Exploring battery material failure mechanisms through synchrotron X-ray characterization techniques

Fang, Lingzhe; Liu, Xiaozhao; Li, Tao

doi:10.1016/j.jechem.2024.02.019

Title: Exploring battery material failure mechanisms through synchrotron X-ray characterization techniques

Journal Article · 05 March 2024 · Journal of Energy Chemistry

DOI: https://doi.org/10.1016/j.jechem.2024.02.019 · OSTI ID:2479098

Fang, Lingzhe ^[1];

^[1];

^[2]

Northern Illinois Univ., DeKalb, IL (United States)
Northern Illinois Univ., DeKalb, IL (United States); Argonne National Laboratory (ANL), Argonne, IL (United States)

Rechargeable battery cycling performance and related safety have been persistent concerns. Here, it is crucial to decipher the capacity fading induced by electrode material failure via a range of techniques. Among these, synchrotron-based X-ray techniques with high flux and brightness play a key role in understanding degradation mechanisms. In this comprehensive review, we summarized recent advancements in degradation modes and mechanisms that revealed by synchrotron X-ray methodologies. Subsequently, an overview of X-ray absorption spectroscopy and X-ray scattering techniques are introduced for the characterizing failure phenomena at local coordination atomic environment and long-range order crystal structure scale, respectively. At last, we envision the future of material failure mechanism exploration.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities (SUF)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 2479098

Journal Information:: Journal of Energy Chemistry, Journal Name: Journal of Energy Chemistry Vol. 94; ISSN 2095-4956

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (37)

