Laser-engraved defects in TiO2 support: Enhancing reducibility and redox capability of Pt/TiO2 catalyst for reactive and selective hydrogenation

Zhang, Yuan; Kamali, Ali; Zhang, Sheng; Wang, Tong; Hwang, Sooyeon; Ashfaq, Aiysha; Gonzalez-Lopez, Lorelis; Kraus, Harrison; Fu, Jiayi; Zhang, Wenfei; Vlachos, Dionisios G.; Al-Sheikhly, Mohamad I.; Liu, Dongxia

doi:10.1016/j.mcat.2024.114602

Title: Laser-engraved defects in TiO₂ support: Enhancing reducibility and redox capability of Pt/TiO₂ catalyst for reactive and selective hydrogenation

Journal Article · 10 October 2024 · Molecular Catalysis (Online)

DOI: https://doi.org/10.1016/j.mcat.2024.114602 · OSTI ID:2475959

Zhang, Yuan ^[1];

^[2]; Zhang, Sheng ^[3];

^[3];

^[4];

^[1];

^[1]; Fu, Jiayi ^[2];

^[5];

^[2]; Al-Sheikhly, Mohamad I. ^[1]; Liu, Dongxia ^[6]

Univ. of Maryland, College Park, MD (United States)
Univ. of Delaware, Newark, DE (United States)
City Univ. of New York (CUNY), NY (United States)
Brookhaven National Laboratory (BNL), Upton, NY (United States). Center for Functional Nanomaterials (CFN)
Xi'an Jiaotong Univ. (China)
Univ. of Delaware, Newark, DE (United States); Univ. of Maryland, College Park, MD (United States)

Titanium dioxide (TiO₂) has been studied as catalyst or catalyst support in catalysis. Its synthesis or modification approach controls the structural, optical, and electronic properties. Here, in this work, we applied laser engraving to the anatase TiO₂ and studied the consequent changes in its structure and property as well as the properties of TiO₂ supported platinum (i.e., Pt/TiO₂) catalyst. The laser engraving enlarged the particle size, formed rutile phase and created defects (i.e., oxygen vacancy (O_v) and Ti³⁺) in anatase TiO₂. This induced band gap change and enhanced visible light absorption. The defects created by laser engraving are stable and more reducible than those existed in the pristine TiO₂. The defective TiO₂ is structurally stable and has great redox properties. The metal-support interaction in the Pt/defective TiO₂ catalyst is stronger than that of the pristine Pt/TiO₂ catalyst, which enabled higher reactivity and selectivity in hydrogenation of 3-nitrostyrene and furfuryl alcohol. Laser-engraved TiO₂ has been rarely studied for thermal catalysis. This work provides basic understanding of material properties and catalysis application of laser-engraved catalyst supports and catalysts in field of thermal catalysis.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities (SUF)

Grant/Contract Number:: SC0012704; SC0001004

OSTI ID:: 2475959

Report Number(s):: BNL--226313-2024-JAAM

Journal Information:: Molecular Catalysis (Online), Journal Name: Molecular Catalysis (Online) Vol. 569; ISSN 2468-8231

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Related Subjects

25 ENERGY STORAGE
Defect engineering
Hydrogenation
Laser engraving
Metal-support interaction
Oxygen vacancy
Titanium dioxide

Title: Laser-engraved defects in TiO2 support: Enhancing reducibility and redox capability of Pt/TiO2 catalyst for reactive and selective hydrogenation

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References (62)

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Title: Laser-engraved defects in TiO₂ support: Enhancing reducibility and redox capability of Pt/TiO₂ catalyst for reactive and selective hydrogenation