterned three-dimensional graphite anode architectures Chen, Kuan-Hung; Namkoong, Min Ji; Goel, Vishwas Journal of Power Sources, Vol. 471 https://doi.org/10.1016/j.jpowsour.2020.228475	journal	September 2020
A simplified electrochemical model for modelling Li-ion batteries comprising blend and bidispersed electrodes for high power applications Petit, Martin; Calas, Elisa; Bernard, Julien Journal of Power Sources, Vol. 479 https://doi.org/10.1016/j.jpowsour.2020.228766	journal	December 2020
Overpotential analysis of graphite-based Li-ion batteries seen from a porous electrode modeling perspective Chen, Zhiqiang; Danilov, Dmitri L.; Raijmakers, Luc H. J. Journal of Power Sources, Vol. 509 https://doi.org/10.1016/j.jpowsour.2021.230345	journal	October 2021
Enabling the electrochemical simulation of Li-ion battery electrodes with anisotropic tortuosity in COMSOL MultiphysicsⓇ Goel, Vishwas; Thornton, Katsuyo MethodsX, Vol. 8 https://doi.org/10.1016/j.mex.2021.101425	journal	January 2021
Multivalent Li-Site Doping of Mn Oxides for Li-Ion Batteries Kong, Fantai; Longo, Roberto C.; Yeon, Dong-Hee The Journal of Physical Chemistry C, Vol. 119, Issue 38 https://doi.org/10.1021/acs.jpcc.5b06844	journal	September 2015
Dendrites and Pits: Untangling the Complex Behavior of Lithium Metal Anodes through Operando Video Microscopy Wood, Kevin N.; Kazyak, Eric; Chadwick, Alexander F. ACS Central Science, Vol. 2, Issue 11 https://doi.org/10.1021/acscentsci.6b00260	journal	October 2016
Rate Limitations in Composite Solid-State Battery Electrodes: Revealing Heterogeneity with Operando Microscopy Davis, Andrew L.; Goel, Vishwas; Liao, Daniel W. ACS Energy Letters, Vol. 6, Issue 8 https://doi.org/10.1021/acsenergylett.1c01063	journal	August 2021
Toward Fast Operation of Lithium Batteries: Ion Activity as the Factor To Determine the Concentration Polarization Kim, Dong-Hui; Hwang, Sunwook; Cho, Jeong-Ju ACS Energy Letters, Vol. 4, Issue 6 https://doi.org/10.1021/acsenergylett.9b00724	journal	April 2019
Diffusion Coefficients of Lithium Ions during Intercalation into Graphite Derived from the Simultaneous Measurements and Modeling of Electrochemical Impedance and Potentiostatic Intermittent Titration Characteristics of Thin Graphite Electrodes Levi, M. D.; Aurbach, D. The Journal of Physical Chemistry B, Vol. 101, Issue 23 https://doi.org/10.1021/jp9701911	journal	June 1997
Challenges and opportunities towards fast-charging battery materials Liu, Yayuan; Zhu, Yangying; Cui, Yi Nature Energy, Vol. 4, Issue 7 https://doi.org/10.1038/s41560-019-0405-3	journal	June 2019
Novel hard carbon/graphite composites synthesized by a facile in situ anchoring method as high-performance anodes for lithium-ion batteries Ge, Chuanzhang; Fan, Zhenghua; Zhang, Jie RSC Advances, Vol. 8, Issue 60 https://doi.org/10.1039/C8RA07170E	journal	January 2018
Problems in the Analysis of Survey Data, and a Proposal Morgan, James N.; Sonquist, John A. Journal of the American Statistical Association, Vol. 58, Issue 302 https://doi.org/10.1080/01621459.1963.10500855	journal	June 1963
The particle swarm - explosion, stability, and convergence in a multidimensional complex space Clerc, M.; Kennedy, J. IEEE Transactions on Evolutionary Computation, Vol. 6, Issue 1 https://doi.org/10.1109/4235.985692	journal	January 2002
The Materials Commons Data Repository Tarcea, Glenn; Puchala, Brian; Berman, Tracy 2022 IEEE 18th International Conference on e-Science (e-Science) https://doi.org/10.1109/eScience55777.2022.00060	conference	October 2022
Fifty Years of Classification and Regression Trees: Fifty Years of Classification and Regression Trees Loh, Wei-Yin International Statistical Review, Vol. 82, Issue 3 https://doi.org/10.1111/insr.12016	journal	June 2014
Comparison of Modeling Predictions with Experimental Data from Plastic Lithium Ion Cells Doyle, Marc Journal of The Electrochemical Society, Vol. 143, Issue 6 https://doi.org/10.1149/1.1836921	journal	January 1996
