Atomic-Site-Specific Surface Valence-Band Structure from X-Ray Standing-Wave Excited Photoemission

Chen, Yanna; Jones, Leighton O.; Lee, Tien Lin; Das, Anusheela; Mosquera, Martín A.; Keane, Denis T.; Schatz, George C.; Bedzyk, Michael J.

doi:10.1103/physrevlett.128.206801

Title: Atomic-Site-Specific Surface Valence-Band Structure from X-Ray Standing-Wave Excited Photoemission

Journal Article · 16 May 2022 · Physical Review Letters

DOI: https://doi.org/10.1103/physrevlett.128.206801 · OSTI ID:2481083

^[1];

^[1]; Lee, Tien Lin ^[2];

^[1];

^[3]; Keane, Denis T. ^[1];

^[1];

^[1]

Northwestern University, Evanston, IL (United States)
Diamond Light Source, Didcot (United Kingdom)
Montana State University, Bozeman, MT (United States)

X-ray standing-wave (XSW) excited photoelectron emission was used to measure the site-specific valence band (VB) for ½ monolayer (ML) Pt grown on a SrTiO₃ (001) surface. The XSW induced modulations in the core level (CL), and VB photoemission from the surface and substrate atoms were monitored for three ℎ⁡kl substrate Bragg reflections. The XSW CL analysis shows the Pt to have a face-centered-cubic-like cube-on-cube epitaxy with the substrate. The XSW VB information compares well to a density functional theory calculated projected density of states from the surface and substrate atoms. Altogether, this Letter represents a novel method for determining the contribution to the density of states by valence electrons from specific atomic surface sites.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Northwestern University, Evanston, IL (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357; FG02-03ER15457

OSTI ID:: 2481083

Journal Information:: Physical Review Letters, Journal Name: Physical Review Letters Journal Issue: 20 Vol. 128; ISSN 0031-9007

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

References (41)

