Gaining insight into lithium-ion battery degradation by a calorimetric approach

Huang, Qian; Choi, Daiwon; Crawford, Alasdair J.; McNamara, Bruce K.; Shamim, Nimat; Viswanathan, Vilayanur V.; Reed, David M.; Sprenkle, Vincent L.

doi:10.1016/j.jpowsour.2024.234628

Title: Gaining insight into lithium-ion battery degradation by a calorimetric approach

Journal Article · Thu May 09 00:00:00 UTC 2024 · Journal of Power Sources

DOI: https://doi.org/10.1016/j.jpowsour.2024.234628 · OSTI ID:2481693

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^[1]; McNamara, Bruce K. ^[1];

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^[1]; Reed, David M. ^[1]; Sprenkle, Vincent L. ^[1]

Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

With the growing demand for lithium-ion batteries (LIBs) in transportation and renewable energy sectors, ensuring reliability and mitigating degradation are crucial challenges for their widespread deployment. Here this study investigates the relationship between thermal characteristics and degradation/reliability by developing an in-situ heat measurement methodology for LIBs operating under grid services. Using adiabatic mode-based calorimetry, we examine the thermal behavior of two commercial cells with different cathode chemistries (Ni-rich layered oxide and olivine) before and after two years of grid service (peak shaving) and demonstrate a strong correlation between thermal characteristics and electrochemical performance and its degradation. By further analyzing the heat sources separation (differentiating between irreversible and reversible heat), we disclose the underlying degradation mechanisms of LIBs. These findings emphasize the critical role of thermal characteristics in determining LIB reliability and deterioration, while the obtained heat data can aid in the development and calibration of LIB state-of-health models for grid applications.

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Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE Office of Electricity (OE)

Grant/Contract Number:: AC05-76RL01830

OSTI ID:: 2481693

Report Number(s):: PNNL-SA--186087

Journal Information:: Journal of Power Sources, Journal Name: Journal of Power Sources Vol. 608; ISSN 0378-7753

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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25 ENERGY STORAGE
calorimetry
degradation
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peak shaving
reliability
state-of-health
thermal study

Title: Gaining insight into lithium-ion battery degradation by a calorimetric approach

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