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Title: Mechanistic insights into the co-recovery of nickel and iron via integrated carbon mineralization of serpentinized peridotite by harnessing organic ligands

Journal Article · · Physical Chemistry Chemical Physics. PCCP
DOI: https://doi.org/10.1039/D3CP04996E · OSTI ID:2480002
ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [3]; ORCiD logo [4]; ORCiD logo [4]; ORCiD logo [5]
  1. School of Civil and Environmental Engineering, Cornell University, Ithaca, NY 14853, USA, Department of Civil Engineering, Indian Institute of Technology Guwahati, Assam 781039, India
  2. Smith School of Chemical and Biomolecular Engineering, Cornell University, Ithaca, NY 14853, USA
  3. School of Civil and Environmental Engineering, Cornell University, Ithaca, NY 14853, USA
  4. Department of Civil Engineering, Indian Institute of Technology Guwahati, Assam 781039, India
  5. School of Civil and Environmental Engineering, Cornell University, Ithaca, NY 14853, USA, Smith School of Chemical and Biomolecular Engineering, Cornell University, Ithaca, NY 14853, USA

Mechanisms underlying co-recovery of energy critical metals and carbon mineralization by harnessing organic ligands are uncovered by investigating the influence of chemical and mineral heterogeneity and the morphological transformations of minerals.

Research Organization:
Cornell Univ., Ithaca, NY (United States)
Sponsoring Organization:
USDOE; USDOE Advanced Research Projects Agency - Energy (ARPA-E)
Grant/Contract Number:
AR0001721; SC0020263
OSTI ID:
2480002
Journal Information:
Physical Chemistry Chemical Physics. PCCP, Journal Name: Physical Chemistry Chemical Physics. PCCP Journal Issue: 12 Vol. 26; ISSN 1463-9076; ISSN PPCPFQ
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English

References (97)