Selective Amplification of CO Bond Hydrogenation on Pt/TiO ₂ : Catalytic Reaction and Sum-Frequency Generation Vibrational Spectroscopy Studies of Crotonaldehyde Hydrogenation Kennedy, Griffin; Baker, L. Robert; Somorjai, Gabor A. Angewandte Chemie, Vol. 126, Issue 13 https://doi.org/10.1002/ange.201400081	journal	February 2014
PHOTOELECTRON ANGULAR DISTRIBUTION PARAMETERS FOR ELEMENTS Z=1 TO Z=54 IN THE PHOTOELECTRON ENERGY RANGE 100–5000 eV Trzhaskovskaya, M. B.; Nefedov, V. I.; Yarzhemsky, V. G. Atomic Data and Nuclear Data Tables, Vol. 77, Issue 1 https://doi.org/10.1006/adnd.2000.0849	journal	January 2001
PHOTOELECTRON ANGULAR DISTRIBUTION PARAMETERS FOR ELEMENTS Z=55 to Z=100 IN THE PHOTOELECTRON ENERGY RANGE 100–5000 eV Trzhaskovskaya, M. B.; Nefedov, V. I.; Yarzhemsky, V. G. Atomic Data and Nuclear Data Tables, Vol. 82, Issue 2 https://doi.org/10.1006/adnd.2002.0886	journal	November 2002
Special Sites at Noble and Late Transition Metal Catalysts Hammer, B. Topics in Catalysis, Vol. 37, Issue 1 https://doi.org/10.1007/s11244-006-0004-y	journal	March 2006
Preparation of platinized strontium titanate covered with hollow silica and its activity for overall water splitting in a novel phase-boundary photocatalytic system Ikeda, S.; Hirao, K.; Ishino, S. Catalysis Today, Vol. 117, Issue 1-3 https://doi.org/10.1016/j.cattod.2006.05.037	journal	September 2006
Non-dipolar effects in photoelectron-based normal incidence X-ray standing wave experiments van Straaten, Gerben; Franke, Markus; Bocquet, François C. Journal of Electron Spectroscopy and Related Phenomena, Vol. 222 https://doi.org/10.1016/j.elspec.2017.07.007	journal	January 2018
Solar light photocatalytic hydrogen production from water over Pt and Au/TiO2(anatase/rutile) photocatalysts: Influence of noble metal and porogen promotion Rosseler, Olivier; Shankar, Muthukonda V.; Du, Maithaa Karkmaz-Le Journal of Catalysis, Vol. 269, Issue 1 https://doi.org/10.1016/j.jcat.2009.11.006	journal	January 2010
Non-dipole effects in high-energy photoelectron emission; identification and quantification using X-ray standing waves Woodruff, D. P. Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 547, Issue 1 https://doi.org/10.1016/j.nima.2005.05.024	journal	July 2005
Valence band photoelectron emission of analyzed with X-ray standing waves Thiess, Sebastian; Lee, Tien-Lin; Bottin, François Solid State Communications, Vol. 150, Issue 13-14 https://doi.org/10.1016/j.ssc.2010.02.009	journal	April 2010
Accurate valence band maximum determination for SrTiO3(001) Chambers, S. A.; Droubay, T.; Kaspar, T. C. Surface Science, Vol. 554, Issue 2-3 https://doi.org/10.1016/j.susc.2004.02.021	journal	April 2004
Interface of Pt with SrTiO3(001); A combined theoretical and experimental study Stoltz, S. E.; Ellis, D. E.; Bedzyk, M. J. Surface Science, Vol. 633 https://doi.org/10.1016/j.susc.2014.11.011	journal	March 2015
Surface and Interface Control in Nanoparticle Catalysis Xie, Chenlu; Niu, Zhiqiang; Kim, Dohyung Chemical Reviews, Vol. 120, Issue 2 https://doi.org/10.1021/acs.chemrev.9b00220	journal	October 2019
Direct Atomic-Scale Observation of Redox-Induced Cation Dynamics in an Oxide-Supported Monolayer Catalyst: WO _x /α-Fe ₂ O ₃ (0001) Feng, Zhenxing; Kim, Chang-Yong; Elam, Jeffrey W. Journal of the American Chemical Society, Vol. 131, Issue 51 https://doi.org/10.1021/ja906816y	journal	December 2009
Metal–Support Interactions between Nanosized Pt and Metal Oxides (WO ₃ and TiO ₂ ) Studied Using X-ray Photoelectron Spectroscopy Lewera, Adam; Timperman, Laure; Roguska, Agata The Journal of Physical Chemistry C, Vol. 115, Issue 41 https://doi.org/10.1021/jp2068446	journal	September 2011
Atomic Imaging of Oxide-Supported Metallic Nanocrystals Feng, Zhenxing; Kazimirov, Alexander; Bedzyk, Michael J. ACS Nano, Vol. 5, Issue 12 https://doi.org/10.1021/nn203273e	journal	November 2011
Hydrogen production from photolysis of steam adsorbed onto platinized SrTiO3 Carr, R. G.; Somorjai, G. A. Nature, Vol. 290, Issue 5807 https://doi.org/10.1038/290576a0	journal	April 1981
Charged and metallic molecular monolayers through surface-induced aromatic stabilization Heimel, G.; Duhm, S.; Salzmann, I. Nature Chemistry, Vol. 5, Issue 3 https://doi.org/10.1038/nchem.1572	journal	February 2013
Element- and momentum-resolved electronic structure of the dilute magnetic semiconductor manganese doped gallium arsenide Nemšák, Slavomír; Gehlmann, Mathias; Kuo, Cheng-Tai Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-05823-z	journal	August 2018
2D materials for quantum information science Liu, Xiaolong; Hersam, Mark C. Nature Reviews Materials, Vol. 4, Issue 10 https://doi.org/10.1038/s41578-019-0136-x	journal	August 2019
Evaporated Metallic Contacts to Conducting Strontium Titanate Single Crystals Carnes, James E.; Goodman, Alvin M. Journal of Applied Physics, Vol. 38, Issue 8 https://doi.org/10.1063/1.1710068	journal	July 1967
Impact of the electroforming process on the device stability of epitaxial Fe-doped SrTiO3 resistive switching cells Menke, T.; Dittmann, R.; Meuffels, P. Journal of Applied Physics, Vol. 106, Issue 11 https://doi.org/10.1063/1.3267485	journal	December 2009
