Antiferromagnetic Ordering in A One‐Dimensional Organic Copper Chloride Hybrid Insulator

Islam, Md Sazedul; Comstock, Andrew; Hua, Zhenqi; Thapa, Puja; He, Yufang; Ben‐Akacha, Azza; Liu, He; Manny, Tarannuma Ferdous; Viera, Jarek; Lin, Xinsong; Ouyang, Bin; Xiong, Peng; Sun, Dali; Ma, Biwu

doi:10.1002/anie.202412759

Title: Antiferromagnetic Ordering in A One‐Dimensional Organic Copper Chloride Hybrid Insulator

Journal Article · 20 September 2024 · Angewandte Chemie (International Edition)

DOI: https://doi.org/10.1002/anie.202412759 · OSTI ID:2475889

Islam, Md Sazedul ^[1]; Comstock, Andrew ^[2]; Hua, Zhenqi ^[3]; Thapa, Puja ^[2]; He, Yufang ^[1]; Ben‐Akacha, Azza ^[1]; Liu, He ^[1]; Manny, Tarannuma Ferdous ^[1]; Viera, Jarek ^[1]; Lin, Xinsong ^[1]; Ouyang, Bin ^[1]; Xiong, Peng ^[3]; Sun, Dali ^[2];

^[1]

Department of Chemistry and Biochemistry Florida State University Tallahassee, Florida 32306 United States
Department of Physics North Carolina State University Raleigh, North Carolina 27695 United States
Department of Physics Florida State University Tallahassee, Florida 32306 United States

Abstract Low dimensional (LD) organic metal halide hybrids (OMHHs) have recently emerged as new generation functional materials with exceptional structural and property tunability. Despite the remarkable advances in the development of LD OMHHs, optical properties have been the major functionality extensively investigated for most of LD OMHHs developed to date, while other properties, such as magnetic and electronic properties, remain significantly under‐explored. Here, we report for the first time the characterization of the magnetic and electronic properties of a 1D OMHH, organic‐copper (II) chloride hybrid (C ₈ H ₂₂ N ₂ )Cu ₂ Cl ₆ . Owing to the antiferromagnetic coupling between Cu atoms through chloride bridges in 1D [Cu ₂ Cl ₆ ²⁻ ] _∞ chains, (C ₈ H ₂₂ N ₂ )Cu ₂ Cl ₆ is found to exhibit antiferromagnetic ordering with a Néel temperature of 24 K. The two‐terminal (2T) electrical measurement on a (C ₈ H ₂₂ N ₂ )Cu ₂ Cl ₆ single crystal reveals its insulating nature. This work shows the potential of LD OMHHs as a highly tunable quantum material platform for spintronics.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 2475889

Journal Information:: Angewandte Chemie (International Edition), Journal Name: Angewandte Chemie (International Edition) Journal Issue: 46 Vol. 63; ISSN 1433-7851

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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