Interphase formation versus fluoride-ion insertion in tunnel-structured transition metal antimonites

Giem, Alice R.; Ayala, Jaime R.; Cheng, Jingxiang; Weiland, Conan; Jaye, Cherno; Fischer, Daniel A.; Banerjee, Sarbajit

doi:10.1039/D4CC04331F

Title: Interphase formation versus fluoride-ion insertion in tunnel-structured transition metal antimonites

Journal Article · 05 December 2024 · ChemComm

DOI: https://doi.org/10.1039/D4CC04331F · OSTI ID:2479989

Giem, Alice R. ^[1];

^[1];

^[1]; Weiland, Conan ^[2]; Jaye, Cherno ^[2]; Fischer, Daniel A. ^[2];

^[1]

Department of Chemistry, Texas A&M University, College Station, TX, 77843, USA, Department of Material Science & Engineering, Texas A&M University, College Station, TX 77843, USA
Material Measurement Laboratory, National Institute of Standards and Technology, Gaithersburg, MD 20899, USA

Understanding the competitive nature of insertion versus interphase formation is key to the design of insertion electrodes of fluoride-ion batteries.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: SC0012704

OSTI ID:: 2479989

Journal Information:: ChemComm, Journal Name: ChemComm Journal Issue: 98 Vol. 60; ISSN CHCOFS; ISSN 1359-7345

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

References (28)

