Vapor–Phase Synthesis of Electrocatalytic Covalent Organic Frameworks

Mohamed, Syed Ibrahim Gnani Peer; Namvar, Shahriar; Zhang, Tan; Shahbazi, Hessam; Jiang, Zhen; Rappe, Andrew M.; Salehi‐Khojin, Amin; Nejati, Siamak

doi:10.1002/adma.202309302

Title: Vapor–Phase Synthesis of Electrocatalytic Covalent Organic Frameworks

Journal Article · 24 December 2023 · Advanced Materials

DOI: https://doi.org/10.1002/adma.202309302 · OSTI ID:2476638

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University of Nebraska, Lincoln, NE (United States); Univ. of Pennsylvania
University of Illinois at Chicago, IL (United States)
University of Pennsylvania, Philadelphia, PA (United States)
University of Nebraska, Lincoln, NE (United States)

The inability to process many covalent organic frameworks (COFs) as thin films plagues their widespread utilization. Herein, a vapor-phase pathway for the bottom-up synthesis of a class of porphyrin-based COFs is presented. This approach allows integrating electrocatalysts made of metal-ion-containing COFs into the electrodes’ architectures in a single-step synthesis and deposition. By precisely controlling the metal sites at the atomic level, remarkable electrocatalytic performance is achieved, resulting in unprecedentedly high mass activity values. How the choice of metal atoms, i.e., cobalt and copper, can determine the catalytic activities of POR-COFs is demonstrated. The theoretical data proves that the Cu site is highly active for nitrate conversion to ammonia on the synthesized COFs.

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Research Organization:: University of Pennsylvania, Philadelphia, PA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division (CSGB); US National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities (SUF); National Energy Research Scientific Computing Center (NERSC)

Grant/Contract Number:: SC0019281; AC02-05CH11231

OSTI ID:: 2476638

Journal Information:: Advanced Materials, Journal Name: Advanced Materials Journal Issue: 14 Vol. 36; ISSN 0935-9648

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Title: Vapor–Phase Synthesis of Electrocatalytic Covalent Organic Frameworks

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