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Title: Probing the protonation and reduction of heptavalent neptunium with computational guidance

Journal Article · · Dalton Transactions
DOI: https://doi.org/10.1039/D4DT01706D · OSTI ID:2459391
ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1];  [2]; ORCiD logo [1]
  1. Department of Chemistry, University of Iowa, Iowa City, IA 52242, USA
  2. Department of Chemistry, University of Iowa, Iowa City, IA 52242, USA, Center for Functional Nanomaterials, Brookhaven National Laboratory, Upton, NY 11973, USA
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Computational and experimental results detail the speciation and stability of Np( vii ) under varied pH conditions. Sequential protonation reactions and their thermodynamic feasibility for the Np( vii )O 4 (OH) 2 3+  to Np( vi )O 2 2+ transition are discussed.

Sponsoring Organization:
USDOE
Grant/Contract Number:
SC0023995; SC0012704
OSTI ID:
2459391
Journal Information:
Dalton Transactions, Journal Name: Dalton Transactions Journal Issue: 39 Vol. 53; ISSN 1477-9226; ISSN ICHBD9
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English

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