Combining In Situ Synchrotron X-Ray Diffraction and Absorption Techniques with Transmission Electron Microscopy to Study the Origin of Thermal Instability in Overcharged Cathode Materials for Lithium-Ion Batteries Nam, Kyung-Wan; Bak, Seong-Min; Hu, Enyuan Advanced Functional Materials, Vol. 23, Issue 8 https://doi.org/10.1002/adfm.201200693	journal	June 2012
An in-situ spectroscopy investigation of alkali metal interaction mechanism with the imide functional group Lian, Xu; Ma, Zhirui; Zhang, Zhonghan Nano Research, Vol. 13, Issue 12 https://doi.org/10.1007/s12274-020-2991-6	journal	August 2020
A novel SAXS/XRD/XAFS combined technique for in-situ time-resolved simultaneous measurements Wu, Zhonghua; Liu, Yunpeng; Xing, Xueqing Nano Research, Vol. 16, Issue 1 https://doi.org/10.1007/s12274-022-4742-3	journal	July 2022
In-depth study on diffusion of oxygen vacancies in Li(NixCoyMnz)O2 cathode materials under thermal induction Wei, Zesen; Liang, Chen; Jiang, Lihua Energy Storage Materials, Vol. 47 https://doi.org/10.1016/j.ensm.2022.01.054	journal	May 2022
Insight into the structural evolution and thermal behavior of LiNi0.8Co0.1Mn0.1O2 cathode under deep charge Liang, Chen; Jiang, Lihua; Wei, Zesen Journal of Energy Chemistry, Vol. 65 https://doi.org/10.1016/j.jechem.2021.06.010	journal	February 2022
Structure-Induced Reversible Anionic Redox Activity in Na Layered Oxide Cathode Rong, Xiaohui; Liu, Jue; Hu, Enyuan Joule, Vol. 2, Issue 1 https://doi.org/10.1016/j.joule.2017.10.008	journal	January 2018
Degradation diagnostics for lithium ion cells Birkl, Christoph R.; Roberts, Matthew R.; McTurk, Euan Journal of Power Sources, Vol. 341 https://doi.org/10.1016/j.jpowsour.2016.12.011	journal	February 2017
Anionic and cationic redox and interfaces in batteries: Advances from soft X-ray absorption spectroscopy to resonant inelastic scattering Yang, Wanli; Devereaux, Thomas P. Journal of Power Sources, Vol. 389 https://doi.org/10.1016/j.jpowsour.2018.04.018	journal	June 2018
Decoupling Cationic–Anionic Redox Processes in a Model Li-Rich Cathode via Operando X-ray Absorption Spectroscopy Assat, Gaurav; Iadecola, Antonella; Delacourt, Charles Chemistry of Materials, Vol. 29, Issue 22 https://doi.org/10.1021/acs.chemmater.7b03434	journal	November 2017
Capacity Fading of Ni-Rich Li[Ni _x Co _y Mn _{1– x – y} ]O ₂ (0.6 ≤ x ≤ 0.95) Cathodes for High-Energy-Density Lithium-Ion Batteries: Bulk or Surface Degradation? Ryu, Hoon-Hee; Park, Kang-Joon; Yoon, Chong S. Chemistry of Materials, Vol. 30, Issue 3 https://doi.org/10.1021/acs.chemmater.7b05269	journal	January 2018
Fluorination-Guided Li-Anchoring Behaviors on Phthalocyanines Lian, Xu; Ma, Zhirui; Zhang, Zhonghan The Journal of Physical Chemistry C, Vol. 125, Issue 15 https://doi.org/10.1021/acs.jpcc.1c00831	journal	April 2021
Capacity Fading Mechanisms in Ni-Rich Single-Crystal NCM Cathodes Ryu, Hoon-Hee; Namkoong, Been; Kim, Jae-Hyung ACS Energy Letters, Vol. 6, Issue 8 https://doi.org/10.1021/acsenergylett.1c01089	journal	July 2021
Structural and Interphasial Stabilities of Sulfurized Polyacrylonitrile (SPAN) Cathode Tan, Sha; Rahman, Muhammad Mominur; Wu, Zhaohui ACS Energy Letters, Vol. 8, Issue 6 https://doi.org/10.1021/acsenergylett.3c00281	journal	May 2023
In Operando Small-Angle X-ray Scattering Investigation of Nanostructured Polymer Electrolyte for Lithium-Ion Batteries Möhl, Gilles E.; Metwalli, Ezzeldin; Müller-Buschbaum, Peter ACS Energy Letters, Vol. 3, Issue 7 https://doi.org/10.1021/acsenergylett.8b00763	journal	June 2018
In Operando Monitoring of the Pore Dynamics in Ordered Mesoporous Electrode Materials by Small Angle X-ray Scattering Park, Gwi Ok; Yoon, Jeongbae; Park, Eunjun ACS Nano, Vol. 9, Issue 5 https://doi.org/10.1021/acsnano.5b01378	journal	April 2015
Operando Grazing Incidence Small-Angle X-ray Scattering/X-ray Diffraction of Model Ordered Mesoporous Lithium-Ion Battery Anodes Bhaway, Sarang M.; Qiang, Zhe; Xia, Yanfeng ACS Nano, Vol. 11, Issue 2 https://doi.org/10.1021/acsnano.6b06708	journal	February 2017
Structural Changes and Thermal Stability of Charged LiNi _x Mn _y Co _z O ₂ Cathode Materials Studied by Combined In Situ Time-Resolved XRD and Mass Spectroscopy Bak, Seong-Min; Hu, Enyuan; Zhou, Yongning ACS Applied Materials & Interfaces, Vol. 6, Issue 24 https://doi.org/10.1021/am506712c	journal	December 2014
Correlating Structural Changes and Gas Evolution during the Thermal Decomposition of Charged Li _x Ni _0.8 Co _0.15 Al _0.05 O ₂ Cathode Materials Bak, Seong-Min; Nam, Kyung-Wan; Chang, Wonyoung Chemistry of Materials, Vol. 25, Issue 3 https://doi.org/10.1021/cm303096e	journal	January 2013
Mesoscale Effects in Electrochemical Conversion: Coupling of Chemistry to Atomic- and Nanoscale Structure in Iron-Based Electrodes Wiaderek, Kamila M.; Borkiewicz, Olaf J.; Pereira, Nathalie Journal of the American Chemical Society, Vol. 136, Issue 17 https://doi.org/10.1021/ja501854y	journal	April 2014
