ZeroCAL: Eliminating Carbon Dioxide Emissions from Limestone’s Decomposition to Decarbonize Cement Production

Leão, Adriano; Collin, Marie; Ghodkhande, Swarali; Bouissonnié, Arnaud; Chen, Xin; Malin, Benjamin; Liu, Yiming; Hovey, Geanna; Govindhakannan, Jagannathan; Plante, Erika La; Jassby, David; Gädt, Torben; Corsini, Lorenzo; Simonetti, Dante; Rosner, Fabian; Sant, Gaurav

doi:10.1021/acssuschemeng.4c03193

Title: ZeroCAL: Eliminating Carbon Dioxide Emissions from Limestone’s Decomposition to Decarbonize Cement Production

Journal Article · 09 October 2024 · ACS Sustainable Chemistry & Engineering

DOI: https://doi.org/10.1021/acssuschemeng.4c03193 · OSTI ID:2462842

^[1];

^[1]; Ghodkhande, Swarali ^[1];

^[1];

^[2]; Malin, Benjamin ^[1];

^[1]; Hovey, Geanna ^[1]; Govindhakannan, Jagannathan ^[1];

^[1];

^[3];

^[4];

^[1]; Rosner, Fabian ^[1];

^[1]

University of California, Los Angeles, CA (United States)
University of California, Los Angeles, CA (United States); Equatic Inc., Los Angeles, CA (United States)
Technical University of Munich, Garching (Germany)
Equatic Inc., Los Angeles, CA (United States)

Limestone (calcite, CaCO₃) is an abundant and cost-effective source of calcium oxide (CaO) for cement and lime production. However, the thermochemical decomposition of limestone (~800 °C, 1 bar) to produce lime (CaO) results in substantial carbon dioxide (CO_2(g)) emissions and energy use, i.e., ~1 tonne [t] of CO₂ and ~1.4 MWh per t of CaO produced. Here, we describe a new pathway to use CaCO₃ as a Ca source to make hydrated lime (portlandite, Ca(OH)₂) at ambient conditions (p, T) while nearly eliminating process CO_2(g) emissions (as low as 1.5 mol. % of the CO₂ in the precursor CaCO₃, equivalent to 9 kg of CO_2(g) per t of Ca(OH)₂) within an aqueous flowelectrolysis/ pH-swing process that coproduces hydrogen (H_2(g)) and oxygen (O_2(g)). Because Ca(OH)₂ is a zero-carbon precursor for cement and lime production, this approach represents a significant advancement in the production of zero-carbon cement. The Zero CArbon Lime (ZeroCAL) process includes dissolution, separation/recovery, and electrolysis stages according to the following steps: (Step 1) chelator (e.g., ethylenediaminetetraacetic acid, EDTA)-promoted dissolution of CaCO₃ and complexation of Ca²⁺ under basic (>pH 9) conditions, (Step 2a) Ca enrichment and separation using nanofiltration (NF), which allows separation of the Ca-EDTA complex from the accompanying bicarbonate (HCO₃^–) species, (Step 2b) acidity-promoted decomplexation of Ca from EDTA, which allows near-complete chelator recovery and the formation of a Ca-enriched stream, and (Step 3) rapid precipitation of Ca(OH)₂ from the Ca-enriched stream using electrolytically produced alkalinity. These reactions can be conducted in a seawater matrix yielding coproducts including hydrochloric acid (HCl) and sodium bicarbonate (NaHCO₃), resulting from electrolysis and limestone dissolution, respectively. Careful analysis of the reaction stoichiometries and energy balances indicates that approximately 1.35 t of CaCO₃, 1.09 t of water, 0.79 t of sodium chloride (NaCl), and ~2 MWh of electrical energy are required to produce 1 t of Ca(OH)₂, with significant opportunity for process intensification. This approach has major implications for decarbonizing cement production within a paradigm that emphasizes the use of existing cement plants and electrification of industrial operations, while also creating approaches for alkalinity production that enable cost-effective and scalable CO₂ mineralization via Ca(OH)₂ carbonation.

