Single-Pass Demonstration of Integrated Capture and Catalytic Conversion of CO 2 from Simulated Flue Gas to Methanol in a Water-Lean Carbon Capture Solvent

Barpaga, Dushyant; King, Jaelynne A.; Kothandaraman, Jotheeswari; Lopez, Johnny S.; Moskowitz, Benjamin M.; Hubbard, Michael L.; Zheng, Richard F.; Malhotra, Deepika; Koech, Phillip K.; Zwoster, Andy J.; Dagle, Robert A.; Heldebrant, David J.

doi:10.1021/acsomega.4c06919

Title: Single-Pass Demonstration of Integrated Capture and Catalytic Conversion of CO ₂ from Simulated Flue Gas to Methanol in a Water-Lean Carbon Capture Solvent

Journal Article · 04 November 2024 · ACS Omega

DOI: https://doi.org/10.1021/acsomega.4c06919 · OSTI ID:2475858

^[1]; King, Jaelynne A. ^[1];

^[1]; Lopez, Johnny S. ^[1]; Moskowitz, Benjamin M. ^[1]; Hubbard, Michael L. ^[1]; Zheng, Richard F. ^[1];

^[1]; Koech, Phillip K. ^[1]; Zwoster, Andy J. ^[1];

^[1];

^[1]

Pacific Northest National Laboratory, 902 Battelle Blvd, Richland, Washington 99352, United States

Not Available

View Journal Article

Cite

Export

Save

Sponsoring Organization:: USDOE

OSTI ID:: 2475858

Journal Information:: ACS Omega, Journal Name: ACS Omega Journal Issue: 46 Vol. 9; ISSN 2470-1343

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (67)

