Understanding the Effects of Bi Modification on the Properties of Ni-Rich Cathodes

Meng, Zifei; Hou, Jiahui; Thanwisai, Panya; Fu, Jinzhao; Yao, Zeyi; Zheng, Yadong; Jin, Wenting; Wang, Zexin; Yang, Zhenzhen; Ma, Xiaotu; Wang, Yan

doi:10.1002/batt.202400107

Title: Understanding the Effects of Bi Modification on the Properties of Ni-Rich Cathodes

Journal Article · 09 April 2024 · Batteries & Supercaps

DOI: https://doi.org/10.1002/batt.202400107 · OSTI ID:2502017

Meng, Zifei ^[1]; Hou, Jiahui ^[1]; Thanwisai, Panya ^[1]; Fu, Jinzhao ^[1]; Yao, Zeyi ^[1]; Zheng, Yadong ^[1]; Jin, Wenting ^[1]; Wang, Zexin ^[1]; Yang, Zhenzhen ^[2]; Ma, Xiaotu ^[1];

^[1]

Worcester Polytechnic Institute, MA (United States)
Argonne National Laboratory (ANL), Argonne, IL (United States)

With the skyrocketing market demands for energy storage, lithium ions batteries (LIB) with higher energy density are urgently needed. Cathodes play a critical role in determining the energy density of LIB, and the most popular one is Ni-rich cathode due to its high capacity. However, due to the fast structural degradation, Ni-rich cathode materials should be further modified to achieve higher stability. Herein, we introduce bismuth ions in LiNi_0.83Co_0.11Mn_0.06O₂ cathodes by adding Bi₂O₃ during sintering to optimize the specific capacity and cycle stability. By adding 0.1% mol Bi, the Li⁺ diffusion and structural stability are effectively optimized, leading to improved electrochemical performances. Further, the modified sample delivers much higher specific capacity (222.9 mAhg^-1, 0.05 C) than unmodified sample (204 mAhg^-1, 0.05 C). Meanwhile, the specific capacity of optimized sample after 100 cycles at 0.33 C is 27.75 mAhg^-1 higher than that of unmodified sample. Therefore, this work demonstrates that Bi modification can be regarded as a possible solution to optimizing the electrochemical performance of Ni-rich cathodes.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Vehicle Technologies Office (VTO)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 2502017

Journal Information:: Batteries & Supercaps, Journal Name: Batteries & Supercaps Journal Issue: 7 Vol. 7; ISSN 2566-6223

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

References (39)

