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Title: Size Effect of Negative Capacitance State and Subthreshold Swing in Van der Waals Ferrielectric Field‐Effect Transistors

Journal Article · · Advanced Electronic Materials
ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [3];  [4]; ORCiD logo [5]
  1. Institute of Physics National Academy of Sciences of Ukraine Pr. Nauky 46 Kyiv 03028 Ukraine
  2. Frantsevich Institute for Problems in Materials Science National Academy of Sciences of Ukraine Str. Omeliana Pritsaka 3 Kyiv 03142 Ukraine
  3. Institute of Solid State Physics and Chemistry Uzhhorod University Uzhhorod 88000 Ukraine
  4. Department of Materials Science and Engineering University of Tennessee Knoxville TN 37996 USA
  5. Taras Shevchenko National University of Kyiv Faculty of Radiophysics Electronics and Computer Systems Pr. Akademika Hlushkova 4g Kyiv 03022 Ukraine, V. Lashkariov Institute of Semiconductor Physics National Academy of Sciences of Ukraine Pr. Nauky 41 Kyiv 03028 Ukraine

Abstract Analytical calculations corroborated by the finite element modeling show that thin films of Van der Waals ferrielectrics covered by a 2D‐semiconductor are promising candidates for the controllable reduction of the dielectric layer capacitance due to the negative capacitance (NC) effect emerging in the thin films. The NC state is conditioned by energy‐degenerated poly‐domain states of the ferrielectric polarization induced in the films under incomplete screening conditions in the presence of a dielectric layer. Calculations performed for the FET‐type heterostructure “ferrielectric CuInP 2 S 6 film—2D‐MoS 2 single‐layer—SiO 2 dielectric layer” reveal the pronounced size effect of the multilayer capacitance. Derived analytical expressions for the electric polarization and multilayer capacitance allow to predict the thickness range of the dielectric layer and ferrielectric film for which the NC effect is the most pronounced in various Van der Waals ferrielectrics, and the corresponding subthreshold swing becomes much less than the Boltzmann's limit. Obtained results can be useful for the size and temperature control of the NC effect in the steep‐slope ferrielectric FETs.

Sponsoring Organization:
USDOE
Grant/Contract Number:
NONE; SC0020145; SC0021118
OSTI ID:
2472967
Journal Information:
Advanced Electronic Materials, Journal Name: Advanced Electronic Materials Journal Issue: 4 Vol. 11; ISSN 2199-160X
Publisher:
Wiley Blackwell (John Wiley & Sons)Copyright Statement
Country of Publication:
United States
Language:
English

References (49)

Modeling of Negative Capacitance in Ferroelectric Thin Films journal June 2019
Ferroelectric Negative Capacitance Field Effect Transistor journal August 2018
Steep Slope Field Effect Transistors Based on 2D Materials journal May 2024
The Concept of Negative Capacitance in Ionically Conductive Van der Waals Ferroelectrics journal September 2020
Domains in Ferroic Crystals and Thin Films book January 2010
Tuning the polar states of ferroelectric films via surface charges and flexoelectricity journal September 2017
Bending-induced isostructural transitions in ultrathin layers of van der Waals ferrielectrics journal January 2024
FerroX: A GPU-accelerated, 3D phase-field simulation framework for modeling ferroelectric devices journal September 2023
Strain tuning on Van der Waals negative capacitance transistors journal July 2024
Large-Scale Domain Engineering in Two-Dimensional Ferroelectric CuInP2S6 via Giant Flexoelectric Effect journal April 2022
Weak Dependence of Voltage Amplification in a Semiconductor Channel on Strain State and Thickness of a Multidomain Ferroelectric in a Bilayer Gate journal November 2023
Negative Capacitance for Stabilizing the Logic State in a Tunnel Field-Effect Transistor journal April 2024
Ferroelectrics-Integrated Two-Dimensional Devices toward Next-Generation Electronics journal September 2022
Negative capacitance in multidomain ferroelectric superlattices journal June 2016
Negative capacitance in a ferroelectric capacitor journal December 2014
Van der Waals negative capacitance transistors journal July 2019
Piezoelectric domain walls in van der Waals antiferroelectric CuInP2Se6 journal July 2020
The ferroelectric field-effect transistor with negative capacitance journal March 2022
Towards two-dimensional van der Waals ferroelectrics journal January 2023
Spatially resolved steady-state negative capacitance journal January 2019
On the stabilization of ferroelectric negative capacitance in nanoscale devices journal January 2018
Ferroelectric thin film properties—Depolarization field and renormalization of a “bulk” free energy coefficients journal January 2003
Surface effect on domain wall width in ferroelectrics journal October 2009
Identification of passive layer in ferroelectric thin films from their switching parameters journal August 1995
Experimental evidence of ferroelectric negative capacitance in nanoscale heterostructures journal September 2011
Hysteretic phenomena in GFET: Comprehensive theory and experiment journal July 2017
Phonon Spectra and Phase Transitions in CuInP 2 (Se x S 1 − x ) 6 Ferroelectrics journal January 2003
Piezoelectric and Ultrasonic Studies of Mixed CuInP 2 (S X Se 1 - X ) 6 Layered Crystals journal June 2007
Linear and Nonlinear Elastic Properties of CuInP 2 S 6 Layered Crystals Under Polarization Reversal journal October 2009
Non-linear dielectric response of layered CuInP 2 S 6 and Cu 0.9 Ag 0.1 InP 2 S 6 crystals journal December 2020
Dielectric and ultrasonic investigation of phase transition in cuinp 2 s 6 crystals journal April 2004
Influence of chemical strains on the electrocaloric response, polarization morphology, tetragonality, and negative-capacitance effect of ferroelectric core-shell nanorods and nanowires journal May 2024
Ferri-ionic coupling in CuInP2S6 nanoflakes: Polarization states and controllable negative capacitance journal September 2024
p − n Junction Dynamics Induced in a Graphene Channel by Ferroelectric-Domain Motion in the Substrate journal August 2017
Phenomenological description of bright domain walls in ferroelectric-antiferroelectric layered chalcogenides journal November 2020
Stress-induced phase transitions in nanoscale Cu In P 2 S 6 journal August 2021
Observability of negative capacitance of a ferroelectric film: Theoretical predictions journal May 2022
Anomalous polarization reversal in strained thin films of CuInP2S6 journal August 2023
Ferrielectric ordering in lamellar CuInP 2 S 6 journal November 1997
Very large dielectric response of thin ferroelectric films with the dead layers journal March 2001
Phase diagram and domain splitting in thin ferroelectric films with incommensurate phase journal May 2010
Defect-driven flexochemical coupling in thin ferroelectric films journal January 2018
Labyrinthine domains in ferroelectric nanoparticles: Manifestation of a gradient-induced morphological transition journal August 2018
Effect of Mechanical Boundary Conditions on Phase Diagrams of Epitaxial Ferroelectric Thin Films journal March 1998
Abrupt Appearance of the Domain Pattern and Fatigue of Thin Ferroelectric Films journal April 2000
Giant negative electrostriction and dielectric tunability in a van der Waals layered ferroelectric journal February 2019
Screening-induced phase transitions in core-shell ferroic nanoparticles journal December 2022
Physics and Modeling of Multidomain FeFET With Domain Wall-Induced Negative Capacitance journal August 2022
Critical Importance of Nonuniform Polarization and Fringe Field Effects for Scaled Ferroelectric FinFET Memory journal September 2022