CO2 Mineral Sequestration: Chemically Enhanced Aqueous Carbonation of Serpentine journal June 2003
Tailoring Metal-Organic Frameworks for CO2 Capture: The Amino Effect journal September 2011
A Petrographic Atlas of Ophiolite: An example from the eastern India-Asia collision zone book January 2014
Solubility and dissolution of iron oxides journal January 1991
Effects of EDTA on the accelerated carbonation behavior of steel slag used as cementitious materials journal February 2023
Changes in surface area and morphology and the mechanism of forsterite dissolution journal December 1978
Accelerated Carbonation of Ca- and Mg-Bearing Minerals and Industrial Wastes Using CO2 book January 2015
An experimental study of forsterite dissolution rates as a function of temperature and aqueous Mg and Si concentrations journal June 2001
Forsteritic olivine: effect of crystallographic direction on dissolution kinetics journal May 2000
Weathering and transport of chromium and nickel from serpentinite in the Coast Range ophiolite to the Sacramento Valley, California, USA journal October 2015
Detection and quantification of low levels of carbonate mineral species using thermogravimetric-mass spectrometry to validate CO2 drawdown via enhanced rock weathering journal November 2022
Production of forsterite from serpentine – Effects of magnesium chloride hexahydrate addition journal May 2015
Quantifying kinetics of mineralization of carbon dioxide by olivine under moderate conditions journal March 2019
CO2 mineralization and concurrent utilization for nickel conversion from nickel silicates to nickel sulfides journal February 2021
Effects of ethylenediamine tetra-acetic acid (EDTA) on the accelerated carbonation and properties of artificial steel slag aggregates journal April 2021
Could reactive MgO cement be a green solution? The effect of CO2 mineralization and manufacturing route on the potential global warming impact journal November 2021
mineral sequestration: physically activated dissolution of serpentine and pH swing process journal November 2004
Precipitation in the Mg-carbonate system—effects of temperature and CO2 pressure journal February 2008
Forsterite dissolution and magnesite precipitation at conditions relevant for deep saline aquifer storage and sequestration of carbon dioxide journal April 2005
Engineered carbon mineralization in ultramafic rocks for CO2 removal from air: Review and new insights journal September 2020
Carbamate Formation in Aqueous - diamine - CO2 Systems journal January 2013
Characterization of carbonated serpentine using XPS and TEM journal December 2004
Chromium and nickel mobilization from a contaminated soil using chelants journal June 2007
Column leaching of chromium and nickel from a contaminated soil using EDTA and citric acid journal May 2012
Elucidating the differences in the carbon mineralization behaviors of calcium and magnesium bearing alumino-silicates and magnesium silicates for CO2 storage journal October 2020
CO2 mineral sequestration and nickel recovery from laterite ore by using waste copperas journal January 2023
Dissolution kinetics of fosteritic olivine at 90–150°C including effects of the presence of CO2 journal September 2006
Fixation of CO2 by chrysotile in low-pressure dry and moist carbonation: Ex-situ and in-situ characterizations journal June 2010
Olivine reactivity with CO2 and H2O on a microscale: Implications for carbon sequestration journal January 2012
An experimental study of magnesite precipitation rates at neutral to alkaline conditions and 100–200°C as a function of pH, aqueous solution composition and chemical affinity journal April 2012
On the hydration of olivine in ultramafic rocks: Implications from Fe isotopes in serpentinites journal October 2017
Mechanism of olivine and glass alteration under experimental H2O-CO2 based supercritical gas: Application to modern and ancient Venus journal October 2022
Geochemical characteristics of mafic and ultramafic rocks from the Naga Hills Ophiolite, India: Implications for petrogenesis journal March 2018
Mineral sequestration of carbon dioxide in basalt: A pre-injection overview of the CarbFix project journal May 2010
Enhancing serpentine dissolution kinetics for mineral carbon dioxide sequestration journal July 2011
The role of H2O in the carbonation of forsterite in supercritical CO2 journal July 2011
Comprehensive analysis of direct aqueous mineral carbonation using dissolution enhancing organic additives journal July 2012
Comparative reactivity study of forsterite and antigorite in wet supercritical CO2 by in situ infrared spectroscopy journal October 2013
Nesquehonite sequesters transition metals and CO 2 during accelerated carbon mineralisation journal December 2016
Fate of transition metals during passive carbonation of ultramafic mine tailings via air capture with potential for metal resource recovery journal April 2018
Production of cleaner high-strength cementing material using steel slag under elevated-temperature carbonation journal March 2022
Accelerated CO2 mineralization and utilization for selective battery metals recovery from olivine and laterites journal March 2023
Dissolution of heat activated serpentine for CO2 sequestration: The effect of silica precipitation at different temperature and pH values journal March 2019
Metal recovery from iron slag via pH swing-assisted carbon mineralization with various organic ligands journal March 2023
Process optimization for integrated mineralization of carbon dioxide and metal recovery of red mud journal April 2020
Simultaneous CO2 utilization and rare earth elements recovery by novel aqueous carbon mineralization of blast furnace slag journal April 2022
Microtextural evolution of chrome spinels in dunites from Mayodia ophiolite complex, Arunachal Pradesh, India: Implications for a missing link in the “two-stage” alteration mechanism journal July 2022
Kinetics and mechanism of mineral carbonation of olivine for CO2 sequestration journal January 2019
Kinetics of antigorite dehydroxylation for CO2 sequestration journal June 2022