Integrated Capture and Conversion of CO₂ to Methanol in a Post‐Combustion Capture Solvent: Heterogeneous Catalysts for Selective CN Bond Cleavage Kothandaraman, Jotheeswari; Lopez, Johnny Saavedra; Jiang, Yuan Advanced Energy Materials, Vol. 12, Issue 46 https://doi.org/10.1002/aenm.202202369	journal	October 2022
Selective Catalytic Synthesis Using the Combination of Carbon Dioxide and Hydrogen: Catalytic Chess at the Interface of Energy and Chemistry Klankermayer, Jürgen; Wesselbaum, Sebastian; Beydoun, Kassem Angewandte Chemie International Edition, Vol. 55, Issue 26 https://doi.org/10.1002/anie.201507458	journal	May 2016
Are Amines the Holy Grail for Facilitating CO ₂ Reduction? Jakobsen, Joakim B.; Rønne, Magnus H.; Daasbjerg, Kim Angewandte Chemie International Edition, Vol. 60, Issue 17 https://doi.org/10.1002/anie.202014255	journal	March 2021
CO 2 Capture and Conversion with a Multifunctional Polyethyleneimine-Tethered Iminophosphine Iridium Catalyst/Adsorbent McNamara, Nicholas D.; Hicks, Jason C. ChemSusChem, Vol. 7, Issue 4 https://doi.org/10.1002/cssc.201301231	journal	March 2014
Aqueous Biphasic Systems for the Synthesis of Formates by Catalytic CO ₂ Hydrogenation: Integrated Reaction and Catalyst Separation for CO ₂ -Scrubbing Solutions Scott, Martin; Blas Molinos, Beatriz; Westhues, Christian ChemSusChem, Vol. 10, Issue 6 https://doi.org/10.1002/cssc.201601814	journal	February 2017
Electrocatalytic Reduction of CO ₂ to Methanol by Iron Tetradentate Phosphine Complex Through Amidation Strategy Bi, Jiaojiao; Hou, Pengfei; Liu, Fang‐Wei ChemSusChem, Vol. 12, Issue 10 https://doi.org/10.1002/cssc.201802929	journal	April 2019
Molecular‐Level Overhaul of γ‐Aminopropyl Aminosilicone/Triethylene Glycol Post‐Combustion CO ₂ ‐Capture Solvents Cantu, David C.; Malhotra, Deepika; Nguyen, Manh‐Thuong ChemSusChem, Vol. 13, Issue 13 https://doi.org/10.1002/cssc.202000724	journal	June 2020
CO ₂ Reduction to Methanol in the Liquid Phase: A Review Xie, Shaoqu; Zhang, Wanli; Lan, Xingying ChemSusChem https://doi.org/10.1002/cssc.202002087	journal	November 2020
Strategies for Integrated Capture and Conversion of CO ₂ from Dilute Flue Gases and the Atmosphere Maina, James W.; Pringle, Jennifer M.; Razal, Joselito M. ChemSusChem, Vol. 14, Issue 8 https://doi.org/10.1002/cssc.202100010	journal	March 2021
Integrated Capture and Conversion of CO ₂ to Methane Using a Water‐lean, Post‐Combustion CO ₂ Capture Solvent Kothandaraman, Jotheeswari; Saavedra Lopez, Johnny; Jiang, Yuan ChemSusChem, Vol. 14, Issue 21 https://doi.org/10.1002/cssc.202101590	journal	October 2021
Carbon Capture and Utilization Update Al-Mamoori, Ahmed; Krishnamurthy, Anirudh; Rownaghi, Ali A. Energy Technology, Vol. 5, Issue 6 https://doi.org/10.1002/ente.201600747	journal	March 2017
The chemistry and catalysis of the water gas shift reaction 1. The kinetics over supported metal catalysts Grenoble, D. Journal of Catalysis, Vol. 67, Issue 1 https://doi.org/10.1016/0021-9517(81)90263-3	journal	January 1981
Advances in carbon capture, utilization and storage Zhang, Zhien; Wang, Tao; Blunt, Martin J. Applied Energy, Vol. 278 https://doi.org/10.1016/j.apenergy.2020.115627	journal	November 2020
Global challenges and strategies for control, conversion and utilization of CO2 for sustainable development involving energy, catalysis, adsorption and chemical processing Song, Chunshan Catalysis Today, Vol. 115, Issue 1-4 https://doi.org/10.1016/j.cattod.2006.02.029	journal	June 2006
A comprehensive review on different approaches for CO2 utilization and conversion pathways Saravanan, A.; Senthil kumar, P.; Vo, Dai-Viet N. Chemical Engineering Science, Vol. 236 https://doi.org/10.1016/j.ces.2021.116515	journal	June 2021
CCUS deployment under the U.S. 45Q tax credit and adaptation by other North American Governments: MARKAL modeling results Victor, Nadejda; Nichols, Christopher Computers & Industrial Engineering, Vol. 169 https://doi.org/10.1016/j.cie.2022.108269	journal	July 2022
Use of monoethanolamine (MEA) for CO 2 capture in a global scenario: Consequences and alternatives Luis, Patricia Desalination, Vol. 380 https://doi.org/10.1016/j.desal.2015.08.004	journal	February 2016