View Journal Article

Cite

Export

Save

Research Organization:: University of California, Los Angeles, CA (United States)

Sponsoring Organization:: USDOE Advanced Research Projects Agency - Energy (ARPA-E)

Grant/Contract Number:: AR0001551; AR0001777

OSTI ID:: 2462842

Journal Information:: ACS Sustainable Chemistry & Engineering, Journal Name: ACS Sustainable Chemistry & Engineering Journal Issue: 43 Vol. 12; ISSN 2168-0485

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

References (89)

Membrane Technology and Applications Baker, Richard W. ohn Wiley & Sons, Ltd https://doi.org/10.1002/0470020393	book	January 2004
New insights into the mechanisms of carbon dioxide mineralization by portlandite Falzone, Gabriel; Mehdipour, Iman; Neithalath, Narayanan AIChE Journal, Vol. 67, Issue 5 https://doi.org/10.1002/aic.17160	journal	January 2021
Literature study on the rate and mechanism of carbonation of lime in mortars / Literaturstudie über Mechanismus und Grad der Karbonatisierung von Kalkhydrat im Mörtel Despotou, Eleni; Shtiza, Aurela; Schlegel, Thomas Mauerwerk, Vol. 20, Issue 2 https://doi.org/10.1002/dama.201500674	journal	April 2016
Comparing nanofiltration and reverse osmosis for drinking water augmentation Bellona, Christopher; Drewes, Jörg E.; Oelker, Gregg Journal AWWA, Vol. 100, Issue 9 https://doi.org/10.1002/j.1551-8833.2008.tb09724.x	journal	September 2008
The Influence of Chelating Agents on the Kinetics of Calcite Dissolution Fredd, Christopher N.; Fogler, H. Scott Journal of Colloid and Interface Science, Vol. 204, Issue 1 https://doi.org/10.1006/jcis.1998.5535	journal	August 1998
Kinetics of Water-Rock Interaction Brantley, Susan L.; Kubicki, James D.; White, Art F. Springer New York, NY https://doi.org/10.1007/978-0-387-73563-4	book	January 2008
Basic Principles of Membrane Technology Mulder, Marcel https://doi.org/10.1007/978-94-009-1766-8	book	January 1996
GEM-Selektor geochemical modeling package: revised algorithm and GEMS3K numerical kernel for coupled simulation codes Kulik, Dmitrii A.; Wagner, Thomas; Dmytrieva, Svitlana V. Computational Geosciences https://doi.org/10.1007/s10596-012-9310-6	journal	August 2012
The ecoinvent database version 3 (part I): overview and methodology Wernet, Gregor; Bauer, Christian; Steubing, Bernhard The International Journal of Life Cycle Assessment, Vol. 21, Issue 9 https://doi.org/10.1007/s11367-016-1087-8	journal	April 2016
Electrification of Industry: Potential, Challenges and Outlook Wei, Max; McMillan, Colin A.; de la Rue du Can, Stephane Current Sustainable/Renewable Energy Reports, Vol. 6, Issue 4 https://doi.org/10.1007/s40518-019-00136-1	journal	November 2019
The effect of pH on the nanofiltration of the carbonate system in solution Simpson, A. E.; Kerr, C. A.; Buckley, C. A. Desalination, Vol. 64 https://doi.org/10.1016/0011-9164(87)90104-4	journal	January 1987
Intermediate reverse osmosis ultrafiltration (RO UF) membranes for concentration and desalting of low molecular weight organic solutes Perry, M.; Linder, C. Desalination, Vol. 71, Issue 3 https://doi.org/10.1016/0011-9164(89)85026-X	journal	January 1989
Characterisation of nanofiltration membranes for the separation of aqueous dye-salt solutions Schirg, P.; Widmer, F. Desalination, Vol. 89, Issue 1 https://doi.org/10.1016/0011-9164(92)80154-2	journal	November 1992
