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Title: Impact of Surface Enhanced Raman Spectroscopy in Catalysis

Journal Article · · ACS Nano
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Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
SC0004752
OSTI ID:
2466249
Journal Information:
ACS Nano, Journal Name: ACS Nano Journal Issue: 43 Vol. 18; ISSN 1936-0851
Publisher:
American Chemical SocietyCopyright Statement
Country of Publication:
United States
Language:
English

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Chiral Carbonaceous Nanotubes Modified with Titania Nanocrystals: Plasmon‐Free and Recyclable SERS Sensitivity journal July 2015
Metal Nanoparticle‐Catalyzed Reduction Using Borohydride in Aqueous Media: A Kinetic Analysis of the Surface Reaction by Microfluidic SERS journal September 2016
C−H Arylation on Nickel Nanoparticles Monitored by In Situ Surface‐Enhanced Raman Spectroscopy journal May 2019
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Towards Reliable and Quantitative Surface‐Enhanced Raman Scattering (SERS): From Key Parameters to Good Analytical Practice journal February 2020
In situ Spectroscopic Insight into the Origin of the Enhanced Performance of Bimetallic Nanocatalysts towards the Oxygen Reduction Reaction (ORR) journal October 2019
Enantiomeric Discrimination by Surface‐Enhanced Raman Scattering–Chiral Anisotropy of Chiral Nanostructured Gold Films journal June 2020
Spectroscopic Verification of Adsorbed Hydroxy Intermediates in the Bifunctional Mechanism of the Hydrogen Oxidation Reaction journal January 2021
Probing Single‐Atom Catalysts and Catalytic Reaction Processes by Shell‐Isolated Nanoparticle‐Enhanced Raman Spectroscopy journal March 2021
The Pivotal Role of Hot Carriers in Plasmonic Catalysis of C−N Bond Forming Reaction of Amines journal April 2021
Surface‐Enhanced Raman Spectroscopic Evidence of Key Intermediate Species and Role of NiFe Dual‐Catalytic Center in Water Oxidation journal July 2021
Unmasking the Critical Role of the Ordering Degree of Bimetallic Nanocatalysts on Oxygen Reduction Reaction by In Situ Raman Spectroscopy journal February 2022
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Dynamics of Solid‐Electrolyte Interphase Formation on Silicon Electrodes Revealed by Combinatorial Electrochemical Screening journal July 2022
Low‐Coordination Single Au Atoms on Ultrathin ZnIn2S4Nanosheets for Selective Photocatalytic CO2Reduction towards CH4 journal September 2022
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Electronic Perturbation of Copper Single‐Atom CO2Reduction Catalysts in a Molecular Way journal December 2022
Tuning the Electronic Properties of Platinum in Hybrid‐Nanoparticle Assemblies for use in Hydrogen Evolution Reaction journal May 2023
Chaotropic Nanoelectrocatalysis: Chemically Disrupting Water Intermolecular Network at the Point‐of‐Catalysis to Boost Green Hydrogen Electrosynthesis journal January 2024
Creating 3D Nanoparticle Structural Space via Data Augmentation to Bidirectionally Predict Nanoparticle Mixture's Purity, Size, and Shape from Extinction Spectra journal February 2024
Unraveling the Chirality Transfer from Circularly Polarized Light to Single Plasmonic Nanoparticles journal February 2024
In-Situ Electrochemical SHINERS Investigation of SEI Composition on Carbon-Coated Zn 0.9 Fe 0.1 O Anode for Lithium-Ion Batteries journal October 2018
Investigation of the Kinetics of a Surface Photocatalytic Reaction in Two Dimensions with Surface‐enhanced Raman Scattering journal October 2014
Asymmetric Photocatalysis Enabled by Chiral Organocatalysts journal November 2021
Thermally Stable TiO 2 - and SiO 2 -Shell-Isolated Au Nanoparticles for In Situ Plasmon-Enhanced Raman Spectroscopy of Hydrogenation Catalysts journal February 2018
Extending Surface‐Enhanced Raman Spectroscopy to Liquids Using Shell‐Isolated Plasmonic Superstructures journal October 2019
Practical Guidelines for Shell-Isolated Nanoparticle-Enhanced Raman Spectroscopy of Heterogeneous Catalysts journal July 2018
Oxygen‐Mediated Surface Photoreactions: Exploring New Pathways for Sustainable Chemistry journal December 2023
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Surface-enhanced Raman spectroscopy: a brief retrospective journal January 2005
All‐dielectric core/shell resonators: From plasmon‐free SERS to multimodal analysis journal February 2018
Theoretical treatment of single‐molecule scanning Raman picoscopy in strongly inhomogeneous near fields journal September 2020
Tailoring the Pore Size and Architecture of CeO2/TiO2 Core/Shell Inverse Opals by Atomic Layer Deposition journal January 2009
A Novel Application of Plasmonics: Plasmon-Driven Surface-Catalyzed Reactions journal July 2012
Triggering and Monitoring Plasmon-Enhanced Reactions by Optical Nanoantennas Coupled to Photocatalytic Beads journal April 2013
All‐Oxide Raman‐Active Traps for Light and Matter: Probing Redox Homeostasis Model Reactions in Aqueous Environment journal December 2013
New Mechanism for Long Photo‐Induced Enhanced Raman Spectroscopy in Au Nanoparticles Embedded in TiO2 journal May 2022
Artificial Intelligence for Surface‐Enhanced Raman Spectroscopy journal October 2023
Surface-Enhanced Raman Spectroscopy as anin SituReal-Time Probe of Catalytic Mechanisms at High Gas Pressures: journal September 1996
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Alumina-coated Ag nanocrystal monolayers as surfaceenhanced Raman spectroscopy platforms for the direct spectroscopic detection of water splitting reaction intermediates journal December 2013
Stabilizing photo-induced vacancy defects in MOF matrix for high-performance SERS detection journal March 2022
Nanoparticle-on-mirror cavity: a historical view across nanophotonics and nanochemistry journal January 2022
Single-atom sites on perovskite chips for record-high sensitivity and quantification in SERS journal March 2022
Raman spectra of pyridine adsorbed at a silver electrode journal May 1974
Voltage-induced shifting of charge-transfer excitations and their role in surface-enhanced Raman scattering journal March 1983
Theory of charge transfer excitation in surface enhanced Raman scattering journal September 1983
A comparison of surface-enhanced infrared and surface-enhanced Raman spectra of pyrazine adsorbed on polycrystalline gold electrodes journal March 2001
