Electroanalytical characterization of Np( vi )/Np( v ) redox in a pentadentate ligand environment and stabilization of [Np V O 2 ] + by hydrogen bonding

Mikeska, Emily R.; Curry, T. Davis; Wilson, Richard E.; Blakemore, James D.

doi:10.1039/D4DT02557A

Title: Electroanalytical characterization of Np( vi )/Np( v ) redox in a pentadentate ligand environment and stabilization of [Np ^V O ₂ ] ⁺ by hydrogen bonding

Journal Article · 09 December 2024 · Dalton Transactions

DOI: https://doi.org/10.1039/D4DT02557A · OSTI ID:2479976

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Department of Chemistry, University of Kansas, 1567 Irving Hill Road, Lawrence, KS 66045, USA, Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, IL 60439, USA
Department of Chemistry, University of Kansas, 1567 Irving Hill Road, Lawrence, KS 66045, USA
Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, IL 60439, USA

Np( vi/v ) redox in a molecular complex was probed in protic and aprotic organic media with electroanalytical, spectroscopic, and structural work. Insights into the reversible electron transfer to interconvert Np( vi ) and Np( v ) have been obtained.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: NONE; SC0019169; SC0014664; AC02-06CH11357

OSTI ID:: 2479976

Journal Information:: Dalton Transactions, Journal Name: Dalton Transactions Journal Issue: 48 Vol. 53; ISSN 1477-9226; ISSN ICHBD9

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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Title: Electroanalytical characterization of Np( vi )/Np( v ) redox in a pentadentate ligand environment and stabilization of [Np ^V O ₂ ] ⁺ by hydrogen bonding