Calcium compleing with carbonate ion in aqueous solutions at 25°C and 1 atmosphere Lafon, G. Michel Geochimica et Cosmochimica Acta, Vol. 34, Issue 8 https://doi.org/10.1016/0016-7037(70)90132-8	journal	August 1970
SUPCRT92: A software package for calculating the standard molal thermodynamic properties of minerals, gases, aqueous species, and reactions from 1 to 5000 bar and 0 to 1000°C Johnson, James W.; Oelkers, Eric H.; Helgeson, Harold C. Computers & Geosciences, Vol. 18, Issue 7 https://doi.org/10.1016/0098-3004(92)90029-Q	journal	August 1992
Desalination of brackish water by nanofiltration and reverse osmosis Mohsen, Mousa S.; Jaber, Jamal O.; Afonso, Maria Diná Desalination, Vol. 157, Issue 1-3 https://doi.org/10.1016/S0011-9164(03)00397-7	journal	August 2003
Variation in calcite dissolution rates: Arvidson, Rolf S.; Ertan, Inci Evren; Amonette, James E. Geochimica et Cosmochimica Acta, Vol. 67, Issue 9 https://doi.org/10.1016/S0016-7037(02)01177-8	journal	May 2003
Energetics of Ca2+–EDTA interactions: calorimetric study Griko, Yuri V. Biophysical Chemistry, Vol. 79, Issue 2 https://doi.org/10.1016/S0301-4622(99)00047-2	journal	June 1999
Recovery of EDTA and metal precipitation from soil flushing solutions Di Palma, L.; Ferrantelli, P.; Merli, C. Journal of Hazardous Materials, Vol. 103, Issue 1-2 https://doi.org/10.1016/S0304-3894(03)00268-1	journal	October 2003
Experimental analysis of negative salt rejection in nanofiltration membranes Gilron, J. Journal of Membrane Science, Vol. 185, Issue 2 https://doi.org/10.1016/S0376-7388(00)00639-6	journal	April 2001
Influence of molecular size, polarity and charge on the retention of organic molecules by nanofiltration Van der Bruggen, B.; Schaep, J.; Wilms, D. Journal of Membrane Science, Vol. 156, Issue 1 https://doi.org/10.1016/S0376-7388(98)00326-3	journal	April 1999
Efficiency improvement of a fuel cell cogeneration plant linked with district heating: Construction of a water condensation latent heat recovery system and analysis of real operational data Yuan-Hu, Li; Kim, Jinyoung; Lee, Sangrae Applied Thermal Engineering, Vol. 201 https://doi.org/10.1016/j.applthermaleng.2021.117754	journal	January 2022
Cemdata18: A chemical thermodynamic database for hydrated Portland cements and alkali-activated materials Lothenbach, Barbara; Kulik, Dmitrii A.; Matschei, Thomas Cement and Concrete Research, Vol. 115 https://doi.org/10.1016/j.cemconres.2018.04.018	journal	January 2019
Calcite dissolution kinetics in view of Gibbs free energy, dislocation density, and pCO2 Xu, Jie; Fan, Chunfang; Teng, H. Henry Chemical Geology, Vol. 322-323 https://doi.org/10.1016/j.chemgeo.2012.04.019	journal	September 2012
From mixed flow reactor to column experiments and modeling: Upscaling of calcite dissolution rate Bouissonnié, Arnaud; Daval, Damien; Marinoni, Marianna Chemical Geology, Vol. 487 https://doi.org/10.1016/j.chemgeo.2018.04.017	journal	May 2018
Process evaluation for optimization of EDTA use and recovery for heavy metal removal from a contaminated soil Lim, Teik-Thye; Chui, Peng-Cheong; Goh, Kok-Hui Chemosphere, Vol. 58, Issue 8 https://doi.org/10.1016/j.chemosphere.2004.09.046	journal	February 2005