Surface raman spectroelectrochemistry: Part I. Heterocyclic, aromatic, and aliphatic amines adsorbed on the anodized silver electrode journal November 1977
Further identification to the SEI film on Ag electrode in lithium batteries by surface enhanced Raman scattering (SERS) journal February 2002
Silver nanoparticle catalyzed reduction of aromatic nitro compounds journal January 2002
Using probe molecule FTIR spectroscopy to identify and characterize Pt-group metal based single atom catalysts journal September 2017
Surface-enhanced vibrational spectroscopies in electrocatalysis: Fundamentals, challenges, and perspectives journal November 2022
Operando SERS self-monitoring photocatalytic oxidation of aminophenol on TiO2 semiconductor journal May 2018
Synthesis of yolk-shell Fe3O4@void@CeO2 nanoparticles and their application in SERS journal March 2021
Plasmon-Induced Interfacial Hot-Electron Transfer Directly Probed by Raman Spectroscopy journal March 2020
Boosting electromagnetic enhancement for detection of non-adsorbing analytes on semiconductor SERS substrates journal June 2023
Trends and advances in Operando methodology journal May 2016
Understanding electrocatalysis at nanoscale electrodes and single atoms with operando vibrational spectroscopy journal December 2022
SERS liquid biopsy: An emerging tool for medical diagnosis journal December 2021
New application of photocatalytic TiO2 nanoparticles on the improved surface-enhanced Raman scattering journal March 2006
Rigorous justification of the |E|4 enhancement factor in Surface Enhanced Raman Spectroscopy journal May 2006
The mechanism of HF formation in LiPF6 based organic carbonate electrolytes journal January 2012
SERS and machine learning based effective feature extraction for detection and identification of amphetamine analogs journal December 2023
In situ surface enhanced Raman spectroscopic studies of solid electrolyte interphase formation in lithium ion battery electrodes journal June 2014
In situ diagnosis of the electrolyte solution in a laminate lithium ion battery by using ultrafine multi-probe Raman spectroscopy journal August 2017
Recent advancement of SiOx based anodes for lithium-ion batteries journal September 2017
How to achieve auto-identification in Raman analysis by spectral feature extraction & Adaptive Hypergraph journal November 2019
Recent progress and applications of Raman spectrum denoising algorithms in chemical and biological analyses: A review journal March 2024
Single-atom heterogeneous catalysts for sustainable organic synthesis journal April 2022
The role of morphology in all-dielectric SERS: A comparison between conformal (T-rex) and non conformal TiO2 shells journal July 2020
Peer Reviewed: The New Interfacial Ubiquity of Surface-Enhanced Raman Spectroscopy journal January 2000
Surface-Enhanced Raman Scattering on Uniform Transition-Metal Films:  Toward a Versatile Adsorbate Vibrational Strategy for Solid-Nonvacuum Interfaces? journal June 1998
Toward In Situ Atomistic Design of Catalytic Active Sites via Controlled Atmosphere Transmission Electron Microscopy journal February 2023
Molecular Optomechanics Approach to Surface-Enhanced Raman Scattering journal July 2022
A Chemist’s View on Electronic and Steric Effects of Surface Ligands on Plasmonic Metal Nanostructures journal July 2023
Plasmon-Mediated Chemical Reactions on Nanostructures Unveiled by Surface-Enhanced Raman Spectroscopy journal September 2019
Single-Molecule Surface-Enhanced Raman Scattering as a Probe of Single-Molecule Surface Reactions: Promises and Current Challenges journal October 2019
Nanophotonic Platforms for Chiral Sensing and Separation journal January 2020
Exploring the Effect of Pd on the Oxygen Reduction Performance of Pt by In Situ Raman Spectroscopy journal March 2022
Visualization of a Machine Learning Framework toward Highly Sensitive Qualitative Analysis by SERS journal July 2022
Chiral Detection of Glucose: An Amino Acid-Assisted Surface-Enhanced Raman Scattering Strategy Showing Opposite Enantiomeric Effects on SERS Signals journal October 2022
Interfacial Evolution on Co-based Oxygen Evolution Reaction Electrocatalysts Probed by Using In Situ Surface-Enhanced Raman Spectroscopy journal December 2022
Digital Protocol for Chemical Analysis at Ultralow Concentrations by Surface-Enhanced Raman Scattering journal December 2017
Quantification of Analyte Concentration in the Single Molecule Regime Using Convolutional Neural Networks journal October 2019
Single-Atom Alloy Catalysis journal June 2020
Single-Atom Catalysts across the Periodic Table journal October 2020
Atomically Dispersed Metals on Well-Defined Supports including Zeolites and Metal–Organic Frameworks: Structure, Bonding, Reactivity, and Catalysis journal October 2020
Chiral Photocatalyst Structures in Asymmetric Photochemical Synthesis journal October 2021
Operando Electron Microscopy of Catalysts: The Missing Cornerstone in Heterogeneous Catalysis Research? journal November 2023
Enhanced Raman Scattering with Dielectrics journal October 2016
Stimulated Raman Scattering: From Bulk to Nano journal December 2016
Single-Molecule Chemistry with Surface- and Tip-Enhanced Raman Spectroscopy journal December 2016
Machine Learning for Silver Nanoparticle Electron Transfer Property Prediction journal October 2017
Deep Learning-Based Spectral Extraction for Improving the Performance of Surface-Enhanced Raman Spectroscopy Analysis on Multiplexed Identification and Quantitation journal April 2022
Photoinduced Enhanced Raman Spectroscopy with Hybrid Au@WS2 Nanosheets journal August 2020
Chiral Optical Force Generated by a Superchiral Near-Field of a Plasmonic Triangle Trimer as Origin of Giant Bias in Chiral Nucleation: A Simulation Study journal March 2021
Stochastic Noise in Single-Nanoparticle Catalysis journal August 2021
Self-Referenced SERS Thermometry of Molecules on a Metallic Nanostructure journal December 2021
Microscopic Understanding of Reaction Rates Observed in Plasmon Chemistry of Nanoparticle–Ligand Systems journal March 2022
Single-Molecule SERS Hotspot Dynamics in Both Dry and Aqueous Environments journal April 2022
Picocavity-Controlled Subnanometer-Resolved Single-Molecule Fluorescence Imaging and Mollow Triplets journal June 2022