Catalytic CO2 conversion to C1 value-added products: Review on latest catalytic and process developments Yusuf, Noor; Almomani, Fares; Qiblawey, Hazim Fuel, Vol. 345 https://doi.org/10.1016/j.fuel.2023.128178	journal	August 2023
Both sites must turn over in tandem catalysis: Lessons from one-pot CO2 capture and hydrogenation Wilson, Elizabeth A. K.; Eady, Shawn C.; Silbaugh, Trent Journal of Catalysis, Vol. 404 https://doi.org/10.1016/j.jcat.2021.04.013	journal	December 2021
Chemical transformations of captured CO2 into cyclic and polymeric carbonates Kothandaraman, Jotheeswari; Zhang, Jun; Glezakou, Vassiliki-Alexandra Journal of CO2 Utilization, Vol. 32 https://doi.org/10.1016/j.jcou.2019.04.020	journal	July 2019
A Process for Capturing CO2 from the Atmosphere Keith, David W.; Holmes, Geoffrey; St. Angelo, David Joule, Vol. 2, Issue 8 https://doi.org/10.1016/j.joule.2018.05.006	journal	August 2018
Tandem and Hybrid Processes for Carbon Dioxide Utilization Overa, Sean; Feric, Tony G.; Park, Ah-Hyung Alissa Joule, Vol. 5, Issue 1 https://doi.org/10.1016/j.joule.2020.12.004	journal	January 2021
Reactive CO2 capture: A path forward for process integration in carbon management Freyman, Megan C.; Huang, Zhe; Ravikumar, Dwarakanath Joule, Vol. 7, Issue 4 https://doi.org/10.1016/j.joule.2023.03.013	journal	April 2023
Current status and advances in membrane technology for carbon capture Hou, Rujing; Fong, Celesta; Freeman, Benny D. Separation and Purification Technology, Vol. 300 https://doi.org/10.1016/j.seppur.2022.121863	journal	November 2022
Integrated CO ₂ Capture and Conversion to Formate and Methanol: Connecting Two Threads Kar, Sayan; Goeppert, Alain; Prakash, G. K. Surya Accounts of Chemical Research, Vol. 52, Issue 10 https://doi.org/10.1021/acs.accounts.9b00324	journal	September 2019
Water-Lean Solvents for Post-Combustion CO ₂ Capture: Fundamentals, Uncertainties, Opportunities, and Outlook Heldebrant, David J.; Koech, Phillip K.; Glezakou, Vassiliki-Alexandra Chemical Reviews, Vol. 117, Issue 14 https://doi.org/10.1021/acs.chemrev.6b00768	journal	May 2017
The Role of Carbon Capture and Utilization, Carbon Capture and Storage, and Biomass to Enable a Net-Zero-CO ₂ Emissions Chemical Industry Gabrielli, Paolo; Gazzani, Matteo; Mazzotti, Marco Industrial & Engineering Chemistry Research, Vol. 59, Issue 15 https://doi.org/10.1021/acs.iecr.9b06579	journal	March 2020
Recycling Carbon Dioxide through Catalytic Hydrogenation: Recent Key Developments and Perspectives Ra, Eun Cheol; Kim, Kwang Young; Kim, Eun Hyup ACS Catalysis, Vol. 10, Issue 19 https://doi.org/10.1021/acscatal.0c02930	journal	August 2020
Combining Low-Pressure CO ₂ Capture and Hydrogenation To Form Methanol Khusnutdinova, Julia R.; Garg, Jai Anand; Milstein, David ACS Catalysis, Vol. 5, Issue 4 https://doi.org/10.1021/acscatal.5b00194	journal	March 2015
Manganese-Catalyzed Sequential Hydrogenation of CO ₂ to Methanol via Formamide Kar, Sayan; Goeppert, Alain; Kothandaraman, Jotheeswari ACS Catalysis, Vol. 7, Issue 9 https://doi.org/10.1021/acscatal.7b02066	journal	August 2017
Integrating CO ₂ Electrolysis into the Gas-to-Liquids–Power-to-Liquids Process van Bavel, Svetlana; Verma, Sumit; Negro, Emanuela ACS Energy Letters, Vol. 5, Issue 8 https://doi.org/10.1021/acsenergylett.0c01418	journal	July 2020
Reduction of CO ₂ to Chemicals and Fuels: A Solution to Global Warming and Energy Crisis Peter, Sebastian C. ACS Energy Letters, Vol. 3, Issue 7 https://doi.org/10.1021/acsenergylett.8b00878	journal	June 2018
Evaluation of a Third Generation Single-Component Water-Lean Diamine Solvent for Post-Combustion CO₂ Capture Barpaga, Dushyant; Jiang, Yuan; Zheng, Richard F. ACS Sustainable Chemistry & Engineering, Vol. 10, Issue 14 https://doi.org/10.1021/acssuschemeng.1c08401	journal	March 2022
Transformation of Carbon Dioxide Sakakura, Toshiyasu; Choi, Jun-Chul; Yasuda, Hiroyuki Chemical Reviews, Vol. 107, Issue 6 https://doi.org/10.1021/cr068357u	journal	June 2007
Methanol from CO ₂ by Organo-Cocatalysis: CO ₂ Capture and Hydrogenation in One Process Step Reller, Christian; Pöge, Matthias; Lißner, Andreas Environmental Science & Technology, Vol. 48, Issue 24 https://doi.org/10.1021/es503914d	journal	November 2014