Simulation and Optimization of the Dual Lithium Ion Insertion Cell Fuller, Thomas F. Journal of The Electrochemical Society, Vol. 141, Issue 1 https://doi.org/10.1149/1.2054684	journal	January 1994
Theoretical Analysis of Current Distribution in Porous Electrodes Newman, John S.; Tobias, Charles W. Journal of The Electrochemical Society, Vol. 109, Issue 12 https://doi.org/10.1149/1.2425269	journal	January 1962
Two-Dimensional Modeling of Lithium Deposition during Cell Charging Tang, Maureen; Albertus, Paul; Newman, John Journal of The Electrochemical Society, Vol. 156, Issue 5 https://doi.org/10.1149/1.3095513	journal	January 2009
Experiments on and Modeling of Positive Electrodes with Multiple Active Materials for Lithium-Ion Batteries Albertus, Paul; Christensen, Jake; Newman, John Journal of The Electrochemical Society, Vol. 156, Issue 7 https://doi.org/10.1149/1.3129656	journal	January 2009
Tool for Tortuosity Estimation in Lithium Ion Battery Porous Electrodes Ebner, Martin; Wood, Vanessa Journal of The Electrochemical Society, Vol. 162, Issue 2 https://doi.org/10.1149/2.0111502jes	journal	December 2014
Optimizing Areal Capacities through Understanding the Limitations of Lithium-Ion Electrodes Gallagher, Kevin G.; Trask, Stephen E.; Bauer, Christoph Journal of The Electrochemical Society, Vol. 163, Issue 2 https://doi.org/10.1149/2.0321602jes	journal	November 2015
Full Cell Parameterization of a High-Power Lithium-Ion Battery for a Physico-Chemical Model: Part I. Physical and Electrochemical Parameters Schmalstieg, Johannes; Rahe, Christiane; Ecker, Madeleine Journal of The Electrochemical Society, Vol. 165, Issue 16 https://doi.org/10.1149/2.0321816jes	journal	January 2018
Requirements for Enabling Extreme Fast Charging of High Energy Density Li-Ion Cells while Avoiding Lithium Plating Colclasure, Andrew M.; Dunlop, Alison R.; Trask, Stephen E. Journal of The Electrochemical Society, Vol. 166, Issue 8 https://doi.org/10.1149/2.0451908jes	journal	January 2019
Kinetics of Nanoparticle Interactions in Battery Electrodes Orvananos, Bernardo; Yu, Hui-Chia; Abdellahi, Aziz Journal of The Electrochemical Society, Vol. 162, Issue 6 https://doi.org/10.1149/2.0481506jes	journal	January 2015
Parameterization of a Physico-Chemical Model of a Lithium-Ion Battery: I. Determination of Parameters Ecker, Madeleine; Tran, Thi Kim Dung; Dechent, Philipp Journal of The Electrochemical Society, Vol. 162, Issue 9 https://doi.org/10.1149/2.0551509jes	journal	January 2015
Model Based Design of Composite Carbonaceous Anode for Li-Ion Battery for Fast Charging Applications Patil, Rajkumar S.; Khandelwal, Ashish; Kim, Ki Young Journal of The Electrochemical Society, Vol. 166, Issue 6 https://doi.org/10.1149/2.0901906jes	journal	January 2019
Electrochemical dynamics in hybrid graphite–carbon electrodes Malik, Affan; Snyder, Kent; Liu, Minghong MRS Communications, Vol. 12, Issue 6 https://doi.org/10.1557/s43579-022-00214-4	journal	August 2022

Similar Records

Enabling 6C Fast Charging of Li-Ion Batteries with Graphite/Hard Carbon Hybrid Anodes

Journal Article · 2020 · Advanced Energy Materials · OSTI ID:1848762

Chen, Kuan‐Hung; Goel, Vishwas; Namkoong, Min Ji; +6 more

Enabling 6C Fast Charging of Li–Ion Batteries with Graphite/Hard Carbon Hybrid Anodes

Journal Article · 2020 · Advanced Energy Materials · OSTI ID:1924792

Chen, Kuan‐Hung; Goel, Vishwas; Namkoong, Min Ji; +6 more

Hard carbon coated nano-Si/graphite composite as a high performance anode for Li-ion batteries

Journal Article · 2016 · Journal of Power Sources · OSTI ID:1397456

Jeong, Sookyung; Li, Xiaolin; Zheng, Jianming; +6 more

Title: The origin of the superior fast-charging performance of hybrid graphite/hard carbon anodes for Li-ion batteries

Citation Formats

References (59)

Similar Records

Related Subjects