Review of the dielectric properties of nanofiltration membranes and verification of the single oriented layer approximation Oatley, Darren L.; Llenas, Laia; Pérez, Ramon Advances in Colloid and Interface Science, Vol. 173 https://doi.org/10.1016/j.cis.2012.02.001	journal	May 2012
Interaction of electrolytes and non-electrolytes in nanofiltration Mandale, Stephen; Jones, Meirion Desalination, Vol. 219, Issue 1-3 https://doi.org/10.1016/j.desal.2007.06.005	journal	January 2008
A combined ion exchange–nanofiltration process for water desalination: III. Pilot scale studies Hilal, Nidal; Kochkodan, Victor; Al Abdulgader, Hasan Desalination, Vol. 363 https://doi.org/10.1016/j.desal.2014.11.030	journal	May 2015
Development of lower cost seawater desalination processes using nanofiltration technologies — A review Zhou, Dong; Zhu, Lijing; Fu, Yinyi Desalination, Vol. 376 https://doi.org/10.1016/j.desal.2015.08.020	journal	November 2015
Design and modeling of novel low-pressure nanofiltration hollow fiber modules for water softening and desalination pretreatment Labban, Omar; Chong, Tzyy Haur; Lienhard, John H. Desalination, Vol. 439 https://doi.org/10.1016/j.desal.2018.04.002	journal	August 2018
Indicators for industrial energy efficiency in India Gielen, Dolf; Taylor, Peter Energy, Vol. 34, Issue 8 https://doi.org/10.1016/j.energy.2008.11.008	journal	August 2009
A forward looking perspective on the cement and concrete industry: Implications of growth and development in the Global South Uratani, Joao M.; Griffiths, Steve Energy Research & Social Science, Vol. 97 https://doi.org/10.1016/j.erss.2023.102972	journal	March 2023
Effects in the solubility of CaCO3: Experimental study and model description Coto, B.; Martos, C.; Peña, J. L. Fluid Phase Equilibria, Vol. 324 https://doi.org/10.1016/j.fluid.2012.03.020	journal	June 2012
Do organic ligands affect calcite dissolution rates? Oelkers, Eric H.; Golubev, Sergey V.; Pokrovsky, Oleg S. Geochimica et Cosmochimica Acta, Vol. 75, Issue 7 https://doi.org/10.1016/j.gca.2011.01.002	journal	April 2011
Trends and developments in green cement and concrete technology Imbabi, Mohammed S.; Carrigan, Collette; McKenna, Sean International Journal of Sustainable Built Environment, Vol. 1, Issue 2 https://doi.org/10.1016/j.ijsbe.2013.05.001	journal	December 2012
Hot water recovery and reuse in textile sector with pilot scale ceramic ultrafiltration/nanofiltration membrane system Ağtaş, Meltem; Yılmaz, Özgün; Dilaver, Mehmet Journal of Cleaner Production, Vol. 256 https://doi.org/10.1016/j.jclepro.2020.120359	journal	May 2020
The past and future of sustainable concrete: A critical review and new strategies on cement-based materials de Brito, Jorge; Kurda, Rawaz Journal of Cleaner Production, Vol. 281 https://doi.org/10.1016/j.jclepro.2020.123558	journal	January 2021
Priorities for supporting emission reduction technologies in the cement sector – A multi-criteria decision analysis of CO2 mineralisation Strunge, Till; Naims, Henriette; Ostovari, Hesam Journal of Cleaner Production, Vol. 340 https://doi.org/10.1016/j.jclepro.2022.130712	journal	March 2022
A novel strategy for the application of levulinic acid with simultaneous NAD+ regeneration and membrane separation of products Bachosz, Karolina; Smułek, Wojciech; Zdarta, Jakub Journal of Environmental Chemical Engineering, Vol. 10, Issue 6 https://doi.org/10.1016/j.jece.2022.108703	journal	December 2022
