Tailorable Multi–Modular Pore–Space–Partitioned Vanadium Metal–Organic Frameworks for Gas Separation

Wang, Wei; Chen, Yichong; Feng, Pingyun; Bu, Xianhui

doi:10.1002/adma.202403834

Title: Tailorable Multi–Modular Pore–Space–Partitioned Vanadium Metal–Organic Frameworks for Gas Separation

Journal Article · 08 May 2024 · Advanced Materials

DOI: https://doi.org/10.1002/adma.202403834 · OSTI ID:2478388

Wang, Wei ^[1]; Chen, Yichong ^[2];

^[2]; Bu, Xianhui ^[1]

California State University Long Beach, CA (United States)
University of California, Riverside, CA (United States)

Currently, few porous vanadium metal-organic frameworks (V-MOFs) are known and even fewer are obtainable as single crystals, resulting in limited information on their structures and properties. Here this work demonstrates remarkable promise of V-MOFs by presenting an extensible family of V-MOFs with tailorable pore geometry and properties. The synthesis leverages inter-modular synergy on a tri-modular pore-partitioned platform. New V-MOFs show a broad range of structural features and sorption properties suitable for gas storage and separation applications for C₂H₂/CO₂, C₂H₆/C₂H₄, and C₃H₈/C₃H₆. The c/a ratio of the hexagonal cell, a measure of pore shape, is tunable from 0.612 to 1.258. Other tunable properties include pore size from 5.0 to 10.9 Å and surface area from 820 to 2964 m² g^–1. With C₂H₂/CO₂ selectivity from 3.3 to 11 and high uptake capacity for C₂H₂ from 65.2 to 182 cm³ g^–1 (298K, 1 bar), an efficient separation is confirmed by breakthrough experiments. The near-record high uptake for C₂H₆ (166.8 cm³ g^–1) contributes to the promise for C₂H₆-selective separation of C₂H₆/C₂H₄. The multi-module pore expansion enables transition from C₃H₆-selective to more desirable C₃H₈-selective separation with extraordinarily high C₃H₈ uptake (254.9 cm³ g^–1) and high separation potential (1.25 mmol g^–1) for C₃H₈/C₃H₆ (50:50 v/v) mixture.

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Research Organization:: University of California, Riverside, CA (United States)

Sponsoring Organization:: NSF MRI; USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division (MSE)

Grant/Contract Number:: SC0010596

OSTI ID:: 2478388

Journal Information:: Advanced Materials, Journal Name: Advanced Materials Journal Issue: 30 Vol. 36; ISSN 0935-9648

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Related Subjects

36 MATERIALS SCIENCE
gas separation
metal-organic framework
multi-module
pore space partition
vanadium

Title: Tailorable Multi–Modular Pore–Space–Partitioned Vanadium Metal–Organic Frameworks for Gas Separation

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