Flexible Soft X-Ray Image Sensors based on Metal Halide Perovskites With High Quantum Efficiency

Tan, Pengju; Liu, Tianyu; Yang, Yuqian; Chen, Yuangan; Guan, Yong; Li, Zidu; Yu, Shunjie; Yang, Xunyong; Xiang, Xueqiang; Zhao, Xiaolong; Li, Yu; Ding, Honghe; Wu, Xuefei; Fink, Zachary; Gao, Shuang; Hou, Xiaohu; Jiao, Xuechen; Zhu, Junfa; Fan, Fengjia; Yang, Shangfeng; Russell, Thomas P.; Liu, Xiaosong; Hu, Qin; Long, Shibing

doi:10.1002/adma.202407244

Title: Flexible Soft X-Ray Image Sensors based on Metal Halide Perovskites With High Quantum Efficiency

Journal Article · 03 October 2024 · Advanced Materials

DOI: https://doi.org/10.1002/adma.202407244 · OSTI ID:2475775

Tan, Pengju ^[1]; Liu, Tianyu ^[1]; Yang, Yuqian ^[1]; Chen, Yuangan ^[1]; Guan, Yong ^[1]; Li, Zidu ^[1]; Yu, Shunjie ^[1]; Yang, Xunyong ^[1]; Xiang, Xueqiang ^[1]; Zhao, Xiaolong ^[1];

^[1]; Ding, Honghe ^[1]; Wu, Xuefei ^[2]; Fink, Zachary ^[3]; Gao, Shuang ^[1]; Hou, Xiaohu ^[1]; Jiao, Xuechen ^[1]; Zhu, Junfa ^[1]; Fan, Fengjia ^[1]; Yang, Shangfeng ^[1] more »

Univ. of Science and Technology of China, Hefei (China)
Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
Univ. of Massachusetts, Amherst, MA (United States); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States); Univ. of Massachusetts, Amherst, MA (United States)

Soft X-ray imaging is a powerful tool to explore the structure of cells, probe material with nanometer resolution, and investigate the energetic phenomena in the universe. Conventional soft X-ray image sensors are by and large Si-based charge coupled devices that suffer from low frame rates, complex fabrication processes, mechanical inflexibility, and required cooling below -60 °C. Here, a soft X-ray photodiode is reported based on low-cost metal halide perovskite with comparable performance to commercial Si-based device. Nanothrough network electrode minimized the optical loss due to the shadowing of insensitive layers, while a multidimensional perovskite heterojunction is generated to reduce the photo-generated carrier loss. Further, this strategy promoted a record quantum efficiency of 8 × 10³% without cooling, several orders of magnitude greater than the previously achieved. Flexible and curved soft X-ray imaging arrays are fabricated based on this high-performance device structure, demonstrating stable soft X-ray response and sharp imaging capabilities. This work highlights the low-cost and efficient perovskite photodiode as a strong candidate for the next-generation soft X-ray image sensors.

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Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)

Sponsoring Organization:: National Natural Science Foundation of China (NSFC); USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 2475775

Journal Information:: Advanced Materials, Journal Name: Advanced Materials Journal Issue: 48 Vol. 36; ISSN 0935-9648

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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36 MATERIALS SCIENCE
X-ray detector
flexible substrate
image array
metal halide perovskite
soft X-ray

Title: Flexible Soft X-Ray Image Sensors based on Metal Halide Perovskites With High Quantum Efficiency

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