Distinct charge dynamics in battery electrodes revealed by in situ and operando soft X-ray spectroscopy Liu, Xiaosong; Wang, Dongdong; Liu, Gao Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms3568	journal	October 2013
Native lattice strain induced structural earthquake in sodium layered oxide cathodes Xu, Gui-Liang; Liu, Xiang; Zhou, Xinwei Nature Communications, Vol. 13, Issue 1 https://doi.org/10.1038/s41467-022-28052-x	journal	January 2022
On the nanoscale structural evolution of solid discharge products in lithium-sulfur batteries using operando scattering Prehal, Christian; von Mentlen, Jean-Marc; Drvarič Talian, Sara Nature Communications, Vol. 13, Issue 1 https://doi.org/10.1038/s41467-022-33931-4	journal	October 2022
Evolution of redox couples in Li- and Mn-rich cathode materials and mitigation of voltage fade by reducing oxygen release Hu, Enyuan; Yu, Xiqian; Lin, Ruoqian Nature Energy, Vol. 3, Issue 8 https://doi.org/10.1038/s41560-018-0207-z	journal	July 2018
Challenges in speeding up solid-state battery development Janek, Jürgen; Zeier, Wolfgang G. Nature Energy, Vol. 8, Issue 3 https://doi.org/10.1038/s41560-023-01208-9	journal	February 2023
Bulk fatigue induced by surface reconstruction in layered Ni-rich cathodes for Li-ion batteries Xu, Chao; Märker, Katharina; Lee, Juhan Nature Materials, Vol. 20, Issue 1 https://doi.org/10.1038/s41563-020-0767-8	journal	August 2020
Material science as a cornerstone driving battery research Tarascon, Jean-Marie Nature Materials, Vol. 21, Issue 9 https://doi.org/10.1038/s41563-022-01342-x	journal	August 2022
Compositionally complex doping for zero-strain zero-cobalt layered cathodes Zhang, Rui; Wang, Chunyang; Zou, Peichao Nature, Vol. 610, Issue 7930 https://doi.org/10.1038/s41586-022-05115-z	journal	September 2022
Charging sustainable batteries Bauer, Christian; Burkhardt, Simon; Dasgupta, Neil P. Nature Sustainability, Vol. 5, Issue 3 https://doi.org/10.1038/s41893-022-00864-1	journal	March 2022
Small-angle X-ray and neutron scattering Jeffries, Cy M.; Ilavsky, Jan; Martel, Anne Nature Reviews Methods Primers, Vol. 1, Issue 1 https://doi.org/10.1038/s43586-021-00064-9	journal	October 2021
Advances in soft X-ray RIXS for studying redox reaction states in batteries Wu, Jue; Yang, Yong; Yang, Wanli Dalton Transactions, Vol. 49, Issue 39 https://doi.org/10.1039/D0DT01782E	journal	January 2020
Spatial dynamics of lithiation and lithium plating during high-rate operation of graphite electrodes Finegan, Donal P.; Quinn, Alexander; Wragg, David S. Energy & Environmental Science, Vol. 13, Issue 8 https://doi.org/10.1039/D0EE01191F	journal	January 2020
Quantification of heterogeneous, irreversible lithium plating in extreme fast charging of lithium-ion batteries Paul, Partha P.; Thampy, Vivek; Cao, Chuntian Energy & Environmental Science, Vol. 14, Issue 9 https://doi.org/10.1039/D1EE01216A	journal	January 2021
High-efficiency, anode-free lithium–metal batteries with a close-packed homogeneous lithium morphology Su, Laisuo; Charalambous, Harry; Cui, Zehao Energy & Environmental Science, Vol. 15, Issue 2 https://doi.org/10.1039/D1EE03103A	journal	January 2022
Multimodal quantification of degradation pathways during extreme fast charging of lithium-ion batteries McShane, Eric J.; Paul, Partha P.; Tanim, Tanvir R. Journal of Materials Chemistry A, Vol. 10, Issue 44 https://doi.org/10.1039/D2TA05887A	journal	January 2022
Prolonging the cycling lifetime of lithium metal batteries with a monolithic and inorganic-rich solid electrolyte interphase Yang, Jinlin; Li, Menghao; Sun, Zejun Energy & Environmental Science, Vol. 16, Issue 9 https://doi.org/10.1039/D3EE00161J	journal	January 2023
Fourth-generation light sources Chapman, Henry N. IUCrJ, Vol. 10, Issue 3 https://doi.org/10.1107/S2052252523003585	journal	April 2023
Why do batteries fail? Palacin, M. R.; de Guibert, A. Science, Vol. 351, Issue 6273 https://doi.org/10.1126/science.1253292	journal	February 2016

Similar Records

Deciphering the Reaction Mechanism of Lithium–Sulfur Batteries by In Situ/Operando Synchrotron-Based Characterization Techniques

Journal Article · 2019 · Advanced Energy Materials · OSTI ID:1558085

Yan, Yingying; Cheng, Chen; Zhang, Liang; +2 more

Synchrotron X-Ray and Neutron Diffraction, Total Scattering, and Small-Angle Scattering Techniques for Rechargeable Battery Research

Journal Article · 2018 · Small Methods · OSTI ID:1558997

Ren, Yang; Zuo, Xiaobing

Structural and chemical evolution in layered oxide battery cathodes revealed by synchrotron techniques

Program Document · · OSTI ID:1785987

Qian, Guannan

Related Subjects

25 ENERGY STORAGE
Battery failure
Synchrotron-based techniques
X-ray absorption spectroscopy
X-ray scattering

Title: Exploring battery material failure mechanisms through synchrotron X-ray characterization techniques

Citation Formats

References (37)

Similar Records

Related Subjects