Homogeneous Hydrogenation of CO ₂ to Methyl Formate Utilizing Switchable Ionic Liquids Yadav, Mahendra; Linehan, John C.; Karkamkar, Abhijeet J. Inorganic Chemistry, Vol. 53, Issue 18 https://doi.org/10.1021/ic501378w	journal	August 2014
Post-Combustion CO₂ Capture Using Solid Sorbents: A Review Samanta, Arunkumar; Zhao, An; Shimizu, George K. H. Industrial & Engineering Chemistry Research, Vol. 51, Issue 4, p. 1438-1463 https://doi.org/10.1021/ie200686q	journal	September 2011
Anthropogenic Chemical Carbon Cycle for a Sustainable Future Olah, George A.; Prakash, G. K. Surya; Goeppert, Alain Journal of the American Chemical Society, Vol. 133, Issue 33 https://doi.org/10.1021/ja202642y	journal	August 2011
Tandem Amine and Ruthenium-Catalyzed Hydrogenation of CO ₂ to Methanol Rezayee, Nomaan M.; Huff, Chelsea A.; Sanford, Melanie S. Journal of the American Chemical Society, Vol. 137, Issue 3 https://doi.org/10.1021/ja511329m	journal	January 2015
Conversion of CO ₂ from Air into Methanol Using a Polyamine and a Homogeneous Ruthenium Catalyst Kothandaraman, Jotheeswari; Goeppert, Alain; Czaun, Miklos Journal of the American Chemical Society, Vol. 138, Issue 3 https://doi.org/10.1021/jacs.5b12354	journal	January 2016
Homogeneous Carbon Capture and Catalytic Hydrogenation: Toward a Chemical Hydrogen Battery System Wei, Duo; Sang, Rui; Moazezbarabadi, Ayeshe JACS Au, Vol. 2, Issue 5 https://doi.org/10.1021/jacsau.1c00489	journal	April 2022
Chemical Recycling of Carbon Dioxide to Methanol and Dimethyl Ether: From Greenhouse Gas to Renewable, Environmentally Carbon Neutral Fuels and Synthetic Hydrocarbons Olah, George A.; Goeppert, Alain; Prakash, G. K. Surya The Journal of Organic Chemistry, Vol. 74, Issue 2, p. 487-498 https://doi.org/10.1021/jo801260f	journal	January 2009
CO ₂ Capture by TiO ₂ Anatase Surfaces: A Combined DFT and FTIR Study Mino, Lorenzo; Spoto, Giuseppe; Ferrari, Anna Maria The Journal of Physical Chemistry C, Vol. 118, Issue 43 https://doi.org/10.1021/jp507443k	journal	October 2014
Mechanism of the Water Gas Shift Reaction on Pt: First Principles, Experiments, and Microkinetic Modeling Grabow, Lars C.; Gokhale, Amit A.; Evans, Steven T. The Journal of Physical Chemistry C, Vol. 112, Issue 12 https://doi.org/10.1021/jp7099702	journal	March 2008
Climate change is hitting the planet faster than scientists originally thought Tollefson, Jeff Nature https://doi.org/10.1038/d41586-022-00585-7	journal	February 2022
The race to upcycle CO2 into fuels, concrete and more Peplow, Mark Nature, Vol. 603, Issue 7903 https://doi.org/10.1038/d41586-022-00807-y	journal	March 2022
Using carbon dioxide as a building block in organic synthesis Liu, Qiang; Wu, Lipeng; Jackstell, Ralf Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms6933	journal	January 2015
The technological and economic prospects for CO2 utilization and removal Hepburn, Cameron; Adlen, Ella; Beddington, John Nature, Vol. 575, Issue 7781 https://doi.org/10.1038/s41586-019-1681-6	journal	November 2019
Recent advances in solid sorbents for CO ₂ capture and new development trends Wang, Junya; Huang, Liang; Yang, Ruoyan Energy Environ. Sci., Vol. 7, Issue 11 https://doi.org/10.1039/C4EE01647E	journal	January 2014
CO ₂ capture by amines in aqueous media and its subsequent conversion to formate with reusable ruthenium and iron catalysts Kothandaraman, Jotheeswari; Goeppert, Alain; Czaun, Miklos Green Chemistry, Vol. 18, Issue 21 https://doi.org/10.1039/C6GC01165A	journal	January 2016
The steps of activating a prospective CO ₂ hydrogenation catalyst with combined CO ₂ capture and reduction Lao, D. B.; Galan, B. R.; Linehan, J. C. Green Chemistry, Vol. 18, Issue 18 https://doi.org/10.1039/C6GC01800A	journal	January 2016
Life cycle assessment of CO ₂ -based C1-chemicals Sternberg, André; Jens, Christian M.; Bardow, André Green Chemistry, Vol. 19, Issue 9 https://doi.org/10.1039/C6GC02852G	journal	January 2017
Carbon capture and storage (CCS): the way forward Bui, Mai; Adjiman, Claire S.; Bardow, André Energy & Environmental Science, Vol. 11, Issue 5 https://doi.org/10.1039/C7EE02342A	journal	January 2018