Brine treatment technologies towards minimum/zero liquid discharge and resource recovery: State of the art and techno-economic assessment Cipolletta, Giulia; Lancioni, Nicola; Akyol, Çağrı Journal of Environmental Management, Vol. 300 https://doi.org/10.1016/j.jenvman.2021.113681	journal	December 2021
Extraction of nickel from spent catalyst using fresh and recovered EDTA Goel, Shina; Pant, K. K.; Nigam, K. D. P. Journal of Hazardous Materials, Vol. 171, Issue 1-3 https://doi.org/10.1016/j.jhazmat.2009.05.131	journal	November 2009
Effect of composition on the short-term and long-term dissolution rates of ten borosilicate glasses of increasing complexity from 3 to 30 oxides Gin, Stéphane; Beaudoux, Xavier; Angéli, Frédéric Journal of Non-Crystalline Solids, Vol. 358, Issue 18-19 https://doi.org/10.1016/j.jnoncrysol.2012.05.024	journal	September 2012
Glass dissolution rate measurement and calculation revisited Fournier, Maxime; Ull, Aurélien; Nicoleau, Elodie Journal of Nuclear Materials, Vol. 476 https://doi.org/10.1016/j.jnucmat.2016.04.028	journal	August 2016
Emerging calcium batteries Stievano, Lorenzo; de Meatza, Iratxe; Bitenc, Jan Journal of Power Sources, Vol. 482 https://doi.org/10.1016/j.jpowsour.2020.228875	journal	January 2021
A pilot scale concurrent removal of fluoride, arsenic, sulfate and nitrate by using nanofiltration: Competing ion interaction and modelling approach Jadhav, Sachin V.; Marathe, Kumudini. V.; Rathod, Virendra K. Journal of Water Process Engineering, Vol. 13 https://doi.org/10.1016/j.jwpe.2016.04.008	journal	October 2016
Separation of metal ions and chelating agents by nanofiltration Balanyà, T.; Labanda, J.; Llorens, J. Journal of Membrane Science, Vol. 345, Issue 1-2 https://doi.org/10.1016/j.memsci.2009.08.009	journal	December 2009
From academia to industry: Success criteria for upscaling nanofiltration membranes for water and solvent applications El Fadil, Abdelhakim; Verbeke, Rhea; Kyburz, Markus Journal of Membrane Science, Vol. 675 https://doi.org/10.1016/j.memsci.2023.121393	journal	June 2023
Surface charge study of EDTA interaction with carbonate rock during chelating agent flooding Hassan, Amjed M.; Al-Hashim, Hasan S. Journal of Petroleum Science and Engineering, Vol. 191 https://doi.org/10.1016/j.petrol.2020.107163	journal	August 2020
Analysis of particles size distributions in Mg(OH)2 precipitation from highly concentrated MgCl2 solutions Battaglia, G.; Romano, S.; Raponi, A. Powder Technology, Vol. 398 https://doi.org/10.1016/j.powtec.2021.117106	journal	January 2022
A review of current practice for life cycle assessment of cement and concrete Olsson, Josefine A.; Miller, Sabbie A.; Kneifel, Joshua D. Resources, Conservation and Recycling, Vol. 206 https://doi.org/10.1016/j.resconrec.2024.107619	journal	July 2024
A critical review on energy use and savings in the cement industries Madlool, N. A.; Saidur, R.; Hossain, M. S. Renewable and Sustainable Energy Reviews, Vol. 15, Issue 4 https://doi.org/10.1016/j.rser.2011.01.005	journal	May 2011
An overview of energy savings measures for cement industries Madlool, N. A.; Saidur, R.; Rahim, N. A. Renewable and Sustainable Energy Reviews, Vol. 19 https://doi.org/10.1016/j.rser.2012.10.046	journal	March 2013