Investigation of SERS Frequency Fluctuations Relevant to Sensing and Catalysis journal August 2022
Photodissociation of H2 on Ag and Au Nanoparticles: Effect of Size and Plasmon versus Interband Transitions on Threshold Intensities for Dissociation journal February 2023
Probing the Intermediate in the Electrochemical Reduction of Nitrobenzene Derivative by EC-TERS journal June 2023
Evaluating Single-Molecule Stokes and Anti-Stokes SERS for Nanoscale Thermometry journal August 2015
Spectroscopic Observation of Reversible Surface Reconstruction of Copper Electrodes under CO 2 Reduction journal May 2017
Influence of Optically Rectified Electric Fields on the Plasmonic Photocatalysis of 4-Nitrothiophenol and 4-Aminothiophenol to 4,4-Dimercaptoazobenzene journal March 2018
Hot Electron-Induced Carbon–Halogen Bond Cleavage Monitored by in Situ Surface-Enhanced Raman Spectroscopy journal June 2019
In Situ Observation of Unique Bianalyte Molecular Behaviors at the Gap of a Single Metal Nanodimer Structure via Electrochemical Surface-Enhanced Raman Scattering Measurements journal September 2019
Taking the Heat Off of Plasmonic Chemistry journal October 2019
Surface Changes of LiNi x Mn y Co 1– xy O 2 in Li-Ion Batteries Using in Situ Surface-Enhanced Raman Spectroscopy journal January 2020
Oxygen Reduction Activities of Strained Platinum Core–Shell Electrocatalysts Predicted by Machine Learning journal February 2020
Direct Operando Observation of Double Layer Charging and Early Solid Electrolyte Interphase Formation in Li-Ion Battery Electrolytes journal May 2020
Atomically Dispersed Pt-group Catalysts: Reactivity, Uniformity, Structural Evolution, and Paths to Increased Functionality journal November 2020
Photoexcited Plasmon-Driven Ultrafast Dynamics of the Adsorbate Probed by Femtosecond Time-Resolved Surface-Enhanced Time-Domain Raman Spectroscopy journal March 2023
Understanding the Chemical Mechanism behind Photoinduced Enhanced Raman Spectroscopy journal May 2023
Using Surface-Enhanced Raman Spectroscopy to Unravel the Wingtip-Dependent Orientation of N-Heterocyclic Carbenes on Gold Nanoparticles journal May 2023
Mapping Atomic-Scale Metal–Molecule Interactions: Salient Feature Extraction through Autoencoding of Vibrational Spectroscopy Data journal August 2023
Surface- and Tip-Enhanced Raman Spectroscopy in Catalysis journal April 2016
Surface-Enhanced Femtosecond Stimulated Raman Spectroscopy at 1 MHz Repetition Rates journal November 2016
Bias-Dependent Chemical Enhancement and Nonclassical Stark Effect in Tip-Enhanced Raman Spectromicroscopy of CO-Terminated Ag Tips journal May 2018
In Situ Nanoscale Investigation of Catalytic Reactions in the Liquid Phase Using Zirconia-Protected Tip-Enhanced Raman Spectroscopy Probes journal March 2019
Room-Temperature Optical Picocavities below 1 nm3 Accessing Single-Atom Geometries journal December 2018
Is the Suzuki–Miyaura Cross-Coupling Reaction in the Presence of Pd Nanoparticles Heterogeneously or Homogeneously Catalyzed? An Interfacial Surface-Enhanced Raman Spectroscopy Study journal March 2019
Role of Valence Band States and Plasmonic Enhancement in Electron-Transfer-Induced Transformation of Nitrothiophenol journal May 2019
Machine Learning Protocol for Surface-Enhanced Raman Spectroscopy journal September 2019
The Effect of Photoinduced Surface Oxygen Vacancies on the Charge Carrier Dynamics in TiO 2 Films journal September 2021
Picocavities: a Primer journal July 2022
In Situ Probe of the Hydrogen Oxidation Reaction Intermediates on PtRu a Bimetallic Catalyst Surface by Core–Shell Nanoparticle-Enhanced Raman Spectroscopy journal June 2022
Selective Photodetoxification of a Sulfur Mustard Simulant Using Plasmonic Aluminum Nanoparticles journal September 2022
Surface Topographical Engineering of Chiral Au Nanocrystals with Chiral Hot Spots for Plasmon-Enhanced Chiral Discrimination journal August 2023
Atomistic Near-Field Nanoplasmonics: Reaching Atomic-Scale Resolution in Nanooptics journal April 2015
Probing Redox Reactions at the Nanoscale with Electrochemical Tip-Enhanced Raman Spectroscopy journal November 2015
Activation Energies of Plasmonic Catalysts journal April 2016
Conformational Contrast of Surface-Mediated Molecular Switches Yields Ångstrom-Scale Spatial Resolution in Ultrahigh Vacuum Tip-Enhanced Raman Spectroscopy journal November 2016
Frequency-Domain Proof of the Existence of Atomic-Scale SERS Hot-Spots journal December 2017
Operando Investigation into Dynamic Evolution of Cathode–Electrolyte Interfaces in a Li-Ion Battery journal February 2019
Angstrom Scale Chemical Analysis of Metal Supported Trans- and Cis-Regioisomers by Ultrahigh Vacuum Tip-Enhanced Raman Mapping journal April 2019
Photocatalytic Hydrogenation of Graphene Using Pd Nanocones journal June 2019
Nonzero Wavevector Excitation of Graphene by Localized Surface Plasmons journal September 2019
Fast and Slow Time-Scale Effects of Photoinduced Surface Oxygen Vacancies on the Charge Carrier Dynamics of TiO2 journal March 2024
Unidirectional/Bidirectional Electron Transfer at the Au/TiO2 Interface Operando Tracked by SERS Spectra from Au and TiO2 journal March 2021
Study of a High-Voltage NMC Interphase in the Presence of a Thiophene Additive Realized by Operando SHINERS journal January 2023
How Does a Plasmon-Induced Hot Charge Carrier Break a C–C Bond? journal June 2019
Electrosynthesis of Ammonia Using Porous Bimetallic Pd–Ag Nanocatalysts in Liquid- and Gas-Phase Systems journal August 2020
Kinetics and Mechanism of Plasmon-Driven Dehalogenation Reaction of Brominated Purine Nucleobases on Ag and Au journal June 2021
Oxyhydroxide Species Enhances CO2 Electroreduction to CO on Ag via Coelectrolysis with O2 journal September 2021
Selective Enhancement of Methane Formation in Electrochemical CO2 Reduction Enabled by a Raman-Inactive Oxygen-Containing Species on Cu journal May 2022
Probing the Intermediates of Catalyzed Dehydration Reactions of Primary Amide to Nitrile in Plasmonic Junctions journal June 2022
Mechanistic Study of Plasmon-Assisted In Situ Photoelectrochemical CO2 Reduction to Acetate with a Ag/Cu2O Nanodendrite Electrode journal January 2023
Enhanced Nitrate Reduction Activity from Cu-Alloy Electrodes in an Alkaline Electrolyte journal May 2023