A review of mineral carbonation technology in sequestration of CO2 journal September 2013
Regenerable solvents mediate accelerated low temperature CO2 capture and carbon mineralization of ash and nano-scale calcium carbonate formation journal May 2022
Dehydroxylation of serpentine minerals: Implications for mineral carbonation journal March 2014
Enhanced CO2 mineralization and selective critical metal extraction from olivine and laterites journal September 2023
Determination of ethylenediaminetetraacetic acid in boiler water by liquid chromatography journal February 1984
Tuning Reactive Crystallization Pathways for Integrated CO2 Capture, Conversion, and Storage via Mineralization journal January 2024
From Unavoidable CO2 Source to CO2 Sink? A Cement Industry Based on CO2 Mineralization journal March 2021
Nanoscale Mg-Depleted Layers Slow Carbonation of Forsterite (Mg2SiO4) When Water Is Limited journal December 2022
Evidence for Carbonate Surface Complexation during Forsterite Carbonation in Wet Supercritical Carbon Dioxide journal July 2015
Controls on CO 2 Mineralization Using Natural and Industrial Alkaline Solids under Ambient Conditions journal August 2021
Carbonation of Silicate Minerals and Industrial Wastes and Their Potential Use as Sustainable Construction Materials book September 2015
Carbon Sequestration via Aqueous Olivine Mineral Carbonation:  Role of Passivating Layer Formation journal August 2006
Ex Situ Aqueous Mineral Carbonation journal April 2007
Assessing the Origin and Fate of Cr, Ni, Cu, Zn, Pb, and V in Industrial Polluted Soil by Combined Microspectroscopic Techniques and Bulk Extraction Methods journal August 2007
Reaction Mechanisms for Enhancing Mineral Sequestration of CO 2 journal July 2009
Effect of Secondary Phase Formation on the Carbonation of Olivine journal August 2010
Comprehensive Study of the Hydration and Dehydration Reactions of Carbon Dioxide in Aqueous Solution journal December 2009
Carbon Capture and Utilization by mineralization of cement pastes derived from recycled concrete journal March 2020
Carbon dioxide and hydrogen adsorption study on surface-modified HKUST-1 with diamine/triamine journal October 2022
Flue gas CO 2 mineralization using thermally activated serpentine: from single- to double-step carbonation journal January 2014
A review of mineral carbonation technologies to sequester CO 2 journal January 2014
Influence of Mg/CTAB ratio on the structural, physicochemical properties and catalytic activity of amorphous mesoporous magnesium silicate catalysts journal January 2019
CO 2 utilization in built environment via the P CO2 swing carbonation of alkaline solid wastes with different mineralogy journal January 2021
Integrated low carbon H2 conversion with in situ carbon mineralization from aqueous biomass oxygenate precursors by tuning reactive multiphase chemical interactions journal January 2023
On the role of system integration of carbon capture and mineralization in achieving net-negative emissions in industrial sectors journal January 2023
Chemical and morphological changes during olivine carbonation for CO2 storage in the presence of NaCl and NaHCO3 journal January 2014
Bonding-state characterization of the constitutent elements of silicate minerals by X-ray photoelectron spectroscopy
  • Seyama, Haruhiko; Soma, Mitsuyuki
  • Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, Vol. 81, Issue 2 https://doi.org/10.1039/f19858100485
journal January 1985
Chemical and morphological evolution of a silicate surface under low-energy ion irradiation journal February 2008
In situ carbonation of peridotite for CO2 storage journal November 2008
Carbon mineralization with concurrent critical metal recovery from olivine journal August 2022
Fizzy ore processing sequesters CO 2 while supplying critical metals journal September 2022
NaHCO3-promoted olivine weathering with H2 generation and CO2 sequestration in alkaline hydrothermal system journal May 2019
Geochemistry of volcanic rocks from the Naga Hills Ophiolites, northeast India and their inferred tectonic setting journal May 1989
Rates and Mechanisms of Mineral Carbonation in Peridotite: Natural Processes and Recipes for Enhanced, in situ CO 2 Capture and Storage journal May 2011
Etch pits on naturally altered olivine from dunites of the Appalachian Blue Ridge Mountains, North Carolina, USA journal February 2008
Element scavenging by recently formed travertine deposits in the alkaline springs from the Oman Semail Ophiolite journal November 2014
Thermal decomposition of ethylenediaminetetraacetic acid in the presence of 1,2-phenylenediamine and hydrochloric acid journal October 2006
Etch-pit size, dissolution rate, and time in the experimental dissolution of olivine: Implications for estimating olivine lifetime at the surface of Mars journal November 2014
Mechanism for the dissolution of olivine series minerals in acidic solutions journal February 2006
Carbon Mineralization: From Natural Analogues to Engineered Systems journal January 2013
Observation of the depassivation effect of attrition on magnesium silicates' direct aqueous carbonation products journal August 2022
Exploring the Thermodynamic Limits of Enhanced H2 Recovery With Inherent Carbon Removal From Low Value Aqueous Biomass Oxygenate Precursors journal September 2021
XPS Study on the Stability and Transformation of Hydrate and Carbonate Phases within MgO Systems journal January 2017
Nickel Extraction from Olivine: Effect of Carbonation Pre-Treatment journal September 2015
Synthesis of Nanosilica via Olivine Mineral Carbonation under High Pressure in an Autoclave journal June 2019
Integrated Mineral Carbonation of Ultramafic Mine Deposits—A Review journal April 2018
Platinum Group Minerals and Silicate Inclusions In Chromitite From the Naga-Manipur Ophiolite Complex, Indo-Myanmar Orogenic Belt, Northeast India journal March 2016
Accelerating Mineral Carbonation in Ultramafic Mine Tailings via Direct CO2 Reaction and Heap Leaching with Potential for Base Metal Enrichment and Recovery journal March 2020