Unraveling capacity fading in lithium-ion batteries using advanced cyclic tests: A real-world approach

Mulpuri, Sai Krishna; Sah, Bikash; Kumar, Praveen

doi:10.1016/j.isci.2023.107770

Title: Unraveling capacity fading in lithium-ion batteries using advanced cyclic tests: A real-world approach

Journal Article · 28 August 2023 · iScience

DOI: https://doi.org/10.1016/j.isci.2023.107770 · OSTI ID:2471458

Mulpuri, Sai Krishna ^[1]; Sah, Bikash ^[2]; Kumar, Praveen ^[3]

Indian Institute of Technology Guwahati, Assam (India)
Mechanical Engineering and Technical Journalism, Hochschule Bonn-Rhein-Seig, North Rhine-Westphalia (Germany); Fraunhofer Institute for Energy Economics and Energy System Technology, Hesse (Germany)
Indian Institute of Technology Guwahati, Assam (India); Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Battery lifespan estimation is essential for effective battery management systems, aiding users and manufacturers in strategic planning. However, accurately estimating battery capacity is complex, owing to diverse capacity fading phenomena tied to factors such as temperature, charge-discharge rate, and rest period duration. In this work, we present an innovative approach that integrates real-world driving behaviors into cyclic testing. Unlike conventional methods that lack rest periods and involve fixed charge-discharge rates, our approach involves 1000 unique test cycles tailored to specific objectives and applications, capturing the nuanced effects of temperature, charge-discharge rate, and rest duration on capacity fading. This yields comprehensive insights into cell-level battery degradation, unveiling growth patterns of the solid electrolyte interface (SEI) layer and lithium plating, influenced by cyclic test parameters. Here, the results yield critical empirical relations for evaluating capacity fading under specific testing conditions.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 2471458

Journal Information:: iScience, Journal Name: iScience Journal Issue: 10 Vol. 26; ISSN 2589-0042

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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