Surface structure determination using x-ray standing waves Woodruff, D. P. Reports on Progress in Physics, Vol. 68, Issue 4 https://doi.org/10.1088/0034-4885/68/4/R01	journal	March 2005
Orbital contributions in the element-resolved valence electronic structure of Bi 2 Se 3 Kuo, Cheng-Tai; Lin, Shih-Chieh; Rueff, Jean-Pascal Physical Review B, Vol. 104, Issue 24 https://doi.org/10.1103/PhysRevB.104.245105	journal	December 2021
X-ray standing-wave investigations of valence electronic structure Woicik, J. C.; Nelson, E. J.; Heskett, D. Physical Review B, Vol. 64, Issue 12 https://doi.org/10.1103/PhysRevB.64.125115	journal	September 2001
Quadrupole effects in core and valence photoelectron emission from crystalline germanium measured via a spatially modulated x-ray interference field Nelson, E. J.; Woicik, J. C.; Pianetta, P. Physical Review B, Vol. 65, Issue 16 https://doi.org/10.1103/PhysRevB.65.165219	journal	April 2002
X-ray standing wave imaging of the 1 3 monolayer Sn/Ge(111) surface Okasinski, J. S.; Kim, C. -Y.; Walko, D. A. Physical Review B, Vol. 69, Issue 4 https://doi.org/10.1103/PhysRevB.69.041401	journal	January 2004
Normal-incidence x-ray standing-wave study of copper phthalocyanine submonolayers on Cu(111) and Au(111) Kröger, Ingo; Stadtmüller, Benjamin; Kleimann, Christoph Physical Review B, Vol. 83, Issue 19 https://doi.org/10.1103/PhysRevB.83.195414	journal	May 2011
Early stages of the Schottky barrier formation in submonolayer Pt on SrTi O 3 (001) Seo, Hosung; Demkov, Alexander A. Physical Review B, Vol. 92, Issue 24 https://doi.org/10.1103/PhysRevB.92.245301	journal	December 2015
Chemically Resolved Interface Structure of Epitaxial Graphene on SiC(0001) Emery, Jonathan D.; Detlefs, Blanka; Karmel, Hunter J. Physical Review Letters, Vol. 111, Issue 21 https://doi.org/10.1103/PhysRevLett.111.215501	journal	November 2013
Solution to the Surface Registration Problem Using X-Ray Standing Waves Golovchenko, J. A.; Patel, J. R.; Kaplan, D. R. Physical Review Letters, Vol. 49, Issue 8 https://doi.org/10.1103/PhysRevLett.49.560	journal	August 1982
Direct Measurement of Valence-Charge Asymmetry by X-Ray Standing Waves Woicik, J. C.; Nelson, E. J.; Pianetta, P. Physical Review Letters, Vol. 84, Issue 4 https://doi.org/10.1103/PhysRevLett.84.773	journal	January 2000
Hybridization and Bond-Orbital Components in Site-Specific X-Ray Photoelectron Spectra of Rutile T i O 2 Woicik, J. C.; Nelson, E. J.; Kronik, Leeor Physical Review Letters, Vol. 89, Issue 7 https://doi.org/10.1103/PhysRevLett.89.077401	journal	July 2002
Fourier-Expansion Solution of Atom Distributions in a Crystal Using X-Ray Standing Waves Cheng, L.; Fenter, P.; Bedzyk, M. J. Physical Review Letters, Vol. 90, Issue 25 https://doi.org/10.1103/PhysRevLett.90.255503	journal	June 2003
Surface of Strontium Titanate Herger, R.; Willmott, P. R.; Bunk, O. Physical Review Letters, Vol. 98, Issue 7 https://doi.org/10.1103/PhysRevLett.98.076102	journal	February 2007
Dynamical Diffraction of X Rays by Perfect Crystals Batterman, Boris W.; Cole, Henderson Reviews of Modern Physics, Vol. 36, Issue 3 https://doi.org/10.1103/RevModPhys.36.681	journal	July 1964
Third Row Transition Metals by X-ray Photoelectron Spectroscopy Engelhard, Mark; Baer, Don Surface Science Spectra, Vol. 7, Issue 1 https://doi.org/10.1116/1.1311915	journal	January 2000
Single Crystal Perovskites Analyzed Using X-ray Photoelectron Spectroscopy: 1. SrTiO3(001) Haasch, Richard T.; Breckenfeld, Eric; Martin, Lane W. Surface Science Spectra, Vol. 21, Issue 1 https://doi.org/10.1116/11.20140901	journal	December 2014
The Structure of Catalytically Active Gold on Titania Chen, M. S. Science, Vol. 306, Issue 5694 https://doi.org/10.1126/science.1102420	journal	October 2004
Control of Metal Nanocrystal Size Reveals Metal-Support Interface Role for Ceria Catalysts Cargnello, M.; Doan-Nguyen, V. V. T.; Gordon, T. R. Science, Vol. 341, Issue 6147 https://doi.org/10.1126/science.1240148	journal	July 2013
Atomic Control of the SrTiO₃ Crystal Surface Kawasaki, M.; Takahashi, K.; Maeda, T. Science, Vol. 266, Issue 5190, p. 1540-1542 https://doi.org/10.1126/science.266.5190.1540	journal	December 1994
Momentum-resolved electronic structure at a buried interface from soft X-ray standing-wave angle-resolved photoemission Gray, A. X.; Minár, J.; Plucinski, L. EPL (Europhysics Letters), Vol. 104, Issue 1 https://doi.org/10.1209/0295-5075/104/17004	journal	October 2013

Similar Records

Atomic imaging of oxide-supported metallic nanocrystals.

Journal Article · 2011 · ACS Nano · OSTI ID:1035773

Feng, Z; Kazimirov, A; Bedzyk, M J

Atomic-Imaging of Oxide Supported Metallic Nanocrystals

Journal Article · 2012 · ACS Nano · OSTI ID:1034188

Feng, Zhenxing; Kazimirov, Alexander; Bedzyk, Michael J

Valence of Sm adsorbed on Pd(001)

Journal Article · 1988 · Phys. Rev. B: Condens. Matter; (United States) · OSTI ID:5682474

Faeldt, A; K Kristensson, D; P Myers, H

Related Subjects

74 ATOMIC AND MOLECULAR PHYSICS
Adsorption
Density functional theory
Density of states
Interfaces
Surface & interfacial phenomena
Surfaces
X-ray photoelectron spectroscopy
X-ray standing waves

Title: Atomic-Site-Specific Surface Valence-Band Structure from X-Ray Standing-Wave Excited Photoemission

Citation Formats

References (41)

Similar Records

Related Subjects