ASb3Mn9O19 (A = K or Rb): New Mn-Based 2D Magnetoplumbites with Geometric and Magnetic Frustration

Chen, Jianyi; Calder, Stuart; Paddison, Joseph M.; Angelo, Gina; Klivansky, Liana; Zhang, Jian; Cao, Huibo; Gui, Xin

doi:10.1002/adma.202417906

Title: ASb₃Mn₉O₁₉ (A = K or Rb): New Mn-Based 2D Magnetoplumbites with Geometric and Magnetic Frustration

Journal Article · 30 December 2024 · Advanced Materials

DOI: https://doi.org/10.1002/adma.202417906 · OSTI ID:2484197

Chen, Jianyi ^[1];

^[2];

^[2]; Angelo, Gina ^[1]; Klivansky, Liana ^[3]; Zhang, Jian ^[3];

^[2];

^[1]

Univ. of Pittsburgh, PA (United States)
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). Molecular Foundry

Magnetoplumbites are one of the most broadly studied families of hexagonal ferrites, typically with high magnetic ordering temperatures, making them excellent candidates for permanent magnets. However, magnetic frustration is rarely observed in magnetoplumbites. Herein, the discovery, synthesis, and characterization of the first Mn-based magnetoplumbite, as well as the first magnetoplumbite involving pnictogens (Sb), ASb₃Mn₉O₁₉ (A = K or Rb) are reported. The Mn³⁺ (S = 2) cations, further confirmed by DC magnetic susceptibility and X-ray photoelectron spectroscopy, construct three geometrically frustrated sublattices, including Kagome, triangular, and puckered honeycomb lattices. Magnetic properties measurements revealed strong antiferromagnetic spin–spin coupling as well as multiple low-temperature magnetic features. Heat capacity data does not show any prominent λ-anomaly, suggesting minimal associated magnetic entropy. Moreover, neutron powder diffraction (NPD) implied the absence of long-range magnetic ordering in KSb₃Mn₉O₁₉ down to 3 K. However, several magnetic peaks are observed in RbSb₃Mn₉O₁₉ at 3 K, corresponding to an incommensurate magnetic structure. Interestingly, strong diffuse scattering is seen in the NPD patterns of both compounds at low angles and is analyzed by reverse Monte Carlo refinements, indicating short-range spin ordering related to frustrated magnetism as well as 2D magnetic correlations in ASb₃Mn₉O₁₉ (A = K or Rb).

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Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States); Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities (SUF)

Grant/Contract Number:: AC02-05CH11231; AC05-00OR22725

OSTI ID:: 2484197

Journal Information:: Advanced Materials, Journal Name: Advanced Materials Journal Issue: 10 Vol. 37; ISSN 0935-9648

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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36 MATERIALS SCIENCE
Kagome lattice
magnetic frustration
magnetoplumbites

Title: ASb3Mn9O19 (A = K or Rb): New Mn-Based 2D Magnetoplumbites with Geometric and Magnetic Frustration

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Title: ASb₃Mn₉O₁₉ (A = K or Rb): New Mn-Based 2D Magnetoplumbites with Geometric and Magnetic Frustration