Enhancing Cycling Stability and Capacity Retention of NMC811 Cathodes by Reengineering Interfaces via Electrochemical Fluorination Thapaliya, Bishnu P.; Misra, Sudhajit; Yang, Shi‐ze Advanced Materials Interfaces, Vol. 9, Issue 18 https://doi.org/10.1002/admi.202200035	journal	February 2022
A Review of Degradation Mechanisms and Recent Achievements for Ni‐Rich Cathode‐Based Li‐Ion Batteries Jiang, Ming; Danilov, Dmitri L.; Eichel, Rüdiger‐A. Advanced Energy Materials, Vol. 11, Issue 48 https://doi.org/10.1002/aenm.202103005	journal	November 2021
Structural Reconstruction Driven by Oxygen Vacancies in Layered Ni‐Rich Cathodes Qiu, Lang; Song, Yang; Zhang, Mengke Advanced Energy Materials, Vol. 12, Issue 19 https://doi.org/10.1002/aenm.202200022	journal	March 2022
Enabling Extreme Fast‐Charging: Challenges at the Cathode and Mitigation Strategies Tanim, Tanvir R.; Weddle, Peter J.; Yang, Zhenzhen Advanced Energy Materials, Vol. 12, Issue 46 https://doi.org/10.1002/aenm.202202795	journal	November 2022
Deciphering the degradation discrepancy in Ni‐rich cathodes with a diverse proportion of [003] crystallographic textures Qiu, Lang; Zhang, Mengke; Song, Yang Carbon Energy, Vol. 5, Issue 7 https://doi.org/10.1002/cey2.298	journal	December 2022
Single‐Crystal LiNi _x Mn _y Co ₁₋ _x ₋ _y O ₂ Cathodes for Extreme Fast Charging Lu, Yanying; Zhu, Tianyu; McShane, Eric Small, Vol. 18, Issue 12 https://doi.org/10.1002/smll.202105833	journal	January 2022
Regulating Anionic Redox via Mg Substitution in Mn‐Rich Layered Oxide Cathodes Enabling High Electrochemical Stability for Sodium‐Ion Batteries Thanwisai, Panya; Vanaphuti, Panawan; Yao, Zeyi Small, Vol. 20, Issue 9 https://doi.org/10.1002/smll.202306465	journal	October 2023
Bismuth effect in the structural, magnetic and dielectric properties of CoZn ferrite Sathishkumar, G.; Venkataraju, C.; Murugaraj, R. Journal of Materials Science: Materials in Electronics, Vol. 23, Issue 1 https://doi.org/10.1007/s10854-011-0395-9	journal	May 2011
Strengthened the structural stability of in-situ F− doping Ni-rich LiNi0.8Co0.15Al0.05O2 cathode materials for lithium-ion batteries Wang, Jiale; Liu, Chengjin; Xu, Guanli Chemical Engineering Journal, Vol. 438 https://doi.org/10.1016/j.cej.2022.135537	journal	June 2022
Enhanced cycle performance and synthesis of LiNi0.6Co0.2Mn0.2O2 single-crystal through the assist of Bi ion Zhang, Shuai; Hu, Guorong; Du, Ke Electrochimica Acta, Vol. 470 https://doi.org/10.1016/j.electacta.2023.143280	journal	December 2023
Unraveling Na and F coupling effects in stabilizing Li, Mn-rich layered oxide cathodes via local ordering modification Vanaphuti, Panawan; Bai, Jianming; Ma, Lu Energy Storage Materials, Vol. 31 https://doi.org/10.1016/j.ensm.2020.08.003	journal	October 2020
The surface double-coupling on single-crystal LiNi0.8Co0.1Mn0.1O2 for inhibiting the formation of intragranular cracks and oxygen vacancies Liu, Yunjian; Zeng, Tianyi; Li, Guotai Energy Storage Materials, Vol. 52 https://doi.org/10.1016/j.ensm.2022.08.026	journal	November 2022
A review on doping/coating of nickel-rich cathode materials for lithium-ion batteries Yan, Wuwei; Yang, Shunyi; Huang, Youyuan Journal of Alloys and Compounds, Vol. 819 https://doi.org/10.1016/j.jallcom.2019.153048	journal	April 2020
Cellulose nanofiber assisted hydrothermal synthesis of Ni-rich cathode materials with high binding particles for lithium-ion batteries Wu, Haiwei; Pang, Xiaofei; Bi, Jingxuan Journal of Alloys and Compounds, Vol. 829 https://doi.org/10.1016/j.jallcom.2020.154571	journal	July 2020
Bi5+ doping improves the electrochemical properties of Ti/SnO2–Sb/PbO2 electrode and its electrocatalytic performance for phenol Wan, Chunli; Zhao, Lianfa; Wu, Changyong Journal of Cleaner Production, Vol. 380 https://doi.org/10.1016/j.jclepro.2022.135005	journal	December 2022
Well-ordered layered LiNi0.8Co0.1Mn0.1O2 submicron sphere with fast electrochemical kinetics for cathodic lithium storage Liang, Jianing; Lu, Yun; Wang, Jie Journal of Energy Chemistry, Vol. 47 https://doi.org/10.1016/j.jechem.2019.12.009	journal	August 2020
A review: Modification strategies of nickel-rich layer structure cathode (Ni ≥ 0.8) materials for lithium ion power batteries Lv, Haijian; Li, Chunli; Zhao, Zhikun Journal of Energy Chemistry, Vol. 60 https://doi.org/10.1016/j.jechem.2021.01.044	journal	September 2021
Extensive comparison of doping and coating strategies for Ni-rich positive electrode materials Ahaliabadeh, Zahra; Kong, Xiangze; Fedorovskaya, Ekaterina Journal of Power Sources, Vol. 540 https://doi.org/10.1016/j.jpowsour.2022.231633	journal	August 2022
Underlying limitations behind impedance rise and capacity fade of single crystalline Ni-rich cathodes synthesized via a molten-salt route Azhari, Luqman; Meng, Zifei; Yang, Zhenzhen Journal of Power Sources, Vol. 545 https://doi.org/10.1016/j.jpowsour.2022.231963	journal	October 2022
Polyanion and cation co-doping stabilized Ni-rich Ni–Co–Al material as cathode with enhanced electrochemical performance for Li-ion battery Qiu, Lang; Xiang, Wei; Tian, Wen Nano Energy, Vol. 63 https://doi.org/10.1016/j.nanoen.2019.06.014	journal	September 2019