Limits of Detection for EXAFS Characterization of Heterogeneous Single-Atom Catalysts journal April 2023
Plasmon-Assisted Chemistry Using Chiral Gold Helicoids: Toward Asymmetric Organic Catalysis journal September 2023
In Situ/Operando Techniques for Characterization of Single-Atom Catalysts journal February 2019
Machine Learning for Accelerated Discovery of Solar Photocatalysts journal October 2019
In Situ Shell-Isolated Nanoparticle-Enhanced Raman Spectroscopy to Unravel Sequential Hydrogenation of Phenylacetylene over Platinum Nanoparticles journal September 2019
Solid Electrolyte Interphase Instability in Operating Lithium-Ion Batteries Unraveled by Enhanced-Raman Spectroscopy journal April 2021
Probing the Role of Atomic Defects in Photocatalytic Systems through Photoinduced Enhanced Raman Scattering journal November 2021
Chemical Production Using Light: Are Sustainable Photons Cheap Enough? journal February 2022
Direct H2S Decomposition by Plasmonic Photocatalysis: Efficient Remediation plus Sustainable Hydrogen Production journal September 2022
The Decisive Role of Li2O2 Desorption for Oxygen Reduction Reaction in Li–O2 Batteries journal February 2023
In Situ Surface-Enhanced Raman Spectroscopic Evidence on the Origin of Selectivity in CO2 Electrocatalytic Reduction journal August 2020
Long-Lived Hot Electron in a Metallic Particle for Plasmonics and Catalysis: Ab Initio Nonadiabatic Molecular Dynamics with Machine Learning journal July 2020
In Situ Photothermal Response of Single Gold Nanoparticles through Hyperspectral Imaging Anti-Stokes Thermometry journal September 2020
Intermolecular Forces Dictate Vibrational Energy Transfer in Plasmonic–Molecule Systems journal December 2021
Two-Dimensional TiVC Solid-Solution MXene as Surface-Enhanced Raman Scattering Substrate journal February 2022
Tip-Enhanced Raman Scattering Imaging of Single- to Few-Layer Ti3C2Tx MXene journal April 2022
Plasmonic Photocatalysis with Chemically and Spatially Specific Antenna–Dual Reactor Complexes journal October 2022
Ostensible Steady-State Molecular Cooling with Plasmonic Gold Nanoparticles journal March 2023
Interface-Dependent Selectivity in Plasmon-Driven Chemical Reactions journal February 2023
High-Speed Spectral Characterization of Single-Molecule SERS Fluctuations journal March 2023
Surface-Enhanced Raman Scattering-Based Surface Chemotaxonomy: Combining Bacteria Extracellular Matrices and Machine Learning for Rapid and Universal Species Identification journal November 2023
Circular Polarization-Resolved Raman Optical Activity: A Perspective on Chiral Spectroscopies of Vibrational States journal May 2024
Enhancement Factors: A Central Concept during 50 Years of Surface-Enhanced Raman Spectroscopy journal March 2024
Fifty Years of Surface-Enhanced Spectroscopy journal February 2024
Surface-Enhanced Raman Spectroscopy: Current Understanding, Challenges, and Opportunities journal May 2024
Mechanism of Charge Transfer from Plasmonic Nanostructures to Chemically Attached Materials journal May 2016
Quantum Mechanical Description of Raman Scattering from Molecules in Plasmonic Cavities journal May 2016
Single-Molecule Imaging Using Atomistic Near-Field Tip-Enhanced Raman Spectroscopy journal May 2017
Atomic-Scale Lightning Rod Effect in Plasmonic Picocavities: A Classical View to a Quantum Effect journal January 2018
Ultrafast Nanoscale Raman Thermometry Proves Heating Is Not a Primary Mechanism for Plasmon-Driven Photocatalysis journal May 2018
Watching Visible Light-Driven CO 2 Reduction on a Plasmonic Nanoparticle Catalyst journal July 2018
Unveiling Defect-Related Raman Mode of Monolayer WS2 via Tip-Enhanced Resonance Raman Scattering journal August 2018
Electrolyte Solvation Structure at Solid–Liquid Interface Probed by Nanogap Surface-Enhanced Raman Spectroscopy journal September 2018
Machine-Learning-Driven Surface-Enhanced Raman Scattering Optophysiology Reveals Multiplexed Metabolite Gradients Near Cells journal February 2019
Present and Future of Surface-Enhanced Raman Scattering journal September 2019
Operando Nanoscale Sensors in Catalysis: All Eyes on Catalyst Particles journal April 2020
Spectrally Resolved Surface-Enhanced Raman Scattering Imaging Reveals Plasmon-Mediated Chemical Transformations journal December 2021
Bright Plasmons with Cubic Nanometer Mode Volumes through Mode Hybridization journal January 2021
Probing the Redox Selectivity on Au@Pd and Au@Pt Bimetallic Nanoplates by Tip-Enhanced Raman Spectroscopy journal June 2021
Locating Single-Atom Optical Picocavities Using Wavelength-Multiplexed Raman Scattering journal October 2021
Chiral Bioinspired Plasmonics: A Paradigm Shift for Optical Activity and Photochemistry journal June 2022
Effect of Material and Shape of Nanoparticles on Hot Carrier Generation journal September 2022
Enantioselective Optical Trapping of Chiral Nanoparticles with Plasmonic Tweezers journal February 2016
Relaxation of Plasmon-Induced Hot Carriers journal December 2017
Valence Electron Density-Dependent Pseudopermittivity for Nonlocal Effects in Optical Properties of Metallic Nanoparticles journal May 2018
Mastering Femtosecond Stimulated Raman Spectroscopy: A Practical Guide journal October 2023
Single-Atom Catalysts: A New Frontier in Heterogeneous Catalysis journal April 2013
A Unified View of Surface-Enhanced Raman Scattering journal June 2009
Asymmetric photochemical reactions in solution journal July 1992
Optical Studies of Dynamics in Noble Metal Nanostructures journal June 2011
Designing Pd-on-Au Bimetallic Nanoparticle Catalysts for Trichloroethene Hydrodechlorination journal March 2005
Surface-Enhanced Raman Spectroscopy as an in-situ Real-Time Probe of Catalytic Mechanisms at High Gas Pressures: The CO-NO Reaction on Rhodium journal March 1995
Charge transfer resonance Raman process in surface-enhanced Raman scattering from p-aminothiophenol adsorbed on silver: Herzberg-Teller contribution journal December 1994
Anomalously intense Raman spectra of pyridine at a silver electrode journal June 1977
Observation of a Small Number of Molecules at a Metal Nanogap Arrayed on a Solid Surface Using Surface-Enhanced Raman Scattering journal January 2007
A Frequency Domain Existence Proof of Single-Molecule Surface-Enhanced Raman Spectroscopy
  • Dieringer, Jon A.; Lettan, Robert B.; Scheidt, Karl A.
