Magnetic properties of the frustrated spin-$\frac{1}{2}$ capped-kagome antiferromagnet (CsBr)Cu5V2O10

Guchhait, S.; Ambika, D. V.; Mohanty, S.; Furukawa, Y.; Nath, R.

doi:10.1103/physrevb.110.174447

Title: Magnetic properties of the frustrated spin-$$\frac{1}{2}$$ capped-kagome antiferromagnet (CsBr)Cu₅V₂O₁₀

Journal Article · 25 November 2024 · Physical Review. B

DOI: https://doi.org/10.1103/physrevb.110.174447 · OSTI ID:2481293

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Indian Institute of Science Education and Research (India)
Ames Lab., and Iowa State Univ., Ames, IA (United States)

Here, the structural and magnetic properties of a spin-$$\frac{1}{2}$$ averievite (CsBr)⁢Cu_5⁢V₂⁢O₁₀ are investigated by means of temperature-dependent x-ray diffraction, magnetization, heat capacity, and ⁵¹V nuclear magnetic resonance (NMR) measurements. The crystal structure (trigonal, $$P\bar{3}$$) features a frustrated capped-kagome lattice of the magnetic Cu²⁺ ions. Magnetic susceptibility analysis indicates a large Curie-Weiss temperature of $$\theta$$_CW ≃ -175K. Heat capacity signals the onset of a magnetic long-range-order (LRO) at T_N≃21.5K at zero magnetic field due to the presence of significant inter-planer coupling in this system. The magnetic LRO below 27 K is further evident from the drastic change in the ⁵¹V NMR signal intensity and rapid enhancement in the ⁵¹V spin-lattice relaxation rate in a magnetic field of 6.3 T. The frustration index ƒ=|⁢$$\theta$$_CW⁢|/⁢T_N ≃ 8 ascertains strong magnetic frustration in this compound. From the high-temperature value of the ⁵¹V NMR spin-lattice relaxation rate, the leading antiferromagnetic exchange interaction between the Cu²⁺ ions is calculated to be J/k_B ≃ 136K.

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Research Organization:: Ames Laboratory (AMES), Ames, IA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division (MSE)

Grant/Contract Number:: AC02-07CH11358

OSTI ID:: 2481293

Report Number(s):: AL-J--676

Journal Information:: Physical Review. B, Journal Name: Physical Review. B Journal Issue: 17 Vol. 110; ISSN 2469-9950

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

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Title: Magnetic properties of the frustrated spin-$$\frac{1}{2}$$ capped-kagome antiferromagnet (CsBr)Cu5V2O10

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Title: Magnetic properties of the frustrated spin-$$\frac{1}{2}$$ capped-kagome antiferromagnet (CsBr)Cu₅V₂O₁₀