Understanding fundamental effects of Cu impurity in different forms for recovered LiNi0.6Co0.2Mn0.2O2 cathode materials Zhang, Ruihan; Meng, Zifei; Ma, Xiaotu Nano Energy, Vol. 78 https://doi.org/10.1016/j.nanoen.2020.105214	journal	December 2020
Optimized activation of Li2MnO3 effectively boosting rate capability of xLi2MnO3∙(1-x)LiMO2 cathode Hao, Youchen; Liu, Wen; Zhang, Qianyu Nano Energy, Vol. 88 https://doi.org/10.1016/j.nanoen.2021.106240	journal	October 2021
An integrated surface coating strategy to enhance the electrochemical performance of nickel-rich layered cathodes Qu, Xingyu; Huang, He; Wan, Tao Nano Energy, Vol. 91 https://doi.org/10.1016/j.nanoen.2021.106665	journal	January 2022
Elucidating the Relationship between Quality Control of the Coating Layer and Suppression of Gas Evolution in Li-Ion Batteries Lee, Youbean; Park, Chanjoo; Park, Kwangjin Chemistry of Materials, Vol. 36, Issue 1 https://doi.org/10.1021/acs.chemmater.3c01998	journal	December 2023
In Situ X-ray Diffraction Study of Layered Li–Ni–Mn–Co Oxides: Effect of Particle Size and Structural Stability of Core–Shell Materials Li, Jing; Shunmugasundaram, Ramesh; Doig, Renny Chemistry of Materials, Vol. 28, Issue 1 https://doi.org/10.1021/acs.chemmater.5b03500	journal	December 2015
Capacity Fading of Ni-Rich Li[Ni _x Co _y Mn _{1– x – y} ]O ₂ (0.6 ≤ x ≤ 0.95) Cathodes for High-Energy-Density Lithium-Ion Batteries: Bulk or Surface Degradation? Ryu, Hoon-Hee; Park, Kang-Joon; Yoon, Chong S. Chemistry of Materials, Vol. 30, Issue 3 https://doi.org/10.1021/acs.chemmater.7b05269	journal	January 2018
Stabilized Lithium, Manganese-Rich Layered Cathode Materials Enabled by Integrating Co-Doping and Nanocoating Vanaphuti, Panawan; Liu, Yangtao; Ma, Xiaotu ACS Applied Materials & Interfaces, Vol. 13, Issue 19 https://doi.org/10.1021/acsami.1c04718	journal	May 2021
Positive Role of Fluorine Impurity in Recovered LiNi_0.6Co_0.2Mn_0.2O₂ Cathode Materials Zheng, Yadong; Zhang, Ruihan; Vanaphuti, Panawan ACS Applied Materials & Interfaces, Vol. 13, Issue 48 https://doi.org/10.1021/acsami.1c17341	journal	November 2021
Enhancing the Integral Structural and Thermal Stability of Ultrahigh-Ni Cathodes via Morphology Refinement and In Situ Interfacial Engineering Jiang, Yuandi; Guo, Fuqiren; Qiu, Lang ACS Applied Materials & Interfaces, Vol. 15, Issue 29 https://doi.org/10.1021/acsami.3c07022	journal	July 2023
Synthesis Method for Long Cycle Life Lithium-Ion Cathode Material: Nickel-Rich Core–Shell LiNi_0.8Co_0.1Mn_0.1O₂ Li, Qi; Dang, Rongbin; Chen, Minmin ACS Applied Materials & Interfaces, Vol. 10, Issue 21 https://doi.org/10.1021/acsami.8b02000	journal	May 2018
Relieving Stress Concentration through Anion–Cation Codoping toward Highly Stable Nickel-Rich Cathode Zhou, Yu; Zhang, Hanwei; Wang, Yinglei ACS Nano, Vol. 17, Issue 20 https://doi.org/10.1021/acsnano.3c07655	journal	October 2023
Preparation and Electrochemical Characterization of La and Al Co-doped NCM811 Cathode Materials Zhang, Mingyu; Wang, Chaoyong; Zhang, Junkai ACS Omega, Vol. 6, Issue 25 https://doi.org/10.1021/acsomega.1c01552	journal	June 2021
Approaching the capacity limit of lithium cobalt oxide in lithium ion batteries via lanthanum and aluminium doping Liu, Qi; Su, Xin; Lei, Dan Nature Energy, Vol. 3, Issue 11 https://doi.org/10.1038/s41560-018-0180-6	journal	June 2018
High-nickel layered oxide cathodes for lithium-based automotive batteries Li, Wangda; Erickson, Evan M.; Manthiram, Arumugam Nature Energy, Vol. 5, Issue 1 https://doi.org/10.1038/s41560-019-0513-0	journal	January 2020
Layered lithium cobalt oxide cathodes Manthiram, Arumugam; Goodenough, John B. Nature Energy, Vol. 6, Issue 3 https://doi.org/10.1038/s41560-020-00764-8	journal	March 2021
Morphology controlled performance of ternary layered oxide cathodes Meng, Zifei; Ma, Xiaotu; Azhari, Luqman Communications Materials, Vol. 4, Issue 1 https://doi.org/10.1038/s43246-023-00418-8	journal	November 2023
Enhanced cycling stability and rate capability of Bi₂O₃-coated Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode materials for lithium-ion batteries Zhou, Lin; Wu, Huali; Tian, Mijie RSC Advances, Vol. 6, Issue 74 https://doi.org/10.1039/C6RA14087D	journal	January 2016
A nanorod-like Ni-rich layered cathode with enhanced Li ⁺ diffusion pathways for high-performance lithium-ion batteries Li, Fangkun; Liu, Zhengbo; Shen, Jiadong Journal of Materials Chemistry A, Vol. 9, Issue 5 https://doi.org/10.1039/D0TA10608A	journal	January 2021
Improved cycling stability of high nickel cathode material for lithium ion battery through Al- and Ti-based dual modification Mao, Guihong; Luo, Jing; Zhou, Qing Nanoscale, Vol. 13, Issue 44 https://doi.org/10.1039/D1NR06005H	journal	January 2021

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25 ENERGY STORAGE
Bi modification
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structural stability

Title: Understanding the Effects of Bi Modification on the Properties of Ni-Rich Cathodes

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