Multi–Stage Optimization of Pore Size and Shape in Pore–Space–Partitioned Metal–Organic Frameworks for Highly Selective and Sensitive Benzene Capture

Chen, Yichong; Wang, Wei; Alston, Samuel; Xiao, Yuchen; Ajayan, Pooja; Bu, Xianhui; Feng, Pingyun

doi:10.1002/anie.202415576

Title: Multi–Stage Optimization of Pore Size and Shape in Pore–Space–Partitioned Metal–Organic Frameworks for Highly Selective and Sensitive Benzene Capture

Journal Article · 19 September 2024 · Angewandte Chemie (International Edition)

DOI: https://doi.org/10.1002/anie.202415576 · OSTI ID:2478390

Chen, Yichong ^[1]; Wang, Wei ^[1]; Alston, Samuel ^[1]; Xiao, Yuchen ^[1]; Ajayan, Pooja ^[1]; Bu, Xianhui ^[2];

^[1]

University of California, Riverside, CA (United States)
California State University, Long Beach, CA (United States)

Compared to exploratory development of new structure types, pushing the limits of isoreticular synthesis on a high-performance MOF platform may have higher probability of achieving targeted properties. Multi-modular MOF platforms could offer even more opportunities by expanding the scope of isoreticular chemistry. However, navigating isoreticular chemistry towards best properties on a multi-modular platform is challenging due to multiple interconnected pathways. Here on the multi-modular pacs (partitioned acs) platform, we demonstrate accessibility to a new regime of pore geometry using two independently adjustable modules (framework-forming module 1 and pore-partitioning module 2). A series of new pacs materials have been made. Benzene/cyclohexane selectivity is tuned, progressively, from 4.5 to 15.6 to 195.4 and to 482.5 by pushing the boundary of the pacs platform towards the smallest modules known so far. The exceptional stability of these materials in retaining both porosity and single crystallinity enables single-crystal diffraction studies of different crystal forms (as-synthesized, activated, guest-loaded) that help reveal the mechanistic aspects of adsorption in pacs materials.

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Research Organization:: University of California, Riverside, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division (MSE); NSF MRI

Grant/Contract Number:: SC0010596

OSTI ID:: 2478390

Journal Information:: Angewandte Chemie (International Edition), Journal Name: Angewandte Chemie (International Edition) Journal Issue: 3 Vol. 64; ISSN 1433-7851

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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