  • Journal of the American Chemical Society, Vol. 129, Issue 51, p. 16249-16256 https://doi.org/10.1021/ja077243c
journal December 2007
Monitoring the Electrochemistry of Single Molecules by Surface-Enhanced Raman Spectroscopy journal December 2010
Evidence for Crystal-Face-Dependent TiO 2 Photocatalysis from Single-Molecule Imaging and Kinetic Analysis journal May 2011
Reactions in the Rechargeable Lithium–O 2 Battery with Alkyl Carbonate Electrolytes journal May 2011
Synthesis of Bifunctional Au/Pt/Au Core/Shell Nanoraspberries for in Situ SERS Monitoring of Platinum-Catalyzed Reactions journal December 2011
Mapping the Energy Distribution of SERRS Hot Spots from Anti-Stokes to Stokes Intensity Ratios journal August 2012
Single Molecule Dynamics at a Mechanically Controllable Break Junction in Solution at Room Temperature journal October 2012
Label-Free SERS Monitoring of Chemical Reactions Catalyzed by Small Gold Nanoparticles Using 3D Plasmonic Superstructures journal November 2012
The Li-Ion Rechargeable Battery: A Perspective journal January 2013
Structure Enhancement Factor Relationships in Single Gold Nanoantennas by Surface-Enhanced Raman Excitation Spectroscopy journal December 2012
Enhancing Raman Scattering without Plasmons: Unprecedented Sensitivity Achieved by TiO2 Shell-Based Resonators journal April 2013
Direct In situ Observation of Li 2 O Evolution on Li-Rich High-Capacity Cathode Material, Li[Ni x Li (1–2 x )/3 Mn (2– x )/3 ]O 2 (0 ≤ x ≤0.5) journal January 2014
Improved SERS Sensitivity on Plasmon-Free TiO 2 Photonic Microarray by Enhancing Light-Matter Coupling journal June 2014
Single-Molecule Surface-Enhanced Raman Spectroscopy of Nonresonant Molecules journal September 2009
Probing Molecular Vibrations at Catalytically Significant Interfaces:  A New Ubiquity of Surface-Enhanced Raman Scattering journal April 1998
Ag@MoS2 Core–Shell Heterostructure as SERS Platform to Reveal the Hydrogen Evolution Active Sites of Single-Layer MoS2 journal March 2020
Probing Bias-Induced Electron Density Shifts in Metal–Molecule Interfaces via Tip-Enhanced Raman Scattering journal January 2021
Molecular Insight of the Critical Role of Ni in Pt-Based Nanocatalysts for Improving the Oxygen Reduction Reaction Probed Using an In Situ SERS Borrowing Strategy journal January 2021
Chemistry under Vibrational Strong Coupling journal October 2021
Chiral Generation of Hot Carriers for Polarization-Sensitive Plasmonic Photocatalysis journal January 2022
Controlling Localized Plasmons via an Atomistic Approach: Attainment of Site-Selective Activation inside a Single Molecule journal January 2022
Room-Temperature Molecular Manipulation via Plasmonic Trapping at Electrified Interfaces journal February 2022
Inherent Promotion of Ionic Conductivity via Collective Vibrational Strong Coupling of Water with the Vacuum Electromagnetic Field journal June 2022
Probing the Dynamics of Low-Overpotential CO2-to-CO Activation on Copper Electrodes with Time-Resolved Raman Spectroscopy journal August 2022
Electrocatalytic CO2-to-C2+ with Ampere-Level Current on Heteroatom-Engineered Copper via Tuning *CO Intermediate Coverage journal August 2022
Au Atoms Anchored on Amorphous C3N4 for Single-Site Raman Enhancement journal November 2022
Vibrationally Hot Reactants in a Plasmon-Assisted Chemical Reaction journal May 2023
Tracking the Evolution of Single-Atom Catalysts for the CO2 Electrocatalytic Reduction Using Operando X-ray Absorption Spectroscopy and Machine Learning journal July 2023
In Situ Monitoring of Electrooxidation Processes at Gold Single Crystal Surfaces Using Shell-Isolated Nanoparticle-Enhanced Raman Spectroscopy journal June 2015
Transient Electrochemical Surface-Enhanced Raman Spectroscopy: A Millisecond Time-Resolved Study of an Electrochemical Redox Process journal September 2015
Direct Observation of Charge Separation on Anatase TiO 2 Crystals with Selectively Etched {001} Facets journal February 2016
Metal-Catalyzed Chemical Reaction of Single Molecules Directly Probed by Vibrational Spectroscopy journal March 2016
Revealing the Role of Interfacial Properties on Catalytic Behaviors by in Situ Surface-Enhanced Raman Spectroscopy journal July 2017
Chemical Pressure-Driven Enhancement of the Hydrogen Evolving Activity of Ni 2 P from Nonmetal Surface Doping Interpreted via Machine Learning journal March 2018
Structural Dynamics of the Oxygen-Evolving Complex of Photosystem II in Water-Splitting Action journal April 2018
Interfacial Construction of Plasmonic Nanostructures for the Utilization of the Plasmon-Excited Electrons and Holes journal May 2019
Direct In Situ Raman Spectroscopic Evidence of Oxygen Reduction Reaction Intermediates at High-Index Pt( hkl ) Surfaces journal December 2019
Spatiotemporal Mapping of Local Heterogeneities during Electrochemical Carbon Dioxide Reduction journal July 2023
Surface-Enhanced Raman Scattering Study on Passivating Films of Ag Electrodes in Lithium Batteries journal August 2000
Surface-Enhanced Raman Scattering:  From Noble to Transition Metals and from Rough Surfaces to Ordered Nanostructures journal September 2002
Proof of Single-Molecule Sensitivity in Surface Enhanced Raman Scattering (SERS) by Means of a Two-Analyte Technique journal February 2006
Size-Dependence of the Enhanced Raman Scattering of Pyridine Adsorbed on Ag n ( n = 2−8, 20) Clusters journal March 2007
Surface Enhanced Raman Scattering Enhancement Factors:  A Comprehensive Study journal August 2007
From Discrete Electronic States to Plasmons: TDDFT Optical Absorption Properties of Ag n ( n = 10, 20, 35, 56, 84, 120) Tetrahedral Clusters journal July 2008
Surface-Enhanced Femtosecond Stimulated Raman Spectroscopy journal April 2011
Raman Enhancement via Polariton States Produced by Strong Coupling between a Localized Surface Plasmon and Dye Excitons at Metal Nanogaps journal December 2013
Substrate-, Wavelength-, and Time-Dependent Plasmon-Assisted Surface Catalysis Reaction of 4-Nitrobenzenethiol Dimerizing to p , p ′-Dimercaptoazobenzene on Au, Ag, and Cu Films journal September 2011