Condensed-phase low temperature heterogeneous hydrogenation of CO ₂ to methanol Kothandaraman, Jotheeswari; Dagle, Robert A.; Dagle, Vanessa Labarbier Catalysis Science & Technology, Vol. 8, Issue 19 https://doi.org/10.1039/C8CY00997J	journal	January 2018
Renewable energy storage via efficient reversible hydrogenation of piperidine captured CO 2 Lu, Mi; Zhang, Jianghao; Yao, Yao Green Chemistry, Vol. 20, Issue 18 https://doi.org/10.1039/C8GC00954F	journal	January 2018
A call to (green) arms: a rallying cry for green chemistry and engineering for CO ₂ capture, utilisation and storage Leclaire, Julien; Heldebrant, David J. Green Chemistry, Vol. 20, Issue 22 https://doi.org/10.1039/C8GC01962B	journal	January 2018
Methylformate from CO 2 : an integrated process combining catalytic hydrogenation and reactive distillation Scott, Martin; Westhues, Christian G.; Kaiser, Teresa Green Chemistry, Vol. 21, Issue 23 https://doi.org/10.1039/C9GC03006A	journal	January 2019
Towards environmentally benign capture and conversion: heterogeneous metal catalyzed CO ₂ hydrogenation in CO ₂ capture solvents Kothandaraman, Jotheeswari; Heldebrant, David J. Green Chemistry, Vol. 22, Issue 3 https://doi.org/10.1039/C9GC03449H	journal	January 2020
A single-component water-lean post-combustion CO ₂ capture solvent with exceptionally low operational heat and total costs of capture – comprehensive experimental and theoretical evaluation Zheng, Richard F.; Barpaga, Dushyant; Mathias, Paul M. Energy & Environmental Science, Vol. 13, Issue 11 https://doi.org/10.1039/D0EE02585B	journal	January 2020
Catalytic hydrogenation of CO₂ from air via porous silica-supported Au nanoparticles in aqueous solution Ni, Siting; Zhu, Jun; Roy, Ranjan Green Chemistry, Vol. 23, Issue 10 https://doi.org/10.1039/D0GC04303F	journal	January 2021
Catalytic coproduction of methanol and glycol in one pot from epoxide, CO ₂ , and H ₂ Kothandaraman, Jotheeswari; Heldebrant, David J. RSC Advances, Vol. 10, Issue 69 https://doi.org/10.1039/D0RA09459E	journal	January 2020
An amino acid based system for CO ₂ capture and catalytic utilization to produce formates Wei, Duo; Junge, Henrik; Beller, Matthias Chemical Science, Vol. 12, Issue 17 https://doi.org/10.1039/D1SC00467K	journal	January 2021
Next steps for solvent-based CO₂ capture; integration of capture, conversion, and mineralisation Heldebrant, David J.; Kothandaraman, Jotheeswari; Dowell, Niall Mac Chemical Science, Vol. 13, Issue 22 https://doi.org/10.1039/D2SC00220E	journal	January 2022
Separation of CO ₂ from Flue Gas: A Review Aaron, Douglas; Tsouris, Costas Separation Science and Technology, Vol. 40, Issue 1-3 https://doi.org/10.1081/SS-200042244	journal	January 2005
Amine Scrubbing for CO2 Capture Rochelle, G. T. Science, Vol. 325, Issue 5948 https://doi.org/10.1126/science.1176731	journal	September 2009
Love at second sight for CO2 and H2 in organic synthesis Klankermayer, J.; Leitner, W. Science, Vol. 350, Issue 6261 https://doi.org/10.1126/science.aac7997	journal	November 2015
Cost and Performance Baseline for Fossil Energy Plants: Bituminous Coal and Natural Gas to Electricity James, Robert; Fout, Timothy; Shultz, Travis SSRN Electronic Journal https://doi.org/10.2139/ssrn.3365992	journal	January 2019

Similar Records

Integrated Capture and Conversion of CO₂ to Methane Using a Water-lean, Post-Combustion CO₂ Capture Solvent

Journal Article · 2021 · ChemSusChem · OSTI ID:1829683

Kothandaraman, Jotheeswari; Saavedra Lopez, Johnny; Jiang, Yuan; +4 more

Integrated capture and conversion of CO₂ to methanol or methanol and glycol

Patent · 2021 · OSTI ID:1805669

Kothandaraman, Jotheeswari; Heldebrant, David J.; Jiang, Yuan; +1 more

Aerosol emissions from water-lean solvents for post-combustion CO₂ capture

Journal Article · 2021 · International Journal of Greenhouse Gas Control · OSTI ID:1849288

Gupta, Vijay; Mobley, Paul; Tanthana, Jak; +7 more

Title: Single-Pass Demonstration of Integrated Capture and Catalytic Conversion of CO 2 from Simulated Flue Gas to Methanol in a Water-Lean Carbon Capture Solvent

Citation Formats

References (67)

Similar Records

Related Subjects

Title: Single-Pass Demonstration of Integrated Capture and Catalytic Conversion of CO ₂ from Simulated Flue Gas to Methanol in a Water-Lean Carbon Capture Solvent