Advancements in active filler-contained polymer solid-state electrolytes for lithium-metal batteries: A concise review

Ding, Hang; Wang, Mingli; Shan, Xinyuan; Yang, Guang; Tian, Ming

doi:10.1016/j.supmat.2025.100097

Title: Advancements in active filler-contained polymer solid-state electrolytes for lithium-metal batteries: A concise review

Journal Article · 19 January 2025 · Supramolecular Materials

DOI: https://doi.org/10.1016/j.supmat.2025.100097 · OSTI ID:2503541

Ding, Hang ^[1]; Wang, Mingli ^[1]; Shan, Xinyuan ^[1];

^[2]; Tian, Ming ^[1]

Beijing University of Chemical Technology (China)
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division; Univ. of Tennessee, Knoxville, TN (United States). Bredesen Center for Interdisciplinary Research and Graduate Education

Lithium-metal batteries (LMBs) usually are regarded as the pinnacle of next-generation energy storage due to the high specific capacity and low redox potential of the Li-metal anode. However, their development is hindered by safety hazards related to flammable electrolytes and uncontrolled side reactions within the battery. Both polymer and solid-state inorganic electrolytes, despite their potential, exhibit shortcomings that limit their practical applications. Active filler-containing polymer electrolytes (AFPEs) offer a promising solution by combining the benefits of both types. Enhanced by supramolecular interactions between the polymer matrix and active fillers, AFPEs demonstrate superior electrochemical performance over traditional polymer electrolytes. This review discusses the progress in active fillers and various polymer matrices, examining the factors that enhance performance, particularly ionic conductivity. It also outlines the future research directions of AFPEs, aiming to broaden the application of solid electrolytes in high-performance LMBs.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: Beijing University of Chemical Technology, China; USDOE

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 2503541

Journal Information:: Supramolecular Materials, Journal Name: Supramolecular Materials Vol. 4; ISSN 2667-2405

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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An anion-immobilized composite electrolyte for dendrite-free lithium metal anodes Zhao, Chen-Zi; Zhang, Xue-Qiang; Cheng, Xin-Bing Proceedings of the National Academy of Sciences, Vol. 114, Issue 42 https://doi.org/10.1073/pnas.1708489114	journal	October 2017
Recovery of Pure Water, Salicylic Acid Crystals, and Paracetamol using PVDF-MWCNT Membranes by Membrane Distillation-crystallization JOURNAL OF POLYMER MATERIALS, Vol. 39, Issue 3-4 https://doi.org/10.32381/JPM.2022.39.3-4.9	journal	May 2023
Study of Galvanic Charging-Discharging Properties of Graphene Nanoplatelets Incorporated Epoxy-Carbon Fabric Composites Journal of Polymer Materials, Vol. 40, Issue 1-2 https://doi.org/10.32381/JPM.2023.40.1-2.8	journal	August 2023
Review on Polymer-Based Composite Electrolytes for Lithium Batteries Yao, Penghui; Yu, Haobin; Ding, Zhiyu Frontiers in Chemistry, Vol. 7 https://doi.org/10.3389/fchem.2019.00522	journal	August 2019

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