Efficiencies and mechanisms of chemical cleaning agents for nanofiltration membranes used in produced wastewater desalination Zhao, Dongsheng; Qiu, Liping; Song, Jiyu Science of The Total Environment, Vol. 652 https://doi.org/10.1016/j.scitotenv.2018.10.221	journal	February 2019
Removal of chelated heavy metals from aqueous solution: A review of current methods and mechanisms Zhu, Ying; Fan, Wenhong; Zhou, Tingting Science of The Total Environment, Vol. 678 https://doi.org/10.1016/j.scitotenv.2019.04.416	journal	August 2019
Environmental benefit assessment of steel slag utilization and carbonation: A systematic review Li, Lufan; Ling, Tung-Chai; Pan, Shu-Yuan Science of The Total Environment, Vol. 806 https://doi.org/10.1016/j.scitotenv.2021.150280	journal	February 2022
The effects of feed solution temperature on pore size and trace organic contaminant rejection by the nanofiltration membrane NF270 Dang, Hai Quang; Price, William E.; Nghiem, Long Duc Separation and Purification Technology, Vol. 125 https://doi.org/10.1016/j.seppur.2013.12.043	journal	April 2014
Experimental simulation of continuous nanofiltration processes by means of a single module in batch mode Santafé-Moros, Asunción; Gozálvez-Zafrilla, José M.; Lora-García, Jaime Separation and Purification Technology, Vol. 187 https://doi.org/10.1016/j.seppur.2017.06.059	journal	October 2017
Energy consumption assessment in a cement production plant Afkhami, Behdad; Akbarian, Babak; Beheshti A., Narges Sustainable Energy Technologies and Assessments, Vol. 10 https://doi.org/10.1016/j.seta.2015.03.003	journal	June 2015
Steel slag in China: Treatment, recycling, and management Guo, Jianlong; Bao, Yanping; Wang, Min Waste Management, Vol. 78 https://doi.org/10.1016/j.wasman.2018.04.045	journal	August 2018
Laboratory and Pilot-Scale Nanofiltration Treatment of Abandoned Mine Drainage for the Recovery of Products Suitable for Industrial Reuse Wadekar, Shardul S.; Hayes, Tom; Lokare, Omkar R. Industrial & Engineering Chemistry Research, Vol. 56, Issue 25 https://doi.org/10.1021/acs.iecr.7b01329	journal	June 2017
The Promise of Calcium Batteries: Open Perspectives and Fair Comparisons Hosein, Ian D. ACS Energy Letters, Vol. 6, Issue 4 https://doi.org/10.1021/acsenergylett.1c00593	journal	March 2021
Electrolytic Seawater Mineralization and the Mass Balances That Demonstrate Carbon Dioxide Removal La Plante, Erika Callagon; Chen, Xin; Bustillos, Steven ACS ES&T Engineering, Vol. 3, Issue 7 https://doi.org/10.1021/acsestengg.3c00004	journal	April 2023
Saline Water-Based Mineralization Pathway for Gigatonne-Scale CO ₂ Management La Plante, Erika Callagon; Simonetti, Dante A.; Wang, Jingbo ACS Sustainable Chemistry & Engineering, Vol. 9, Issue 3 https://doi.org/10.1021/acssuschemeng.0c08561	journal	January 2021
Experimental Energy Barriers to Anions Transporting through Nanofiltration Membranes Richards, Laura A.; Richards, Bryce S.; Corry, Ben Environmental Science & Technology, Vol. 47, Issue 4 https://doi.org/10.1021/es303925r	journal	February 2013
Use of Crushed Limestone to Neutralize Acid Wastes Pearson, Frank H.; McDonnell, Archie J. Journal of the Environmental Engineering Division, Vol. 101, Issue 1 https://doi.org/10.1061/JEEGAV.0000293	journal	January 1975