Nonlocal Effects in the Nanofocusing Performance of Plasmonic Tips journal May 2012
Hot Electrons Do the Impossible: Plasmon-Induced Dissociation of H 2 on Au journal December 2012
Green chemistry journal December 2007
Light-activated catalysts point the way to sustainable chemistry journal February 2023
Nanostructure-based plasmon-enhanced Raman spectroscopy for surface analysis of materials journal April 2016
Shell-isolated nanoparticle-enhanced Raman spectroscopy journal March 2010
Chemical mapping of a single molecule by plasmon-enhanced Raman scattering journal June 2013
Evidence and implications of direct charge excitation as the dominant mechanism in plasmon-mediated photocatalysis journal January 2016
Quantum mechanical effects in plasmonic structures with subnanometre gaps journal June 2016
Photo-induced enhanced Raman spectroscopy for universal ultra-trace detection of explosives, pollutants and biomolecules journal July 2016
Revealing the molecular structure of single-molecule junctions in different conductance states by fishing-mode tip-enhanced Raman spectroscopy journal May 2011
In situ dynamic tracking of heterogeneous nanocatalytic processes by shell-isolated nanoparticle-enhanced Raman spectroscopy journal May 2017
Bridging quantum and classical plasmonics with a quantum-corrected model journal January 2012
A 1.7 nm resolution chemical analysis of carbon nanotubes by tip-enhanced Raman imaging in the ambient journal February 2014
A generalized non-local optical response theory for plasmonic nanostructures journal May 2014
Coherent anti-Stokes Raman scattering with single-molecule sensitivity using a plasmonic Fano resonance journal July 2014
Noble metal-comparable SERS enhancement from semiconducting metal oxides by making oxygen vacancies journal July 2015
Conductivity in organic semiconductors hybridized with the vacuum field journal September 2015
Nanostructured organic semiconductor films for molecular detection with surface-enhanced Raman spectroscopy journal August 2017
Plasmon-induced hot carrier science and technology journal January 2015
Molecular cavity optomechanics as a theory of plasmon-enhanced Raman scattering journal November 2015
Probing the electronic and catalytic properties of a bimetallic surface with 3 nm resolution journal November 2016
Selection-rule breakdown in plasmon-induced electronic excitation of an isolated single-walled carbon nanotube journal May 2013
Seeing a single molecule vibrate through time-resolved coherent anti-Stokes Raman scattering journal July 2014
Simple experimental procedures to distinguish photothermal from hot-carrier processes in plasmonics journal June 2020
Semiconductor SERS enhancement enabled by oxygen incorporation journal December 2017
In situ formation of catalytically active graphene in ethylene photo-epoxidation journal August 2018
Plasmon-enhanced stimulated Raman scattering microscopy with single-molecule detection sensitivity journal November 2019
A rich catalog of C–C bonded species formed in CO2 reduction on a plasmonic photocatalyst journal May 2021
In-situ nanospectroscopic imaging of plasmon-induced two-dimensional [4+4]-cycloaddition polymerization on Au(111) journal July 2021
Resolving sub-angstrom ambient motion through reconstruction from vibrational spectra journal November 2021
Hollow-core optical fibre sensors for operando Raman spectroscopy investigation of Li-ion battery liquid electrolytes journal March 2022
Chiral molecular imprinting-based SERS detection strategy for absolute enantiomeric discrimination journal September 2022
Giant optomechanical spring effect in plasmonic nano- and picocavities probed by surface-enhanced Raman scattering journal June 2023
Resolving nanostructure and chemistry of solid-electrolyte interphase on lithium anodes by depth-sensitive plasmon-enhanced Raman spectroscopy journal June 2023
Revealing the role of interfacial water and key intermediates at ruthenium surfaces in the alkaline hydrogen evolution reaction journal August 2023
Forward-predictive SERS-based chemical taxonomy for untargeted structural elucidation of epimeric cerebrosides journal March 2024
Explainable machine learning in materials science journal September 2022
Identifying the components of the solid–electrolyte interphase in Li-ion batteries journal August 2019
Enantioselective photoinduced cyclodimerization of a prochiral anthracene derivative adsorbed on helical metal nanostructures journal April 2020
In situ Raman spectroscopic evidence for oxygen reduction reaction intermediates at platinum single-crystal surfaces journal December 2018
Light-driven methane dry reforming with single atomic site antenna-reactor plasmonic photocatalysts journal January 2020
In situ probing electrified interfacial water structures at atomically flat surfaces journal April 2019
High-speed imaging of surface-enhanced Raman scattering fluctuations from individual nanoparticles journal September 2019
Single-molecule tautomerization tracking through space- and time-resolved fluorescence spectroscopy journal January 2020
Machine learning for nanoplasmonics journal January 2023
Sub-nanometre resolution in single-molecule photoluminescence imaging journal August 2020
Electronic excitations at the plasmon–molecule interface journal July 2024
Chiral molecules and the electron spin journal March 2019
The concept of active site in heterogeneous catalysis journal January 2022
Experimental characterization techniques for plasmon-assisted chemistry journal March 2022
Spatial and temporal exploration of heterogeneous catalysts with synchrotron radiation journal August 2018
Visualizing vibrational normal modes of a single molecule with atomically confined light journal April 2019
In situ Raman spectroscopy reveals the structure and dissociation of interfacial water journal December 2021
Digital colloid-enhanced Raman spectroscopy by single-molecule counting journal April 2024
