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Title: A Carborane-Derived Proton-Coupled Electron Transfer Reagent

Journal Article · · Journal of the American Chemical Society
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Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
SC0019136
OSTI ID:
2475199
Journal Information:
Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 44 Vol. 146; ISSN 0002-7863
Publisher:
American Chemical SocietyCopyright Statement
Country of Publication:
United States
Language:
English

References (42)

Crystal Structures of the Carborane Dianions [1,4‐(PhCB10H10C)2C6H4]2− and [1,4‐(PhCB10H10C)2C6F4]2− and the Stabilizing Role of the para‐Phenylene Unit on 2 n+3 Skeletal Electron Clusters journal February 2014
Outer-Sphere 2 e − /2 H + Transfer Reactions of Ruthenium(II)-Amine and Ruthenium(IV)-Amido Complexes journal February 2017
Changing the Reactivity of Zero‐ and Mono‐Valent Germanium with a Redox Non‐Innocent Bis(silylenyl)carborane Ligand journal June 2021
Determination of the C4H Bond Dissociation Energies of NADH Models and Their Radical Cations in Acetonitrile journal February 2003
Synthesis and Structure of an o‐Carboranyl‐Substituted Three‐Coordinate Borane Radical Anion journal May 2021
On the Basicity of Organic Bases in Different Media: On the Basicity of Organic Bases in Different Media journal September 2019
Anion radicals of the barene series
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Structural, spectroscopic, electrochemical and computational studies of C,C′-diaryl-ortho-carboranes, 1-(4-XC6H4)-2-Ph-1,2-C2B10H10 (X = H, F, OMe, NMe2, NH2, OH and O−) journal November 2008
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Photochemical and Electrochemical Applications of Proton-Coupled Electron Transfer in Organic Synthesis journal November 2021
Free Energies of Proton-Coupled Electron Transfer Reagents and Their Applications journal December 2021
Electrochemistry and Photoluminescence of Icosahedral Carboranes, Boranes, Metallacarboranes, and Their Derivatives journal November 2016
Electrocatalytic Ketyl-Olefin Cyclization at a Favorable Applied Bias Enabled by a Concerted Proton–Electron Transfer Mediator journal April 2022
Carboxamidate Ligand Noninnocence in Proton Coupled Electron Transfer journal March 2019
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Strikingly Long C···C Distances in 1,2-Disubstitutedortho-Carboranes and Their Dianions journal September 2005
Main Group Redox Catalysis: Reversible P III /P V Redox Cycling at a Phosphorus Platform journal July 2012
Proton-Coupled Electron Transfer in Azobenzene/Hydrazobenzene Couples with Pendant Acid–Base Functions. Hydrogen-Bonding and Structural Effects journal June 2014
Proton-Coupled Electron Transfer Guidelines, Fair and Square journal January 2021
Generating Potent C–H PCET Donors: Ligand-Induced Fe-to-Ring Proton Migration from a Cp*Fe III –H Complex Demonstrates a Promising Strategy journal October 2020
Electrocatalytic Reduction of C–C π-Bonds via a Cobaltocene-Derived Concerted Proton–Electron Transfer Mediator: Fumarate Hydrogenation as a Model Study journal June 2021
Use of a PCET Mediator Enables a Ni-HER Electrocatalyst to Act as a Hydride Delivery Agent journal October 2022
Full Electron Delocalization across the Cluster in 1,12-bisBMes2-p-carborane Radical Anion journal June 2024
Cp* Noninnocence Leads to a Remarkably Weak C–H Bond via Metallocene Protonation journal February 2019
Bi(I)-Catalyzed Transfer-Hydrogenation with Ammonia-Borane journal February 2019
Establishing the Hydride Donor Abilities of Main Group Hydrides journal May 2015
Cobalt-electrocatalytic HAT for functionalization of unsaturated C–C bonds journal May 2022
Tandem electrocatalytic N2 fixation via proton-coupled electron transfer journal August 2022
Exo-π-bonding to an ortho-carborane hypercarbon atom: systematic icosahedral cage distortions reflected in the structures of the fluoro-, hydroxy- and amino-carboranes, 1-X-2-Ph-1,2-C2B10H10 (X = F, OH or NH2) and related anions journal January 2004
Strategies for switching the mechanism of proton-coupled electron transfer reactions illustrated by mechanistic zone diagrams journal January 2022
Carborane radical anions: spectroscopic and electronic properties of a carborane radical anion with a 2n + 3 skeletal electron count journal January 2007
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Advancing electrocatalytic nitrogen fixation: insights from molecular systems journal January 2023
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A molecular mediator for reductive concerted proton-electron transfers via electrocatalysis journal August 2020
Electron Transfer in Proteins journal June 1996
Novel Method for the Preparation of Triethylsilyl Peroxides from Olefins by the Reaction with Molecular Oxygen and Triethylsilane Catalyzed by Bis(1,3-diketonato)cobalt(II) journal April 1989

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