Porous Liquids: Versatile Fusion of Porosity and Fluidity

Ganesan, Arvind; Dai, Sheng

doi:10.1021/acs.chemmater.4c02399

Title: Porous Liquids: Versatile Fusion of Porosity and Fluidity

Journal Article · 06 October 2024 · Chemistry of Materials

DOI: https://doi.org/10.1021/acs.chemmater.4c02399 · OSTI ID:2474763

^[1];

^[2]

Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)

Porous liquids and fluids with permanent porosity have been explored over the past decade as transformative functional materials for several sustainable chemical processes. This perspective tracks the evolution of porous liquids and summarizes recent advances in the development of porous liquids for several applications, such as sorptive separations, catalysis, etc. Finally, the latter section discusses the prospects of porous liquids in several novel applications (bio applications, gas storage, heat insulation) and machine learning guided pathways for task-specific design and synthesis of porous liquids.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 2474763

Journal Information:: Chemistry of Materials, Journal Name: Chemistry of Materials Journal Issue: 20 Vol. 36; ISSN 0897-4756

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

References (18)

Revolutionizing Porous Liquids: Stabilization and Structural Engineering Achieved by a Surface Deposition Strategy Qiu, Liqi; Peng, Honggen; Yang, Zhenzhen Advanced Materials, Vol. 35, Issue 32 https://doi.org/10.1002/adma.202302525	journal	June 2023
Liquids with High Compressibility Lai, Beibei; Liu, Siyuan; Cahir, John Advanced Materials, Vol. 35, Issue 44 https://doi.org/10.1002/adma.202306521	journal	September 2023
Porous Liquids: A Promising Class of Media for Gas Separation Zhang, Jinshui; Chai, Song-Hai; Qiao, Zhen-An Angewandte Chemie International Edition, Vol. 54, Issue 3 https://doi.org/10.1002/anie.201409420	journal	November 2014
Porous Ionic Liquids or Liquid Metal-Organic Frameworks? Costa Gomes, Margarida; Pison, Laure; Červinka, Ctirad Angewandte Chemie International Edition, Vol. 57, Issue 37 https://doi.org/10.1002/anie.201805495	journal	August 2018
Rational Design of Porous Ionic Liquids for Coupling Natural Gas Purification with Waste Gas Conversion Ning, Hailong; Shi, Mingzhen; Yang, Qian Angewandte Chemie International Edition, Vol. 62, Issue 46 https://doi.org/10.1002/anie.202310741	journal	October 2023
Porous Liquids O'Reilly, Niamh; Giri, Nicola; James, Stuart L. Chemistry - A European Journal, Vol. 13, Issue 11 https://doi.org/10.1002/chem.200700090	journal	April 2007
Composite Porous Liquid for Recyclable Sequestration, Storage and In Situ Catalytic Conversion of Carbon Dioxide at Room Temperature Bhattacharjee, Archita; Kumar, Raj; Sharma, Kamendra P. ChemSusChem, Vol. 14, Issue 16 https://doi.org/10.1002/cssc.202100931	journal	July 2021
A bifunctional zeolitic porous liquid with incompatible Lewis pairs for antagonistic cascade catalysis Chen, Hao; Yang, Zhenzhen; Peng, Honggen Chem, Vol. 7, Issue 12 https://doi.org/10.1016/j.chempr.2021.08.022	journal	December 2021
CO₂ Separation Performance of Zeolitic Imidazolate Framework-8 Porous Slurry in a Pilot-Scale Packed Tower Li, Hai; Liu, Bei; Yang, Mingke Industrial & Engineering Chemistry Research, Vol. 59, Issue 13 https://doi.org/10.1021/acs.iecr.9b06897	journal	March 2020
Porous Liquids: Computational Design for Targeted Gas Adsorption Rimsza, Jessica M.; Nenoff, Tina M. ACS Applied Materials & Interfaces, Vol. 14, Issue 16 https://doi.org/10.1021/acsami.2c03108	journal	April 2022
Porous Ionic Liquids Go Green Avila, Jocasta; Corsini, Chiara; Correa, Cintia M. ACS Nano, Vol. 17, Issue 20 https://doi.org/10.1021/acsnano.3c06343	journal	October 2023
Charge Shielding-Oriented Design of Zinc-Based Nanoparticle Liquids for Controlled Nanofabrication Tao, Peipei; Wang, Qianqian; Vockenhuber, Michaela Journal of the American Chemical Society, Vol. 145, Issue 43 https://doi.org/10.1021/jacs.3c07595	journal	October 2023
Liquids with permanent porosity Giri, Nicola; Del Pópolo, Mario G.; Melaugh, Gavin Nature, Vol. 527, Issue 7577 https://doi.org/10.1038/nature16072	journal	November 2015
Liquid metal–organic frameworks Gaillac, Romain; Pullumbi, Pluton; Beyer, Kevin A. Nature Materials, Vol. 16, Issue 11 https://doi.org/10.1038/nmat4998	journal	October 2017
Breathing porous liquids based on responsive metal-organic framework particles Koutsianos, Athanasios; Pallach, Roman; Frentzel-Beyme, Louis Nature Communications, Vol. 14, Issue 1 https://doi.org/10.1038/s41467-023-39887-3	journal	July 2023
Coordination cages as permanently porous ionic liquids Ma, Lillian; Haynes, Cally J. E.; Grommet, Angela B. Nature Chemistry, Vol. 12, Issue 3 https://doi.org/10.1038/s41557-020-0419-2	journal	February 2020
The changing state of porous materials Bennett, Thomas D.; Coudert, François-Xavier; James, Stuart L. Nature Materials, Vol. 20, Issue 9 https://doi.org/10.1038/s41563-021-00957-w	journal	April 2021
Microporous water with high gas solubilities Erdosy, Daniel P.; Wenny, Malia B.; Cho, Joy Nature, Vol. 608, Issue 7924 https://doi.org/10.1038/s41586-022-05029-w	journal	August 2022

Similar Records

Transforming Porous Organic Cages into Porous Ionic Liquids via a Supramolecular Complexation Strategy

Journal Article · 2019 · Angewandte Chemie (International Edition) · OSTI ID:1761669

Jie, Kecheng; Onishi, Nicole; Schott, Jennifer A.; +4 more

Transforming Porous Organic Cages into Porous Ionic Liquids via a Supramolecular Complexation Strategy

Journal Article · 2020 · Angewandte Chemie · OSTI ID:1581025

Jie, Kecheng; Onishi, Nicole; Schott, Jennifer A.; +4 more

Electrostatic-Assisted Liquefaction of Porous Carbons

Journal Article · 2017 · Angewandte Chemie (International Edition) · OSTI ID:1427644

Li, Peipei; Schott, Jennifer A.; Zhang, Jinshui; +9 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
liquids
materials
metal organic frameworks
porosity
solvents

Title: Porous Liquids: Versatile Fusion of Porosity and Fluidity

Citation Formats

References (18)

Similar Records

Related Subjects