The refinery of the future journal May 2024
Nanoscale chemical imaging using tip-enhanced Raman spectroscopy journal March 2019
Investigating heterogeneous defects in single-crystalline WS2 via tip-enhanced Raman spectroscopy journal September 2022
Operando monitoring of temperature and active species at the single catalyst particle level journal September 2019
Imaging the dynamics of catalysed surface reactions by in situ scanning electron microscopy journal December 2019
Self-activation of copper electrodes during CO electro-oxidation in alkaline electrolyte journal September 2020
Mechanistic study of an immobilized molecular electrocatalyst by in situ gap-plasmon-assisted spectro-electrochemistry journal February 2021
Plasmon-driven carbon–fluorine (C(sp3)–F) bond activation with mechanistic insights into hot-carrier-mediated pathways journal June 2020
N-Heterocyclic carbenes as tunable ligands for catalytic metal surfaces journal May 2021
Atomic-scale surface restructuring of copper electrodes under CO2 electroreduction conditions journal August 2023
Electrochemical surface-enhanced Raman spectroscopy journal October 2023
In-situ plasmon-driven chemical reactions revealed by high vacuum tip-enhanced Raman spectroscopy journal September 2012
“RaMassays”: Synergistic Enhancement of Plasmon-Free Raman Scattering and Mass Spectrometry for Multimodal Analysis of Small Molecules journal October 2016
Single molecule level plasmonic catalysis – a dilution study of p-nitrothiophenol on gold dimers journal January 2015
Ultrafast surface-enhanced Raman spectroscopy journal January 2015
Ultrafast and nonlinear surface-enhanced Raman spectroscopy journal January 2016
Plasmon-free SERS detection of environmental CO2on TiO2surfaces journal January 2016
Enantioselective amplification on circularly polarized laser-induced chiral nucleation from a NaClO3solution containing Ag nanoparticles journal January 2016
Dynamics of a plasmon-activated p-mercaptobenzoic acid layer deposited over Au nanoparticles using time-resolved SERS journal January 2016
Spatial resolution of tip-enhanced Raman spectroscopy – DFT assessment of the chemical effect journal January 2016
Molecular fluorescence enhancement in plasmonic environments: exploring the role of nonlocal effects journal January 2016
A classical description of subnanometer resolution by atomic features in metallic structures journal January 2017
ZORRO: zirconium oxide resonators for all-in-one Raman and whispering-gallery-mode optical sensing journal January 2017
Electrode–electrolyte interfaces in lithium-based batteries journal January 2018
Linking classical and molecular optomechanics descriptions of SERS journal January 2017
Shell isolated nanoparticles for enhanced Raman spectroscopy studies in lithium–oxygen cells journal January 2017
Nanoscale chemical imaging of solid–liquid interfaces using tip-enhanced Raman spectroscopy journal January 2018
Probing surface mediated configurations of nonplanar regioisomeric adsorbates using ultrahigh vacuum tip-enhanced Raman spectroscopy journal January 2019
Surface-enhanced Raman spectroscopy (SERS): a powerful technique to study the SEI layer in batteries journal January 2021
Asymmetric organocatalysis: an enabling technology for medicinal chemistry journal January 2021
New advances in using Raman spectroscopy for the characterization of catalysts and catalytic reactions journal January 2021
Bioinspired self-similar all-dielectric antennas: probing the effect of secondary scattering centres by Raman spectroscopy journal January 2020
Decoding the kinetic limitations of plasmon catalysis: the case of 4-nitrothiophenol dimerization journal January 2020
Metal–organic frameworks: opportunities and challenges for surface-enhanced Raman scattering – a review journal January 2020
Defect engineering in semiconductor-based SERS journal January 2022
Machine learning for rapid quantification of trace analyte molecules using SERS and flexible plasmonic paper substrates journal January 2022
Tracking heterogeneous structural motifs and the redox behaviour of copper–zinc nanocatalysts for the electrocatalytic CO2 reduction using operando time resolved spectroscopy and machine learning journal January 2022
Elucidating electrochemical CO2 reduction reaction processes on Cu(hkl) single-crystal surfaces by in situ Raman spectroscopy journal January 2022
Incorporating plasmonic featurization with machine learning to achieve accurate and bidirectional prediction of nanoparticle size and size distribution journal January 2022
Multi-mode enhanced Raman scattering spectroscopy using aggregation-free hybrid metal/metal-oxide nanoparticles with intrinsic oxygen vacancies journal January 2023
Tip-enhanced Raman imaging of plasmon-driven dimerization of 4-bromothiophenol on nickel-decorated gold nanoplate bimetallic nanostructures journal January 2023
Seeking a Au–C stretch on gold nanoparticles with 13C-labeled N-heterocyclic carbenes journal January 2023
Recent progress in SERS monitoring of photocatalytic reactions journal January 2024
Operando insights into correlating CO coverage and Cu–Au alloying with the selectivity of Au NP-decorated Cu2O nanocubes during the electrocatalytic CO2 reduction journal January 2024
Coupling of plasmonic hot spots with shurikens for superchiral SERS-based enantiomer recognition journal January 2023
Unlimiting ionic conduction: manipulating hydration dynamics through vibrational strong coupling of water journal January 2023
Plasmon-mediated dehydrogenation of the aromatic methyl group and benzyl radical formation journal January 2023
Expanding generality of surface-enhanced Raman spectroscopy with borrowing SERS activity strategy journal January 2007
Combining in situ characterization methods in one set-up: looking with more eyes into the intricate chemistry of the synthesis and working of heterogeneous catalysts journal January 2010
