The Hard Ferromagnetism in FePS 3 Induced by Non‐Magnetic Molecular Intercalation

Ou, Yunbo; Li, Xiaoyin; Kopaczek, Jan; Davis, Austin; Jackson, Gigi; Sayyad, Mohammed; Liu, Feng; Tongay, Seth Ariel

doi:10.1002/apxr.202400101

Title: The Hard Ferromagnetism in FePS ₃ Induced by Non‐Magnetic Molecular Intercalation

Journal Article · 31 October 2024 · Advanced Physics Research

DOI: https://doi.org/10.1002/apxr.202400101 · OSTI ID:2475874

^[1]; Li, Xiaoyin ^[2];

^[3]; Davis, Austin ^[1]; Jackson, Gigi ^[1]; Sayyad, Mohammed ^[1]; Liu, Feng ^[2];

^[1]

Materials Science and Engineering School for Engineering of Matter Transport and Energy Arizona State University Tempe Arizona 85287 USA
Department of Materials Science and Engineering University of Utah Salt Lake City Utah 84112 USA
Materials Science and Engineering School for Engineering of Matter Transport and Energy Arizona State University Tempe Arizona 85287 USA, Department of Semiconductor Materials Engineering Faculty of Fundamental Problems of Technology Wroclaw University of Science and Technology Wybrzeże Stanisława Wyspiańskiego Wroclaw 50‐370 Poland

Abstract Manipulating the magnetic ground states of 2D magnets is a focal point of recent research efforts. Various methods have demonstrated efficacy in modulating the magnetic properties inherent to van der Waals (vdW) magnetic systems. Herein, the emergence of robust anisotropic ferromagnetism within antiferromagnetic FePS ₃ is unveiled via intercalation with non‐magnetic pyridinium ions. A one‐step ion exchange reaction facilitates the formation of energetically favorable B‐phase and metastable P‐phase. Notably, both B‐ and P‐phases manifest hard ferromagnetic behavior, featuring substantial unsaturated coercive fields (>7 T) and high Curie temperatures (72–87 K). First‐principles calculations elucidate the pivotal role of electron transfer from pyridinium ions to FePS ₃ in engineering magnetic exchange interactions. Calculated effective spin Hamiltonian corroborates the observed hard ferromagnetism in intercalated FePS ₃ . This study offers crucial insights into hard magnetism in intercalated vdW materials, thereby presenting promising avenues for 2D vdW magnet‐based magnetic devices.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: FG02-04ER46148; SC0020653

OSTI ID:: 2475874

Journal Information:: Advanced Physics Research, Journal Name: Advanced Physics Research Journal Issue: 2 Vol. 4; ISSN 2751-1200

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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