Influence of chemical speciation on the separation of metal ions from chelating agents by nanofiltration membranes Balanyà, Teresa; Labanda, Jordi; Llorens, Joan Separation Science and Technology, Vol. 54, Issue 1 https://doi.org/10.1080/01496395.2018.1502781	journal	July 2018
Bench and pilot scale performance assessment of recycled membrane converted from old nanofiltration membranes Coutinho de Paula, Eduardo; Martins, Poliana Vicente; Ferreira, Isabella Coelho de Melo Environmental Technology, Vol. 41, Issue 10 https://doi.org/10.1080/09593330.2018.1526218	journal	September 2018
Selection of nanofiltration membranes as pretreatment for scaling prevention in SWRO using real seawater Llenas, Laia; Ribera, Gemma; Martínez-Lladó, Xavier Desalination and Water Treatment, Vol. 51, Issue 4-6 https://doi.org/10.1080/19443994.2012.714578	journal	January 2013
Comprehensive pilot-scale investigation of seawater nanofiltration softening by increasing permeate recovery with recirculation Song, Yuefei; Li, Tiemei; Zhou, Jianguo Desalination and Water Treatment, Vol. 57, Issue 37 https://doi.org/10.1080/19443994.2015.1084531	journal	August 2016
Natural and enhanced carbonation of lime in its different applications: a review Campo, Francesco Pietro; Tua, Camilla; Biganzoli, Laura Environmental Technology Reviews, Vol. 10, Issue 1 https://doi.org/10.1080/21622515.2021.1982023	journal	January 2021
A profile refinement method for nuclear and magnetic structures Rietveld, H. M. Journal of Applied Crystallography, Vol. 2, Issue 2, p. 65-71 https://doi.org/10.1107/S0021889869006558	journal	June 1969
Profex : a graphical user interface for the Rietveld refinement program BGMN Doebelin, Nicola; Kleeberg, Reinhard Journal of Applied Crystallography, Vol. 48, Issue 5 https://doi.org/10.1107/S1600576715014685	journal	August 2015
Fluid Mechanics of Waste-Water Disposal in the Ocean Koh, R. C. Y.; Brooks, N. H. Annual Review of Fluid Mechanics, Vol. 7, Issue 1 https://doi.org/10.1146/annurev.fl.07.010175.001155	journal	January 1975
Nanofiltration in Transforming Surface Water into Healthy Water: Comparison with Reverse Osmosis Naidu, L. D.; Saravanan, S.; Chidambaram, M. Journal of Chemistry, Vol. 2015 https://doi.org/10.1155/2015/326869	journal	January 2015
High Flux and Antifouling Nanofiltration Membrane Modified by Ag@UiO-66-NH2 and Its Application for Biphenol A Removal Chen, Qing-Chun; Bang, Yu; Li, Lu Advances in Polymer Technology, Vol. 2022 https://doi.org/10.1155/2022/4197365	journal	January 2022
Nagra/PSI Chemical Thermodynamic Data Base 01/01 Hummel, W.; Berner, U.; Curti, E. Radiochimica Acta, Vol. 90, Issue 9-11 https://doi.org/10.1524/ract.2002.90.9-11_2002.805	journal	January 2002
Cement and carbon emissions Barcelo, Laurent; Kline, John; Walenta, Gunther Materials and Structures, Vol. 47, Issue 6 https://doi.org/10.1617/s11527-013-0114-5	journal	June 2013
The pore solution of blended cements: a review Vollpracht, Anya; Lothenbach, Barbara; Snellings, Ruben Materials and Structures, Vol. 49, Issue 8 https://doi.org/10.1617/s11527-015-0724-1	journal	October 2015
Theoretical prediction of the thermodynamic behavior of aqueous electrolytes by high pressures and temperatures; IV, Calculation of activity coefficients, osmotic coefficients, and apparent molal and standard and relative partial molal properties to 600 degrees C and 5kb Helgeson, H. C.; Kirkham, D. H.; Flowers, G. C. American Journal of Science, Vol. 281, Issue 10 https://doi.org/10.2475/ajs.281.10.1249	journal	December 1981