Polarization characteristics of surface-enhanced Raman scattering from a small number of molecules at the gap of a metal nano-dimer journal January 2011
Resonance contributions to anti-Stokes/Stokes ratios under surface enhanced Raman scattering conditions journal August 2005
Effect of surface plasmons on transitions in molecules journal March 1975
Theory of Raman scattering by molecules adsorbed on electrode surfaces journal November 1978
Surface roughness and the enhanced intensity of Raman scattering by molecules adsorbed on metals journal November 1978
Charge‐transfer theory of surface enhanced Raman spectroscopy: Herzberg–Teller contributions journal April 1986
Contribution of oxygen vacancies to the ferroelectric behavior of Hf0.5Zr0.5O2 thin films journal March 2015
Coupled wave equations theory of surface-enhanced femtosecond stimulated Raman scattering journal September 2016
Plasmonic reactivity of halogen thiophenols on gold nanoparticles studied by SERS and XPS journal August 2022
All-plasmonic-metal chiral nanostructures fabricated by circularly polarized light journal August 2023
Heterometallic antenna−reactor complexes for photocatalysis journal July 2016
Cascaded nanooptics to probe microsecond atomic-scale phenomena journal June 2020
Hot carrier multiplication in plasmonic photocatalysis journal May 2021
Computational chromatography: A machine learning strategy for demixing individual chemical components in complex mixtures journal December 2022
Quantifying the ultrafast and steady-state molecular reduction potential of a plasmonic photocatalyst journal October 2023
Direct-write 3D printing of plasmonic nanohelicoids by circularly polarized light journal March 2024
Probing the spatial extension of light trapping-induced enhanced Raman scattering in high-density Si nanowire arrays journal October 2014
Optical chiral metamaterials: a review of the fundamentals, fabrication methods and applications journal September 2016
Visually constructing the chemical structure of a single molecule by scanning Raman picoscopy journal November 2019
Photo-induced enhanced Raman spectroscopy as a probe for photocatalytic surfaces
  • Ben-Jaber, Sultan; Glass, Daniel; Brick, Thomas
  • Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 381, Issue 2259 https://doi.org/10.1098/rsta.2022.0343
journal September 2023
Surface-enhanced Raman spectroscopy at single-molecule scale and its implications in biology journal February 2013
Theory of Raman enhancement by two-dimensional materials: Applications for graphene-enhanced Raman spectroscopy journal July 2014
Ab initio nanoplasmonics: The impact of atomic structure journal October 2014
Quantum hydrodynamic theory for plasmonics: Impact of the electron density tail journal May 2016
Electromagnetic contributions to single-molecule sensitivity in surface-enhanced Raman scattering journal September 2000
Transformation-Optics Description of Nonlocal Effects in Plasmonic Nanostructures journal March 2012
Quantum Corrections in Nanoplasmonics: Shape, Scale, and Material journal April 2017
Theory of Enhance I Light Scattering from Molecules Adsorbed at the Metal-Solution Interface journal July 1979
Ultrahigh-Vacuum Studies of Enhanced Raman Scattering from Pyridine on Ag Surfaces journal June 1980
Electric Field Gradient Effects in Raman Spectroscopy journal November 2000
Beyond a Gaussian Denoiser: Residual Learning of Deep CNN for Image Denoising journal July 2017
Metal-organic frameworks tailor the properties of aluminum nanocrystals journal February 2019
Tracking interfacial single-molecule pH and binding dynamics via vibrational spectroscopy journal June 2021
Optical suppression of energy barriers in single molecule-metal binding journal June 2022
Spin-induced asymmetry reaction—The formation of asymmetric carbon by electropolymerization journal August 2022
Enhanced Enantioselectivity in Excitation of Chiral Molecules by Superchiral Light journal April 2011
Efficient hot-electron transfer by a plasmon-induced interfacial charge-transfer transition journal August 2015
Single-molecule optomechanics in “picocavities” journal November 2016
Quantifying hot carrier and thermal contributions in plasmonic photocatalysis journal October 2018
Tilting a ground-state reactivity landscape by vibrational strong coupling journal February 2019
Determining structural and chemical heterogeneities of surface species at the single-bond limit journal February 2021
Earth-abundant photocatalyst for H 2 generation from NH 3 with light-emitting diode illumination journal November 2022
Single-Molecule Surface-Enhanced Raman Spectroscopy journal May 2012
First-Principles Insights into Plasmon-Induced Catalysis journal April 2021
Mechanisms of Photothermalization in Plasmonic Nanostructures: Insights into the Steady State journal April 2023
Localized Surface Plasmon Resonance Spectroscopy and Sensing journal May 2007
Time-Dependent Determination of HF Formation in LiPF6 -Containing Electrolytes in Different Cell Types by Spectroscopic Ellipsometry journal March 2013
Advanced Model for Solid Electrolyte Interphase Electrodes in Liquid and Polymer Electrolytes journal January 1997
Combined miRNA and SERS urine liquid biopsy for the point-of-care diagnosis and molecular stratification of bladder cancer journal April 2022
Determination of Molecular Orientation in Bi-analyte Mono-molecule Layer through Electrochemical Surface-enhanced Raman Scattering Measurements journal August 2019
Quantum plasmonics: from jellium models to ab initio calculations journal January 2016
Perspective: plasmon antennas for nanoscale chiral chemistry journal February 2020
Applied Catalysis in Chemical Industry: Synthesis, Catalyst Design, and Evaluation journal March 2023
Development of Highly Sensitive Raman Spectroscopy for Subnano and Single-Atom Detection journal August 2021
Single-Molecule Surface-Enhanced Raman Spectroscopy journal June 2022
Plasmon Enhanced Spectroscopy and Photocatalysis preprint January 2024

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