Sodium‐Ion Batteries Paving the Way for Grid Energy Storage Hirsh, Hayley S.; Li, Yixuan; Tan, Darren H. S. Advanced Energy Materials, Vol. 10, Issue 32 https://doi.org/10.1002/aenm.202001274	journal	July 2020
Post‐Lithium Storage—Shaping the Future Esser, Birgit; Ehrenberg, Helmut; Fichtner, Maximilian Advanced Energy Materials https://doi.org/10.1002/aenm.202402824	journal	August 2024
Reconsidering Anode Materials for Fluoride‐Ion Batteries–The Unexpected Roles of Carbide Formation** McTaggart, Don; Warren, Scott C.; Clemens, Oliver ChemSusChem, Vol. 16, Issue 18 https://doi.org/10.1002/cssc.202300486	journal	July 2023
Powerful oxidizing agents for the oxidative deintercalation of lithium from transition-metal oxides Wizansky, Abigail R.; Rauch, Paul E.; Disalvo, Francis J. Journal of Solid State Chemistry, Vol. 81, Issue 2 https://doi.org/10.1016/0022-4596(89)90007-8	journal	August 1989
XPS determination of Mn oxidation states in Mn (hydr)oxides Ilton, Eugene S.; Post, Jeffrey E.; Heaney, Peter J. Applied Surface Science, Vol. 366 https://doi.org/10.1016/j.apsusc.2015.12.159	journal	March 2016
The case for fluoride-ion batteries Xiao, Albert W.; Galatolo, Giulia; Pasta, Mauro Joule, Vol. 5, Issue 11 https://doi.org/10.1016/j.joule.2021.09.016	journal	November 2021
Low-temperature solvothermal fluorination method and synthesis of La4Ni3O8F oxyfluorides via the La4Ni3O8 infinite-layer intermediate Blakely, Colin K.; Bruno, Shaun R.; Kraemer, Shannon K. Journal of Solid State Chemistry, Vol. 289 https://doi.org/10.1016/j.jssc.2020.121490	journal	September 2020
Emerging trends in sustainable battery chemistries Xu, Panpan; Tan, Darren H. S.; Chen, Zheng Trends in Chemistry, Vol. 3, Issue 8 https://doi.org/10.1016/j.trechm.2021.04.007	journal	August 2021
Lessons learned from FeSb2O4 on stereoactive lone pairs as a design principle for anion insertion Zaheer, Wasif; Agbeworvi, George; Perez-Beltran, Saul Cell Reports Physical Science, Vol. 2, Issue 10 https://doi.org/10.1016/j.xcrp.2021.100592	journal	October 2021
Lone but Not Alone: Precise Positioning of Lone Pairs for the Design of Photocatalytic Architectures Handy, Joseph V.; Zaheer, Wasif; Rothfuss, Arianna R. M. Chemistry of Materials, Vol. 34, Issue 4 https://doi.org/10.1021/acs.chemmater.1c03762	journal	January 2022
Electron and Ion Transport in Lithium and Lithium-Ion Battery Negative and Positive Composite Electrodes Quilty, Calvin D.; Wu, Daren; Li, Wenzao Chemical Reviews, Vol. 123, Issue 4 https://doi.org/10.1021/acs.chemrev.2c00214	journal	February 2023
Topotactic Fluorine Insertion into the Channels of FeSb ₂ O ₄ -Related Materials de Laune, Benjamin P.; Rees, Gregory J.; Marco, José F. Inorganic Chemistry, Vol. 56, Issue 16 https://doi.org/10.1021/acs.inorgchem.7b01613	journal	July 2017
How Bulk Sensitive is Hard X-ray Photoelectron Spectroscopy: Accounting for the Cathode–Electrolyte Interface when Addressing Oxygen Redox Lebens-Higgins, Zachary W.; Chung, Hyeseung; Zuba, Mateusz J. The Journal of Physical Chemistry Letters, Vol. 11, Issue 6 https://doi.org/10.1021/acs.jpclett.0c00229	journal	February 2020
Reversible Room-Temperature Fluoride-Ion Insertion in a Tunnel-Structured Transition Metal Oxide Host Zaheer, Wasif; Andrews, Justin L.; Parija, Abhishek ACS Energy Letters, Vol. 5, Issue 8 https://doi.org/10.1021/acsenergylett.0c01328	journal	July 2020
Room-Temperature Electrochemical Fluoride (De)insertion into CsMnFeF₆ Andrews, Jessica L.; McClure, Eric T.; Jew, Kenneth K. ACS Energy Letters, Vol. 7, Issue 7 https://doi.org/10.1021/acsenergylett.2c01324	journal	June 2022
Multiple Scattering Calculations of Bonding and X-ray Absorption Spectroscopy of Manganese Oxides Gilbert, B.; Frazer, B. H.; Belz, A. The Journal of Physical Chemistry A, Vol. 107, Issue 16 https://doi.org/10.1021/jp021493s	journal	April 2003
Dynamic behaviour of interphases and its implication on high-energy-density cathode materials in lithium-ion batteries Li, Wangda; Dolocan, Andrei; Oh, Pilgun Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms14589	journal	April 2017
Battery technology and recycling alone will not save the electric mobility transition from future cobalt shortages Zeng, Anqi; Chen, Wu; Rasmussen, Kasper Dalgas Nature Communications, Vol. 13, Issue 1 https://doi.org/10.1038/s41467-022-29022-z	journal	March 2022
Future material demand for automotive lithium-based batteries Xu, Chengjian; Dai, Qiang; Gaines, Linda Communications Materials, Vol. 1, Issue 1 https://doi.org/10.1038/s43246-020-00095-x	journal	December 2020
Antimony oxofluorides – a synthesis concept that yields phase pure samples and single crystals Ali, Sk Imran; Johnsson, Mats Dalton Transactions, Vol. 45, Issue 30 https://doi.org/10.1039/C6DT01897A	journal	January 2016
The hydrothermal synthesis, crystal structure and electrochemical properties of MnSb₂O₄ Roelsgaard, Martin; Nørby, Peter; Eikeland, Espen Dalton Transactions, Vol. 45, Issue 47 https://doi.org/10.1039/C6DT03459D	journal	January 2016
La ₂ CoO ₄ : a new intercalation based cathode material for fluoride ion batteries with improved cycling stability Nowroozi, Mohammad Ali; Ivlev, Sergei; Rohrer, Jochen Journal of Materials Chemistry A, Vol. 6, Issue 11 https://doi.org/10.1039/C7TA09427B	journal	January 2018
Insights into the first multi-transition-metal containing Ruddlesden–Popper-type cathode for all-solid-state fluoride ion batteries Vanita, Vanita; Waidha, Aamir Iqbal; Vasala, Sami Journal of Materials Chemistry A, Vol. 12, Issue 15 https://doi.org/10.1039/D4TA00704B	journal	January 2024
Batteries based on fluoride shuttle Anji Reddy, M.; Fichtner, M. Journal of Materials Chemistry, Vol. 21, Issue 43, p. 17059-17062 https://doi.org/10.1039/c1jm13535j	journal	October 2011
Correlation between oxygen vacancies and magnetism in Mn-doped Y2O3 nanocrystals investigated by defect engineering techniques Wu, T. S.; Chen, Y. C.; Shiu, Y. F. Applied Physics Letters, Vol. 101, Issue 2 https://doi.org/10.1063/1.4732094	journal	July 2012
Standard Electrode Potentials and Temperature Coefficients in Water at 298.15 K Bratsch, Steven G. Journal of Physical and Chemical Reference Data, Vol. 18, Issue 1 https://doi.org/10.1063/1.555839	journal	January 1989
Expression and interactions of stereochemically active lone pairs and their relation to structural distortions and thermal conductivity Tolborg, Kasper; Gatti, Carlo; Iversen, Bo B. IUCrJ, Vol. 7, Issue 3 https://doi.org/10.1107/S2052252520003619	journal	March 2020
Room-temperature cycling of metal fluoride electrodes: Liquid electrolytes for high-energy fluoride ion cells Davis, Victoria K.; Bates, Christopher M.; Omichi, Kaoru Science, Vol. 362, Issue 6419 https://doi.org/10.1126/science.aat7070	journal	December 2018

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