Comparison of Technologies for CO2 Capture from Cement Production—Part 2: Cost Analysis Gardarsdottir, Stefania; De Lena, Edoardo; Romano, Matteo Energies, Vol. 12, Issue 3 https://doi.org/10.3390/en12030542	journal	February 2019
The Use of Calcium Phosphates in Cosmetics, State of the Art and Future Perspectives Carella, Francesca; Degli Esposti, Lorenzo; Adamiano, Alessio Materials, Vol. 14, Issue 21 https://doi.org/10.3390/ma14216398	journal	October 2021
Mussel Shells, a Valuable Calcium Resource for the Pharmaceutical Industry Mititelu, Magdalena; Stanciu, Gabriela; Drăgănescu, Doina Marine Drugs, Vol. 20, Issue 1 https://doi.org/10.3390/md20010025	journal	December 2021
Analysis of the Flux Performance of Different RO/NF Membranes in the Treatment of Agroindustrial Wastewater by Means of the Boundary Flux Theory Ochando-Pulido, Javier M.; Martínez-Férez, Antonio; Stoller, Marco Membranes, Vol. 9, Issue 1 https://doi.org/10.3390/membranes9010002	journal	December 2018
A Pilot-Scale Nanofiltration–Ultrafiltration Integrated System for Advanced Drinking Water Treatment: Process Performance and Economic Analysis Chen, Fengxia; Zhu, Lifang; Tang, Jianzhong Processes, Vol. 11, Issue 5 https://doi.org/10.3390/pr11051300	journal	April 2023
Principles and Technical Application of Mixing Zones for Wastewater Discharges to Freshwater and Marine Environments Campos, Carlos J. A.; Morrisey, Donald J.; Barter, Paul Water, Vol. 14, Issue 8 https://doi.org/10.3390/w14081201	journal	April 2022
GEM-SELEKTOR GEOCHEMICAL MODELING PACKAGE: TSolMod LIBRARY AND DATA INTERFACE FOR MULTICOMPONENT PHASE MODELS Wagner, T.; Kulik, D. A.; Hingerl, F. F. The Canadian Mineralogist, Vol. 50, Issue 5 https://doi.org/10.3749/canmin.50.5.1173	journal	October 2012
Performance of NF90 and NF270 commercial nanofiltration membranes in the defluoridation of Algerian brackish water Ramdani, Amina; Deratani, André; Taleb, Safia DESALINATION AND WATER TREATMENT, Vol. 212 https://doi.org/10.5004/dwt.2021.26680	journal	January 2021
Global CO ₂ emissions from cement production Andrew, Robbie M. Earth System Science Data, Vol. 10, Issue 1 https://doi.org/10.5194/essd-10-195-2018	journal	January 2018

Similar Records

Scalable electrified cementitious materials production and recycling

Journal Article · 2024 · Energy & Environmental Science · OSTI ID:2483753

Lu, Xiao Kun; Zhang, Wenxin; Ruggiero, Brianna N.; +2 more

Study of limestone calcination with CO{sub 2} capture: decomposition behavior in a CO{sub 2} atmosphere

Journal Article · 2007 · Energy and Fuels · OSTI ID:20978282

Wang, Yin; Lin, Shiying; Suzuki, Yoshizo

Comparative SO sub 2 reactivity of CaO derived from CaCO sub 3 and Ca(OH) sub 2

Technical Report · 1988 · OSTI ID:5743604

Gullett, B K; Bruce, K R; Beach, L O

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
calcite
calcium
cement
decarbonization
dissolution
electrolysis
limestone
membranes
pH swing
seawater

Title: ZeroCAL: Eliminating Carbon Dioxide Emissions from Limestone’s Decomposition to Decarbonize Cement Production

Citation Formats

References (89)

Similar Records

Related Subjects